Tag: catalysis
Questions Related to catalysis
What does a catalyst do?
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Alter the state of equilibrium.
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Decreases the activation energy.
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Increases collision frequency.
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Increases the average kinetic energy of reacting species.
Catalyst is a substance, which lowers the activation energy of reaction because it provides an alternate pathway for reaction. Also, it increases backward and forward reaction to the same extent. Due to this lower activation energy, equilibrium is attained faster.
Which of the following are electrophiles?
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$BF _3$
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$: CCl _2$
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$^{\oplus}NH _4$
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$I^{\ominus}$
Which of the following is the best way to speed up a chemical reaction?
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Make an effort to concentrate the reactants as best as possible
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Add a catalyst
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Cool the reaction down
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Increase the pressure on the system
Competitive inhibition is reversible.
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True
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False
Competitive Inhibitors belong to the category of enzymes known as reversible inhibitors. Reversible inhibitors dissociate the enzyme-inhibitor complex as soon as possible.
This Chemical reaction can be reversed by increasing concentration of substrate. These process continuously takes place as $E + S \rightarrow ES \rightarrow E + P$The structural resemblence of substrate and inhibitor leads to______________ inhibition.
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non-competitive
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competitive
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both $A$ and $B$
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none of the above
Competitive Inhibitor - A competitive inhibitor is any compound which closely resembles the chemical structure and molecular geometry of the substrate.
Non-competitive Inhibitor - A non-competitive inhibitor is a substance that interacts with the enzyme, but usually not at the active site. The noncompetitive inhibitor reacts either remote from or very close to the active site.
The process which is catalysed by one of the product is called :
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acid - base catalysis
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autocatalysis
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negative catalysis
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homogeneous catalysis
A catalyst increases the rate of a reaction by:
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increasing the activation energy of the reaction
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increasing the value of rate constants $(k _f$ and $k _b)$
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increasing the enthalpy change of the reaction
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decreasing the enthalpy change of the reaction
A catalyst increases rate of reacting by decreasing activation energy. and increasing the enthalpy change of the reaction
The auto catalyst in the decomposition of arsine to Arsenic and $H _2$ is
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$As _2O _3$
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$As$
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$H _2$
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$Ge$
Which of the following is used as autocatalyst
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$ KMnO _4 $
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$ AI _2O _3 $
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$ CaC _3 $
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All of these
Which one of the following reactions is an example of auto-catalysis ?
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$2{ AsH } _{ 3 }(s)\rightarrow 2As(s)+3{ H } _{ 2 }(g)$
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${ N } _{ 2 }(g)\rightarrow 3{ H } _{ 2 }(g)\overset { Fe(g) }{ \rightarrow } 2N{ H } _{ 3 }(g)$
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${ 2SO } _{ 2 }(g)\rightarrow { O } _{ 2 }(g)\overset { NO(g) }{ \rightarrow } 2S{ O } _{ 3 }(g)$
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${ C } _{ 12 }{ H } _{ 22 }{ O } _{ H }(l)+{ H } _{ 2 }O(l)\overset { { H }^{ - }(l) }{ \rightarrow } { C } _{ 6 }{ H } _{ 12 }{ O } _{ 6 }(l){ HC } _{ 6 }{ H } _{ 12 }{ O } _{ 6 }(l)$
Auto-catalysis is defined as the reaction that is catalyzed by one of its product. in auto-catalysis product of reaction acts as a catalyst for the reaction. In auto-catalysis the initial rate of reaction rises as the catalytic product is formed instead of decreasing steadily.