0

Chemical Thermodynamics and Energetics

Description: This test is based on Chemical thermodyanamics & Energetics which is highly useful for engeneering aspirants.
Number of Questions: 25
Created by:
Tags: enthalpy intensive propertive state function endothermic reaction etc Basic Concepts and Zeroth Law of Thermodynamics Laws of Thermodynamics Entropy and Gibbs Free Energy Gibbs Energy and Spontaneity Hess Law of Constant Heat Summation Hess-s Law
Attempted 0/25 Correct 0 Score 0

The thermodyanamic process proceeding without any change in enthalpy is

  1. an isenthalpic process

  2. isentropic process

  3. an isochoric process

  4. an isobaric process


Correct Option: A
Explanation:

This process proceeds without any change in enthalpy or specific enthalpy (H), e.g. throttling process.

Which of the following posseses the highest magnitude of internal energy?

  1. Gaseous state

  2. Liquid state

  3. Solid state

  4. All have same magnitude


Correct Option: A
Explanation:

This state of matter has relatively low density and viscosity. It also has relatively great expansion and contraction with changes in pressure and temperature. It has the highest magnitude of internal energy among the three states of matter.

Sweating in summers is a/an _______________ process.

  1. exothermic

  2. endothermic

  3. isodesmic reaction

  4. reversible reaction


Correct Option: B
Explanation:

In endothermic process, a system absorbs energy from the surroundings in the form of heat. During summers, heat absorbed from the surrounding is used in sweating to maintain the body temperature.

Which of the following modes of energy constitutes both kinetic & potential energy?

  1. Nuclear energy

  2. Rotational energy

  3. Translational energy

  4. Vibrational energy


Correct Option: D
Explanation:

It is the energy of molecules due to vibrations of their atoms to & fro. It is associated with both kinetic & potential energy as the vibrational motion is along the bond.

When the door of refrigerator is kept open the temperature of air in the room will

  1. increase

  2. decrease

  3. remain constant

  4. first decrease then increase


Correct Option: A
Explanation:

Due to isothermal contraction of the refrigerator gas, heat is liberated into the surroundings, i.e. in room. So, the temperature of the room will increase.

Which among the following is an extensive property of the system?

  1. Compressibility

  2. Enthalpy

  3. Specific enthalpy

  4. Heat capacity


Correct Option: B
Explanation:

It is defined as a measure of the total energy of a thermodynamic system including the internal energy. It is a state function and an extensive property of the system.

Which of the following thermodynamic processes occurs infinitely slowly?

  1. Isothermal process

  2. Isentropic process

  3. Isenthalpic process

  4. Quasistatic process


Correct Option: D
Explanation:

This process is an idealized model of a thermodynamic process, which takes place infinitely slowly. Practically no real process is quasistatic.

Which among the following can be excluded from the category of state function?

  1. Fugacity

  2. Exergy

  3. Particle number

  4. None of these


Correct Option: D
Explanation:

All are state functions.

Photosynthesis in plant is an example of

  1. isolated system

  2. closed system

  3. open system

  4. adiabatic system


Correct Option: C
Explanation:

This system exchange both matter and energy with the surroundings. Since plant exchanges both matter and energy with the surroundings, photosynthesis is an example of open system.

The thermodynamic state function has

  1. absolute value

  2. no absolute value

  3. zero value

  4. infinite value


Correct Option: B
Explanation:

The kinetic energy is made up of different types of movements of particles. As the number of the movements are not same, K.E. has fluctuating value & not absolute value. The thermodynamic state function; like E, H, T, etc. depends on kinetic energy. Hence they have no absolute value.

In which of the following stages, an explosion in the combustion chamber occurs?

  1. Intake stroke

  2. Compression stroke

  3. Power stroke

  4. Exhaust stroke


Correct Option: C
Explanation:

A spark is produced at the TDC by spark plug, which ignites the compressed air-fuel mixture. This creates an explosion in the combustion chamber. This force gushes the piston towards BDC.

Which of the following entropies lies at the junction of entropy and life?

  1. Tsallis entropy

  2. Residual entropy

  3. Negentropy

  4. Loop entropy


Correct Option: C
Explanation:

The negentropy of a living system is the entropy, which consigns to keep its own entropy low. It lies at the junction of entropy and life.

In thermodynamics, the term negative entropy was coined by

  1. Erwin Schrodinger

  2. Max Wien

  3. Hermann von Helmholtz

  4. William Rankine


Correct Option: A
Explanation:

Erwin Schrodinger was a theoretical biologist. He coined the term negative entropy in thermodynamics.

