Bond enthalpies - class-XII
Description: bond enthalpies | |
Number of Questions: 58 | |
Created by: Rani Rajan | |
Tags: how far? how fast? chemistry energetics and thermochemistry chemical thermodynamics enthalpy changes thermodynamics |
The enthalpies of combustion of carbon and carbon monoxide are -393.5 KJ and -283 KJ respectively the enthalpy of formation of carbon monoxide is :
The incorrect statement is :
The enthalpy of tetramerization of $X$ in gas phase $(4X(g)\rightarrow { X } _{ 4 }(g))$ is $-100\ kJ/mol$ at $300\ K$. The enthalpy of vaporisation for liquid $X$ and ${X} _{4}$ are respectively $30\ kJ/mol$ and $72\ kJ/mol$ respectively.
$\Delta S$ for tetramerization of $X$ in liquid phase is $-125\ J/K mol$ at $300\ K$.
What is the $\Delta G$ at $300\ K$ for tetramerization of $X$ in liquid phase?
Heat of formation of $2$ moles of ${NH} _{3}(g)$ is $-90kJ$; bond energies of $H-H$ and$N-N$ bonds are $435kJ$ and $390kJ$ ${mol}^{-1}$ respectively. The value of the bond energy of $N\equiv N$ will be:
The standard enthalpy of formation of ${NH} _{3}$ is $-46kJ{ mol }^{ -1 }$. If the enthalpy of formation of ${H} _{2}$ from its atoms is $-436kJ{ mol }^{ -1 }$ and that of ${N} _{2}$ is $-712kJ{ mol }^{ -1 }$, the average bond enthalpy of $N-H$ bond in ${NH} _{3}$ is:
Calculate $ \Delta { H }^{ o }$ of the reaction:
$H _{2}+Cl _{2}\rightarrow 2HCl+44\ K.Cal$. Heat of decomposition of $HCl$ is:
Two moles of an ideal gas expended isothermally and reversibly from 1 litre to 10 litre at 300 K. The enthalpy change (in kJ) for the process is:
The standard enthalpies of n-pentane, isopentane and neopentane are $-35.0,\ -37.0$ and $-40.0$ $K \ cal/mole$ respectively. The most stable isomer of pentane in terms of energy is ____________.
Calculate P - CI bond enthalpy
Given : $\Delta f H(PCl _3, g) = 306 KJ/mol;$ $\Delta H _{atomization} (P, s) = 314 KJ / mol;$
$\Delta f H (Cl, g) = 121 KJ / mol$
Given that bond energies of H-H and Cl-Cl are $430$ and $240$ kJ $mol^{-1}$ respectively and $\Delta _fH$ for HCl is $-90$kJ $mol^{-1}$. Bond enthalpy of HCl is?
Choose the correct order of lattice enthalpy of $LiCl,\ LiF,\ NaCl$ and $NaF$ :
$100 ml$ of $0.2\ M\ H _{2}SO _{4}$ is reacted with $100\ ml$ of $0.5\ M\ NaOH$ solution. what is the normality of the solution
Calculate the average Bond energy of O-F bond in the following reaction :-
$OF _{2(g)}\rightarrow O _{(g)}+2F _{(g)}$
Given :
$OF _{2(g)}\rightarrow OF _{(g)}+F _{(g)}$; $\Delta H$=201 kJ
$OF _{(g)}\rightarrow O _{(g)}+F _{(g)}$; $\Delta H$=199 kJ
Which one of the following statement(s) is/are true?
The bond energy in $kcal : mol^{-1}$ of a $C-! ! ! -C$ single bond is approximately :
Bond energies can be obtained by using the following relation:
$\Delta H$(reaction) $=\sum$ Bond energy of bonds, broken in the reactants $- \sum$ Bond energy of bonds, formed in the products
a. greater is the bond length, lesser is the bond energy
b. bond energy increases with the bond multiplicity
c. bond energy increases with the electronegativity difference between the bonding atoms.
Bond energies can be obtained by using the following relation:
$\Delta H(reaction) =\sum$ Bond energy of bonds, broken in the reactants $- \sum$ Bond energy of bonds, formed in the products.
Bond energy depends on three factors:
b. bond energy increases with the bond multiplicity
c. bond energy increases with the electronegativity difference between the bonding atoms. Which among the following sequences is correct about the bond energy of $C-C$, $C=C$, and $C\equiv C$ bonds?
Bond energies can be obtained by using the following relation:
$\Delta H(reaction) =\sum$ Bond energy of bonds, broken in the reactants $- \sum$ Bond energy of bonds, formed in the products
Bond energy depends on three factors:
a. greater is the bond length, lesser is the bond energy
b. bond energy increases with the bond multiplicity
c. bond energy increases with the electronegativity difference between the bonding atoms.Bond energy of different halogen molecules will lie in the sequences of:
Bond energies can be obtained by using the following relation:
$\Delta H(reaction) =\sum$ Bond energy of bonds, broken in the reactants $- \sum$ Bond energy of bonds, formed in the products
a. greater is the bond length, lesser is the bond energy
b. bond energy increases with the bond multiplicity
c. bond energy increases with the electronegativity difference between the bonding atoms.In $CH _4$ molecule.