An intensive property is independent of the amount of material present within thermodynamic system. Which among the following is not an intensive property?

  1. Vapour pressure of a liquid

  2. Mass

  3. Boiling point

  4. Refractive index


Correct Option: B
Explanation:

It tells us about how much of the initial matter was contained in the system and how much will be left after the process is complete. It is an extensive property.

Which of the following is generally applied to biological macromolecules such as proteins and RNA?

  1. Configuration entropy

  2. Conformational entropy

  3. Geometrical frustration

  4. Disintegration


Correct Option: B
Explanation:

This entropy is associated with the physical set up of a polymer chains that allines a compact or globular state in solution. This concept is most commonly applied to biological macromolecules such as proteins and RNA.

The enthalpy of all the elements at 298K is

  1. greater than zero

  2. less than zero

  3. zero

  4. infinite


Correct Option: C
Explanation:

The enthalpy of all the elememts in standard physical state is always zero.

Fusion of ice is

  1. a process where no heat change occurs

  2. an exothermic change

  3. an endothermic change

  4. a process involving both endothermic & exothermic change


Correct Option: C
Explanation:

In an endothermic change, energy is absorbed. Heat has to be absorbed in fusion of ice to give water.

According to the Hess's Law of Constant heat Summation,

  1. work is a path function

  2. temperature affects the heat of reaction

  3. conservation of mass takes place

  4. change in enthalpy is a state function


Correct Option: D
Explanation:

Change in enthalpy does not depen upon path followed in a reaction. It only depends upon initial & final state of the reaction. So, it is a state function.

When the door of refrigerator is closed, the cooling effect inside is due to the

  1. isothermal expansion

  2. adiabatic expansion

  3. adiabatic compression

  4. isothermal compression


Correct Option: B
Explanation:

During adiabatic expansion, there is increase in volume without heat flow, in or out. Inside a refrigerator, due to the isolated system, the adiabatic expansion of refrigerator gases like freon takes place by using the heat from the gas itself. This causes lowering of temperature of the gas, i.e. cooling effect of the refrigerator.

Which among the following thermodynamic cycles is an illuminated cycle for compressing the ignition engines?

  1. The dual cycle

  2. The diesel cycle

  3. The otto cycle

  4. The Rankine cycle


Correct Option: B
Explanation:

The diesel cycle is an illuminated cycle for compressing the ignition engines (ones that don't use a spark plug).

In which of the following processes, dQ=0?

  1. Isothermal process

  2. Isobaric process

  3. Isochoric process

  4. Adiabatic process


Correct Option: D
Explanation:

In this process, no heat is exchanged into or out of a system so, dQ=0. We can control heat flow either by surrounding the system with thermally insulating material or by carrying out the process so promptly that there is not enough time for ascertainable heat flow.

During the adiabatic expansion, the temperature of the system

  1. decreases

  2. increases

  3. remains constant

  4. becomes zero


Correct Option: A
Explanation:

In adiabatic process, the net heat transfer is zero. The heat content of the system is used for the expansion of the gas, which causes a decrease in the temperature of the system.

The enthalpy change in a reaction is constant irrespective of steps involved. This statement is known as

  1. Hooke's Law

  2. Hess's Law

  3. Gauss's law

  4. Kirchhoff's Law


Correct Option: B
Explanation:

Hess's Law states that the heat evolved or absorbed in a chemical process is the same whether the process takes place in one or in several steps.

Which of the following is a wrong statement regarding the postulates of kinetic theory of gases?

  1. The molecular density of the gas remains unchanged throughout the gas.

  2. The molecules of gases possess potential energy & kinetic energy.

  3. The molecules of a gas obey Newton's laws of motion.

  4. The collisions are perfectly elastic in nature.


Correct Option: B
Explanation:

The molecules of gases do not exert any force of attraction or repulsion on each other, except at the time of collision. Thus, the molecules do not have any potential energy. Their energy is only kinetic energy.

During isothermal expansion of ideal gas its

  1. internal energy increases

  2. enthalpy increases

  3. enthalpy remains constant

  4. enthalpy reduces to zero


Correct Option: B
Explanation:

Enthalpy is a thermodynamic function of a system. It is equivalent to the sum of the internal energy of the system plus the product of its volume multiplied by the pressure exerted on it by its surroundings. Since heat is absorbed from the surroundings therefore the enthalpy of the ideal gas increases.

- Hide questions