${ \Delta H } _{ r }={ X } _{ 1 }+{ 3X } _{ 2 }-{ 2X } _{ 3 }$
The bond energy is the energy required to:
The enthalpy change for the following reaction is 514 kJ. Calculate the average Cl - F bond energy.
$ClF _3(g)\rightarrow Cl(g)+3:F(g)$
$AB,\, A _2$ and $B _2$ are diatomic molecules. If the bond enthalpies of $A _2,\, AB\, &\, B _2$ are in the ratio 1 : 1 : 0.5 and enthalpy of formation of AB from $A _2$ and $B _2$ is - 100 kJ/mol$^{-1}$. What is the bond enthalpy of $A _2$.
From the following thermochemical equations:
$C _2H _4 \rightarrow C _2H _6; \triangle H = -32.7 kcal$
$C _6H _6+3H _2 \rightarrow C _6H _{12}; \triangle H= -49.2kcal$
Calculate resonance energy of benzene.
Energy required to dissociate $4g$ of gaseous hydrogen into free gaseous atoms is $208\ Kcal$ at ${25}^{o}C$. The bond energy of $H-H$ bond will be:
The dissociation energy of ${CH} _{4}$ is $400kcal$ ${mol}^{-1}$ and that of ethane is $670kcal$ ${mol}^{-1}$. The C-C bond energy is:
The bond dissociation energy of $C-H$ in ${CH} _{4}$ from the equation
$C(g)+4H(g)\rightarrow {CH} _{4}(g);\Delta H=-397.8kcal$ is:
Given that $\Delta {H} _{f}(H)=218kJ/mol$, express the $H-H$ bond energy in $kcal/mol$:
The $S-S$ bond energy is:
Using the data provided, calculate the multiple bond energy ($kJ{ mol }^{ -1 }$) of $C\equiv C$ bond in ${C} _{2}{H} _{2}$. That energy is (take the bond energy of a $C-H$ bond as $350kJ{ mol }^{ -1 }$):
$2C(s)+{ H } _{ 2 }(g)\longrightarrow { C } _{ 2 }{ H } _{ 2 }(g);\Delta { H }^{ }=225kJ{ mol }^{ -1 }$
$2C(s)\longrightarrow 2C(g);\Delta { H }^{ }=1410kJ{ mol }^{ -1 }\quad $
${H} _{2}(g)\longrightarrow 2H(g);\Delta { H }^{ }=330kJ{ mol }^{ -1 }\quad $
Given that, bond energies of $H-H$ and $Cl-Cl$ ar $430kJ/mol$ and $240kJ/mol$ respectively. $\Delta {H} _{f}$ for $HCl$ is $-90kJ/mol$. Bond enthalpy of $HCl$ is:
If values of $\Delta { H } _{ f }^{ o }$ of $ICl(g),\, Cl(g),\, I(g)$ are respectively $17.57,\,121.34,\,106.96$ J mol $^{-1}$. The value of $I-Cl$ (bond energy) in J mol $^{-1}$ is:
The bond dissociation energies for single covalent bonds formed between carbon and $A,B,C,D$ and $E$ atoms are:
Bond | Bond energy $kcal{ mol }^{ -1 }$ |
---|---|
(i) $C-A$ | $240$ |
(ii) $C-B$ | $382$ |
(iii) $C-D$ | $276$ |
(iv) $C-E$ | $486$ |
This indicates that the smallest atom is:
Given the bond dissociation energies below (in kcal/mole), estimate the $\Delta { H }^{ o }$ for the propagation step
${ \left( { CH } _{ 3 } \right) } _{ 2 }CH+{ Cl } _{ 2 }\longrightarrow { \left( { CH } _{ 3 } \right) } _{ 2 }CHCl+Cl$
${ CH } _{ 3 }{ CH } _{ 2 }{ CH } _{ 2 }-H$ | $98$ |
---|---|
${ \left( { CH } _{ 3 } \right) } _{ 2 }CH-H$ | $95$ |
$Cl-Cl$ | $58$ |
$H-Cl$ | $103$ |
${ CH } _{ 3 }{ CH } _{ 2 }{ CH } _{ 2 }-Cl$ | $81$ |
${ \left( { CH } _{ 3 } \right) } _{ 2 }CH-Cl$ | $80$ |
Given the bond dissociation energies below (in $kcal$ /mole), estimate the $\triangle H^{\circ}$ for the propagation step
$(CH _{3}) _{2} CH + Cl _{2}\rightarrow (CH _{3}) _{2} CHCl + Cl$
$CH _{3} CH _{2}CH _{2} - H \ 98$
$(CH _{3}) _{2} CH - H \ 95$
$Cl - Cl\ 58$
$H-Cl\ 103$
$CH _{3}CH _{2}CH _{2} - Cl\ 81$
$(CH _{3}) _{2} CH - Cl \ 80$
If the bond energies of $H-H,\ Br-Br$ and $H-Br$ are 433, 192 and 364 $kJ \, mol^{-1}$ respectively, $\Delta H$ for the reaction $H _{2(g)}+BR _{2(g)}\rightarrow 2HBr _{(g)}$ is:
$NO(g) + O _{3}(g)\rightarrow NO _{2}(g) + O _{2}(g)\ triangle H = -198.9\ kJ/mol$
$O _{3}(g) \rightarrow 3/2\ O _{2}(g) \ \triangle H = -142.3\ kJ/mol$
$O _{2}(g) \rightarrow 2O(g) \ \triangle H = +495.0\ kJ/mol$
$NO(g) + O(g)\rightarrow NO _{2}(g)$
$H-H$ bond energy: $431.37kJ\quad { mol }^{ -1 }$
$C=C$ bond energy: $606.10kJ\quad { mol }^{ -1 }\quad $
$C-C$ bond energy: $336.49kJ\quad { mol }^{ -1 }$
$C-H$ bond energy: $410.50kJ\quad { mol }^{ -1 }$
Enthalpy for the reaction will be:
If, $C(s)+2H _2(g)\rightarrow CH _4(g); \triangle H= -X _1 kcal$
$C(g)+4H(g)\rightarrow CH _4(g); \triangle H = -X _2 kcal$
$CH _4(g) \rightarrow CH _3(g)+H(g); \triangle H = +Y kcal$
The average bond energy of C-Hbond in kcal $mol^{-1}$ is :
Which is the correct order of bond energy of single, double and triple bonds between carbon atoms?
Bond energies of H - H and CI - CI are $430 \ kJ mol^{-1}$ and $242 \ kJ mol^{-1}$ respectively. $\Delta H _f$ for HCl is $91 \ kJ mol^{-1}$ . What will be the bond energy of H - Cl bond (per mole value)?
Which of the following relationships is not correct?
Bond energies of some bonds are given below:
Cl-Cl = 242.8 kJ $mol^{-1}$, H-Cl = 431.8 kJ $mol^{-1}$,
O-H = 464 kJ $mol^{-1}$, O=O = 442 kJ $mol^{-1}$
Using the B.E.s given, calculate $\Delta H$ for the given reaction: $2Cl _2 + 2H _2O \rightarrow 4HCl + O _2$
The enthalpy of dissociation of $PH _3$ is $954$ kJ/mol and that of $P _2H _4$ is $1.485$ MJ/mol. What is the bond enthalpy of $P-P$ bond?
Amount of energy required to break a specific covalent bond is called:
The bond energy of $H _2$ is $104.3 : kcal : mol^{-1}$. It means that:
The average, $S - F$ bond energy in $SF _6$ if the $\Delta H^{\circ} _f$ value are $-1100, +275$ and $+80 kJ/mol$ respectively for $SF _6(g),$ S(g) and F(g) is
Bond energy of hydrogen gas is $-433 kJ$. How much is the bond dissociation energy of $0.5 mole$ of hydrogen gas?
A vessel contains 100 litres of a liquid x. Heat is supplied to the liquid in such a fashion that, heat gives a change in enthalpy. The volume of the liquid increases by 2 litres. If the external pressure is one atm, and 202.6 Joules of heat supplied, then [U $\rightarrow$ total internal energy] :
Enthalpy of polymerisation of ethylene, as represented by the reaction, $ nCH _2 = CH _2 \rightarrow {(-CH _2- CH _2-)} _n $ is -100kJ per mole of ethylene.Given bond enthalpy of $ C = C $ bond is 600 kJ$ mol^{-1} $ , enthalpy of $ C - C $ bond (in kJ mol) will be :
The first and second dissociation constant of an acid ${ H } _{ 2 }A$ are $1.0\ \times \ { 10 }^{ -5 }$ and $5.0\ \times \ { 10 }^{ -10 }$ respectively. The over all dissociation constant of the acid will be:
$\triangle H _{f} (C _{2}H _{4}) = 12.5\ kcal$
Bond energy of $H _{2} = 104.3\ kcal$
Dissociation of water takes place in two steps:
$H _2O \rightarrow H^+ + OH^-$; $\Delta H$ = +497.8 kJ
$OH^- \rightarrow H^+ + O^{2-}$; $\Delta H$ = +428.5 kJ
What is the bond energy of O - H bond?
The dissociation energy of $CH _4$ and $C _2H _6$ are respectively 360 and 620 kcal /mole. the bond energy $C-C$ is:
The heat of neutralisation of $HCl$ by $NaOH$ is -55.9 KJ/mole. If the heat of neutralisation of $HCN$ by$ NaOH$ is -12.1 KJ/mole, the energy of dissociation of $HCN$ is: