0

Extraction of metal from concentrated ore - class-XII

Description: extraction of metal from concentrated ore
Number of Questions: 78
Created by:
Tags: metallurgy general principles of metallurgy production of metals chemistry general principles and processes of isolation of elements principles of metallurgy
Attempted 0/75 Correct 0 Score 0

Which of the following sulphides when  heated strongly in air gives the corresponding metal without undergoing separate reduction of oxide?

  1. $Cu _2S$

  2. $FeS$

  3. $HgS$

  4. $ZnS$


Correct Option: B
Explanation:

$2Cu _2S+3O _2\longrightarrow 2Cu _2O+2SO _2$

$2ZnS+3O _2\longrightarrow 2ZnO+2SO _2$
$2PbS+3O _2\longrightarrow 2PbO+2SO _2$
$2HgS+3O _2\longrightarrow 2HgO+2SO _2$
$FeS+O _2\longrightarrow Fe+SO _2$
$FeS$ when heated directly in air gives $Fe$. 

Which of the following reactions show the process of smelting?

  1. $2PbO + PbS \rightarrow 3Pb + SO _2$

  2. $2Na[Au(CN) _2]+Zn \rightarrow Na _2[Zn(CN) _4]+2Au$

  3. $PbO+C\rightarrow Pb + CO$

  4. $2HgS + 3O _2\rightarrow 2HgO+2SO _2$


Correct Option: C
Explanation:

Carbon reduction occurs in smelting from oxide ore. $PbO+C\longrightarrow Pb+CO$

Fill in the blanks with the correct choice.
The undesired impurities present in the ores are called (i). To remove the volatile impurities from the ore, the (ii) process is carried out. Flux combines with non-fusible impurities to form (iii). $CaO$ acts as a (iv) flux.

  1. (i) - gangue, (ii) -roasting, (iii) - slag, (iv) -acidic

  2. (i) - gangue, (ii) - calcination, (iii) - slag, (iv) - basic

  3. (i) - anode mud, (ii) - leaching, (iii) - matrix, (iv) -acidic

  4. (i) - gangue, (ii) -roasting, (iii) - solution, (iv) -acidic


Correct Option: B
Explanation:
$(i)$ The undesired impurities present in the ores are called gangue.
$(ii)$ To remove the volatile impurities from the ore calcination is carried out.
$(iii)$ Flux combines with non-fusible impurities to form slag.
$(iv)$ $CaO$ acts as basic flux.

Extraction of chlorine from brine is based on:

  1. reduction

  2. displacement

  3. oxidation

  4. evaporation


Correct Option: C
Explanation:
In the extraction of chlorine by electrolysis of brine, oxidation of ${ Cl }^{ - }$ ion to chlorine gas occurs.
$2{ Cl }^{ - }+2{ H } _{ 2 }O\rightarrow 2{ OH }^{ - }+{ H } _{ 2 }+{ Cl } _{ 2 }$

Which of the following is reactions is an example of autoreduction? 

  1. $Fe _3O _4+4CO\rightarrow 3Fe+4CO _2$

  2. $CuO+C\rightarrow 2Cu+CO$

  3. $Cu^{2+} _{(aq)}+Fe _{(s)}\rightarrow Cu _{(s)}+Fe^{(2+)} _{(aq)}$

  4. $Cu _2O+\frac{1}{2}Cu _2S\rightarrow 2Cu+\frac{1}{2}SO _2$


Correct Option: D
Explanation:

The sulphide ores of certain less electropositive metals like those of Hg, Pb, Cu, etc. when heated in air bring about the conversion of a part of the sulphide ore to oxide or sulphate which then reacts with the remaining sulphide to give the matal and $SO _2$. No external reducing agent is used in this process.
$2Cu _2S+3O _2\rightarrow 2Cu _2O+3SO _2$
$2Cu _2O+Cu _2S\rightarrow 6Cu+ SO _2$

In the process of extraction of gold, Roasted gold ore$+CN^- _{(aq)}+H _2O\overset{O _2}{\rightarrow}[X]+[OH^-]$, $[X]+Zn\rightarrow [Y]+Au$
Identify the complexes [X] and [Y].

  1. $[Au(CN) _2]^-, [Zn(CN) _4]^{2-}$

  2. $[Au(CN) _4]^{3-}, [Zn(CN) _4]^{2-}$

  3. $[Au(CN) _2]^{2-}, [Zn(CN) _6]^{4-}$

  4. $[Au(CN) _4]^-, [Zn(CN) _4]^{2-}$


Correct Option: A
Explanation:
$4Au+8{ CN }^{ - }+2{ H } _{ 2 }O+{ O } _{ 2 }\longrightarrow 4{ \left[ Au{ \left( CN \right)  } _{ 2 } \right]  }^{ - }+4{ OH }^{ - }$
$2{ \left[ Au{ \left( CN \right)  } _{ 2 } \right]  }^{ - }+Zn\longrightarrow 2Au+{ \left[ Zn{ \left( CN \right)  } _{ 4 } \right]  }^{ 2- }$
It is Mc-Arthur process. Here
$X={ \left[ Au{ \left( CN \right)  } _{ 2 } \right]  }^{ - }$ & $Y={ \left[ Zn{ \left( CN \right)  } _{ 4 } \right]  }^{ 2- }$

The major step involved in extraction of a metal after its ore is :

  1. concentration

  2. reduction

  3. purification

  4. all of these


Correct Option: D
Explanation:

 The three steps involved in extraction are:
1) Concentration of the ore to remove impurities.
2) Reduction of the ore to get the metal.
3) Purification of the ore.

Which of the following is not a method of extraction of metals?

  1. Enrichment of ore

  2. Refining

  3. Magnetic separation

  4. None of the above


Correct Option: D
Explanation:

Refining and magnetic separation are methods of extraction of metals .Enrichment of ore is also known as concentration of ore. It means purification of ore.

Process of removal of gangue from the ore are based on:

  1. differences between physical and chemical properties of the gangue and the ore

  2. difference between densities of gangue and ore

  3. difference between melting point between of gangue and ore

  4. all of the above


Correct Option: D
Explanation:

Impurities are removed prior to the extraction of metal. The process used for removal of gangue from the ore are based on the differences between physical and chemical properties of the gangue.

What will happen during roasting?

  1. The sulphide ores are converted into oxides

  2. The oxide ores are converted into sulphides

  3. The sulphide ores are converted into carbonates

  4. The oxide ores are converted into carbonates.


Correct Option: A
Explanation:

During roasting, the sulphide ores are converted into oxides by heating strongly in excess of air.
$ZnS + 3O _2 \rightarrow 2ZnO + 2SO _2$

Which if the following is a common reducing agent for extracting metals from ore?

  1. $CO$

  2. Carbon

  3. Hydrogen

  4. All of the above


Correct Option: D
Explanation:

Reduction is the process of removal of oxygen for extraction of metals from their oxide ores. The common reducing agents used for reduction of metal oxides are: Carbon monoxide,  Carbon, Hydrogen.

During electrolysis, electrons are being added directly to the metal ions at the ___________.

  1. anode

  2. cathode

  3. both $A$ and $B$

  4. none of the above


Correct Option: B
Explanation:

During electrolysis, electrons are being added directly to the metal ions at the cathode (the negative electrode). The downside (particularly in the aluminum case) is the cost of the electricity. An advantage is that it can produce very pure metals.

Which of the following technique uses high temperature to convert ore into raw metals?

  1. Pyrometallurgy

  2. Hydrometallurgy

  3. Both a and b

  4. None of above


Correct Option: A
Explanation:

After the ore is mined, the metals must be extracted, usually by chemical or electrolytic reduction. Pyrometallurgy uses high temperatures  to convert ore into raw metals, while hydrometallurgy employs aqueous treatment for the same purpose.

Metals more reactive than carbon are usually extracted by_________.

  1. Pyrolysis

  2. Electrolysis

  3. Fractional distillation

  4. Filteration


Correct Option: B
Explanation:

Metals more reactive than carbon are usually extracted by electrolysis. Electrolysis is the process of breaking down a compound using electrical energy and is needed to extract  the most reactive metals. 

What is the most common type of electrometallurgical processes to obtain pure metal?

  1. Electro-refining

  2. Electrowinning

  3. Both a and b

  4. Oxidation


Correct Option: C
Explanation:

The most common types of electrometallurgical processes are electrowinning and electro-refining. Electrowinning is an electrolysis process used to recover metals in aqueous solution, usually as the result of an ore having undergone one or more hydrometallurgical processes. Electro-refining is used to dissolve an impure metallic anode and produce a high purity cathode. 

Which of the following is a physical mean for concentration of ore?

  1. Using sodium hydroxide

  2. Using electrolysis

  3. Froth flotation method

  4. None of above


Correct Option: C
Explanation:

In many cases, it is possible to separate the metal compound from unwanted rocky material by physical means. A common example of this involves froth flotation. In this method, the unwanted object binds with air and comes on the surface as bubbles.

In electrolytic refining of any metal impure metal is taken as ...............

  1. anode

  2. cathode

  3. solution

  4. both B and C


Correct Option: A
Explanation:

In electrolytic refining, impure metal is of positive charged anode and pure metal is of negative charged cathode.

Heating the ore is in the presence of air is ?

  1. roasting

  2. melting

  3. calcination

  4. none of these


Correct Option: A
Explanation:

Heating of ore in the presence of oxygen is called roasting. It is a Pyrochemical Process. 

Eg: $2ZnS(s) + 3O _2 (g) \rightarrow 2ZnO (s) + 2SO _2 (g) $
      Zinc Blende 

The order of processes involved in the dressing of an ore are :
(i) grinding and crushing           (ii) hand picking                (iii) pulverization

  1. (i), (ii), (iii)

  2. (i), (iii), (ii)

  3. (ii), (iii), (i)

  4. (ii), (i), (iii)


Correct Option: D
Explanation:

Dressing of ore can be carried out by first handpicking followed by crushing and grinding and then pulverization.


Hence, the correct option is $(D)$

Identify the oxide ore among the following :

  1. Copper pyrites

  2. Copper glance

  3. Siderite

  4. Limonite


Correct Option: D
Explanation:

Formula of Limonite is $F _eO(OH)\cdot nH _2O$. It is an oxide ore.

The process of carrying out the reduction of metal oxides by heating with coke is termed as :

  1. Roasting

  2. Smelting

  3. Zone refining

  4. Ore dressing


Correct Option: B
Explanation:

Smelting is the process where heat is applied to ore to extract the base metal, using a reducing agent. So, it is used to carry out reduction of metal oxides to metal by heating with coke.

The above process is:

$HgS\xrightarrow{O _2}HgS.HgO$
                         $\downarrow\Delta$
                        $Hg$ 

  1. auto oxidation

  2. self reduction

  3. thermal reduction

  4. none of the above


Correct Option: B
Explanation:

Cinnabar ($HgS$), when heated with a current of $O _2$ gets reduced to $Hg$ without the need of any additional reducing agent. The process involved is known as self reduction

Which of the following metal oxides are reduced by CO?

  1. ZnO

  2. Fe$ _2$O$ _3$

  3. CaO

  4. Al$ _2$O$ _3$


Correct Option: A,B
Explanation:

Oxides of highly reactive metals cannot be reduced by $CO$. Hence $CaO$ and $Al _2O _3$ are not reduced by $CO$ and both $ZnO $ and $Fe _2O _3$ are reduced by $CO$

In which of the following chemical leaching is used either in the extraction of metal or in the concentration of ore?

  1. Argentite

  2. Bauxite

  3. Alluvial sand containing gold

  4. All of these


Correct Option: A

Which one of the following statements is incorrect about rock salt type?

  1. It has fcc arrangement of $\mathrm { Na } ^ { + }$

  2. Nat and Cl-ions have a co-ordination number of $6:6$

  3. A unit cell of $NaCl$ consists of four $NaCl$ units

  4. All halides of alkali metals have rock-salt type structure


Correct Option: D
Explanation:

The alkali halides crystallize in the NaCl structure also known as rock-salt structure (rock salt is the mineral form of sodium chloride); exceptions being CsCl, CsBr, and CsI, which crystallize in the CsCl structure. In the NaCl structure (face-centered cubic lattice), each cation is surrounding by six anions, and vice versa (coordination number of 6). In the CsCl structure, each cation is surrounded by eight anions and vice versa (coordination number of 8).

Option D is incorrect

The extraction of metals from oxide ores may involve:

  1. reduction with carbon

  2. reduction with aluminium

  3. electrolyte reduction

  4. reduction with CO


Correct Option: A,B,C,D
Explanation:

These are the methods for extraction of metals from oxide ores:
Carbon reduction, involving reduction with CO or C
Self reduction
Thermite reduction, which employs Al
Electrolytic reduction.

The advantage(s) of using carbon to reduced a number of oxides and other compounds are :

  1. easy availability of coke.

  2. low cost of carbon.

  3. tendency of carbon to show catenation..

  4. presence of carbon lowers the melting point of the oxide.


Correct Option: A,B
Explanation:

The advantage(s) of using carbon to reduced a number of oxides and other compounds are
 (i) easy availability of coke.
 (ii) low cost of carbon.
 (iii) exothermic nature of reaction which requires less energy to keep the furnace hot.


Hence, A and B are the correct options. 

The extraction of metals from oxide ores involve :

  1. reduction with carbon

  2. reduction with aluminium

  3. electrolyte reduction

  4. reduction with $CO$


Correct Option: A,B,C,D
Explanation:

During extraction of metals from oxide ores, the reduction of metal ore to crude metal can be carried out by using several methods such as pyrometallurgy, hydrometallurgy and electrometallurgy. Various reducing agents such as carbon, hydrogen, aluminum or other metals can be used. CO also reduces metal ores to crude metals.

Aluminothermy used for the spot welding of large iron structures is based upon the fact that :

  1. As compared to iron, aluminium has greater affinity for oxygen.

  2. As compared to aluminium, iron has greater affinity for oxygen.

  3. Reaction between aluminium and oxygen is endothermic..

  4. Reaction between iron oxide and aluminium is exothermic.


Correct Option: A,D
Explanation:

Aluminothermy used for the spot welding of large iron structures is based upon two facts 
(i) As compared to iron, aluminum has greater affinity for oxygen. hence, aluminum acts are reducing agent.
(ii) Reaction between iron oxide and aluminum is exothermic. High temperature is involved in the reaction.
Aluminum reduces iron oxide to iron. 

$Fe _2O _3 + 2 Al \rightarrow 2 Fe + Al _2O _3$

Oxides of the various metals are converted into metal by heating but not in :

  1. $Ag _2O$

  2. CuO

  3. HgO

  4. all are correct


Correct Option: B
Explanation:

Oxides of various metal oxides are converted into metals on heating but CuO (copper oxide) does not not converted into metal on heating but by reaction with Cu2S.

CuO + Heat$ \rightarrow$ no reaction
So, answer is B.

The methods chiefly used for the extraction of lead and tin from their ores are respectively _________________.

  1. self reduction and carbon reduction

  2. self reduction and electrolytic reduction

  3. carbon reduction and self reduction

  4. cyanide process and carbon reduction


Correct Option: A
Explanation:

The methods chiefly used for the extraction of lead and tin from their ores are respectively self reduction and carbon reduction. Self reduction for lead is as follows.
$2PbS+3O _2 \rightarrow 2PbO+2SO _2 \uparrow$
$PbS+2O _2 \rightarrow PbSO _4$
$2PbO + PbS \rightarrow 3Pb+SO _2 \uparrow$
$PbSO _4+PbS \rightarrow 2Pb+2SO _2 \uparrow$
Carbon reduction for tin is as follows.
$SnO _2+2C \rightarrow Sn+2CO \uparrow$

Which will not give metal on heating ?

  1. $Ag _2CO _3$

  2. $ZnCO _3$

  3. $HgO$

  4. $CuO$


Correct Option: B,D
Explanation:
A) $Ag _2CO _3(s)\rightarrow 2Ag(s) + CO _2(g) + O _2(g)$ on heating gives Ag(metal).
B) $ZnCO _3(s)\rightarrow ZnO(s) + CO _2(g)$ on heating  do not give metal it gives ZnO(zinc oxide).
C) $2HgO(heat)\rightarrow 2 Hg + O _2$ on heating gives Hg(metal).
D) CuO when heated in presence of sulfuric acid it also gives CuO again, hence CuO on heating do not give metal.
Hence option B and D are correct.

Which of the following metal oxide(s) gives metal and oxygen on heating ? 

  1. $ NaNO _3 $

  2. $ KNO _3 $

  3. $ Hg(NO _3) _2 $

  4. $ AgNO _3 $


Correct Option: C,D
Explanation:

$ AgNO _3 \xrightarrow{\Delta} Ag + \frac {1}{2} O _2  +NO _2 $

$ Hg(NO _3) _2 \xrightarrow{\Delta}  Hg + O _2 +2NO _2 $

$4KNO _3(s)\xrightarrow{\Delta} 2K _2O(s)+2N _2(g)+5O _2(g)$

$4NaNO _3(s)\xrightarrow{\Delta} 2Na _2O(s)+2N _2(g)+5O _2(g)$

Selection of temperature to carry out a reduction process depends so as to make:

  1. $\Delta G$ negative

  2. $\Delta G$ positive

  3. $\Delta H$ negative

  4. $\Delta H$ positive


Correct Option: A
Explanation:

When $\Delta$G is negative, a process or chemical reaction proceeds spontaneously in the forward direction and similar condition is required for a reduction process also. 

Auto reduction process is used for the extraction of:

  1. Cu

  2. Hg

  3. Pb

  4. Al


Correct Option: A,B,C
Explanation:
Auto-reduction or air reduction is a very popular reaction in metallurgy. 

It is a process in which sulphide ores of less electropositive metals like Hg, Pb, Cu etc., are heated in the air so as to convert part of the ore into oxide or sulphate which then reacts with the remaining of sulphide ore in absence of air to give the metal and sulphur dioxide.

In which of the following isolations is no reducing agent required?

  1. Iron from haematire

  2. Tin from tin oxide

  3. Mercury from cinnabar

  4. Zine from zinc blende


Correct Option: C
Explanation:

Cinnabar ore is relatively concentrated, it can be processed directly without any intermediate steps to remove waste material and without requirement of a reducing agent. 

The extraction of metals from oxide ores involve(s) :

  1. reduction with carbon

  2. reduction with aluminium

  3. electrolytic reduction

  4. reduction with CO


Correct Option: A,B,C,D
Explanation:

During extraction of metals from oxide ores, the reduction of metal ore to crude metal can be carried out by using several methods such as pyrometallurgy, hydrometallurgy and electrometallurgy. Various reducing agents such as carbon, hydrogen, aluminum or other metals can be used. CO also reduces metal ores to crude metals.

$H _2$ is not widely used as the reducing agent in metallurgic process because :

  1. many metals react with $H _2$ at elevated temperature forming hydrides

  2. there is a risk of explosion from $H _2$ and $O _2$ present in the air

  3. reducing power of $H _2$ does not increase with temperature

  4. reducing power of $H _2$, increases with temperature


Correct Option: A,B,C
Explanation:

$H _2$ is not widely used as the reducing agent in metallurgic process because metals react with $H _2$ at elevated temperature forming hydrides. When $H _2$ and $O _2$ present in the air are combined it will be explosive. Reducing power of $H _2$ does not increase with temperature, which is essential in metallurgy.

Lead obtained from galena ore (PbS) by air reduction or carbon reduction process contains base metal (Cu, Bi, As, Sn, Zn) as impurities. Gelatin acts as an addition agent in the electrolysis of Pb. In the presence of gelatin, Pb becomes :

  1. hard and brittle

  2. soft and rubbery

  3. smooth and uniform

  4. only brittle


Correct Option: C
Explanation:
Lead obtained contains impurities like $Cu, Sb, Sn, As, Ag, Au, etc.$ which make it hard. During electrolytic refining of lead, the electrolyte $(PbSiF _6+H _2SiF _6)$ is mixed with a little gelatin. Gelatin is added for smooth and uniform deposition of lead in this process. 

Hence, the correct option is (C).

Which of the following metal oxides are reduced by self reduction method?

  1. $Cu _2O$

  2. $PbO$

  3. $HgO$

  4. $CaO$


Correct Option: A,B,C
Explanation:

Self-reduction process:  This process is also called auto reduction process or air reduction process. 


The sulphide ores of less electropositive metals like Hg, Pb, Cu etc. are heated in the air as to convert part of the ore into oxide or sulphate which then reacts with the remaining sulphide ore to give the metal and sulphur dioxide. 


No external reducing agent is used in this process.

Hence options A,B & C are correct options.

Pb is a very important element of carbon family. It forms a number of compounds which are very useful in industries. The process of removal of base metals (Cu, Sn, Bi, As) from lead is called:

  1. softening process

  2. liquation

  3. parke's process

  4. cupellalion


Correct Option: A
Explanation:

For the removal of base metals the impure bullion is charged to a softening furnace whereby oxidation these elements form drosses or slags and, with some lead, are skimmed from the bath. This is the softening process. 

Aquaregia is ___ part conc. HCI and ___ part conc. $HNO _3$.

  1. one,three

  2. one,one

  3. three,three

  4. three,one


Correct Option: D
Explanation:

Aqua regia is three parts conc. $ HCI$ and one part conc. $HNO _3$.


$HNO _3 + 3HCl \rightarrow NOCl + 2H _2O + 2CI$

So, the correct option is $D$

The main source of lead is PbS. It is converted to Pb by:- 


(i) ${PbS\xrightarrow[\Delta]{air }PbO+SO _2\xrightarrow[\Delta]{C}Pb+CO _2}$


(ii) ${PbS\xrightarrow[\Delta]{air }PbO+PbS\xrightarrow[]{\Delta}Pb+SO _2}$ 

Self reduction process is:
  1. i

  2. ii

  3. both

  4. none


Correct Option: B
Explanation:

Self reduction process of Pb is

$PbS + 2PbO \rightarrow   3Pb + SO _2$
so (ii) is self reduction process.

Which of the following reduction processes are correct?

  1. ${Fe _2O _3+C\overset{Reduction}{\rightarrow}Fe}$

  2. ${ZnO+C\overset{Reduction}{\rightarrow}Zn}$

  3. ${SnO _2+C\overset{Reduction}{\rightarrow}Sn}$

  4. ${PbO+C\overset{Reduction}{\rightarrow}Pb}$


Correct Option: A,B,C,D
Explanation:

Reduction is loss of oxygens.
In all the above reactions the metal oxides are reduced to metals by the elimination of oxygens,so all are reduction ractions.
Hence options A,B,C & D are correct.

Which one of the following metals can not be extracted by using Al as a reducing agent ________________.

  1. $\displaystyle Na$ from $\displaystyle { Na } _{ 2 }O$

  2. $\displaystyle Cr$ from $\displaystyle { Cr } _{ 2 }{ O } _{ 3 }$

  3. $\displaystyle Mn$ from $\displaystyle { MnO } _{ 2 }$

  4. $\displaystyle Fe$ from $\displaystyle { Fe } _{ 2 }{ O } _{ 3 }$


Correct Option: A
Explanation:

As sodium  (alkali metal) is more reactive than Al so it cannot be extracted from $Na _2O$ by using Al as a reducing agent.

Metals can be recovered from their ores by chemical methods.

  1. True

  2. False


Correct Option: A
Explanation:

Metals can be recovered from their ores by following chemical methods:

Calcination, Leaching, Roasting etc.

Sequence the following steps involved generally in the extraction of a metal in pure form from its ore.
(a) The metal obtained from its oxide require further purification for end use.
(b) The ore should be converted to its oxide form.
(c) The ore is beneficial to us if it is handpicked then metal crushed and ground, and later subjected to pulverization as per the requirement
(d) The ore in the form of oxide is required to be reduced.
(e) Dressed ore is required for it to be concentrated.

  1. e c b d a

  2. c e b d a

  3. c e b a d

  4. c e d b a


Correct Option: B
Explanation:

(c) The ore is beneficial to us if it is handpicked then metal crushed and ground, and later subjected to pulverization as per the requirement
(e) Dressed ore is required for it to be concentrated.
(b) The ore should be converted to its oxide form.
(d) The ore in the form of oxide is required to be reduced.
(a) The metal obtained from its oxide require further purification for end use.

The process in which the state of a substance changes from solid to liquid is called:

  1. boiling

  2. condensation

  3. freezing

  4. melting


Correct Option: D
Explanation:

Melting is the process in which a substance changes from solid to liquid.

When a solid melts, the temperature:

  1. increases

  2. decreases

  3. remains same

  4. can't say


Correct Option: C
Explanation:

When a solid melts the temperature remains same until the whole solid melts.

During melting of ice, the temperature of the ice does not change until the ice melts. The heat is used up in :

  1. changing the state overcoming the forces of attraction

  2. changing the state without overcoming the forces of attraction

  3. releasing into atmosphere

  4. None of the above


Correct Option: A
Explanation:

The heat is used up in changing the state overcoming the forces of attraction.

Which of the following method is used for extracting metals from ores?

  1. Reduction

  2. Melting

  3. Electrolysis

  4. Both $A$ and $C$


Correct Option: D
Explanation:

The compounds of reactive metals from which metals extracted and purified are called ores of metals. Metals can be extracted from ore by reduction and electrolysis.

Prior to reduction, metal sulphide and carbonates are converted into oxides because:

  1. carbonates, sulphides are heavy molecules

  2. it is easier to obtain a metal from its oxide as compared to its sulphides and carbonates

  3. it is easy to heat oxide compared to sulphides and carbonates

  4. both $A$ and $B$


Correct Option: B
Explanation:

It is easier to obtain a metal from its oxide, as compared to its sulphides and carbonates. Therefore, prior to reduction, the metal sulphides and carbonates must be converted to metal oxides.

Ores contain a large amount of impurities, which is called as:

  1. ore

  2. gangue

  3. dust

  4. particulate


Correct Option: B
Explanation:

Ores contain large amount of impurities, which is called as gangue. The process of removing of impurities by physical means of methods like hand picking, crushing or pulverizing and grinding) is called dressing of ore.

_________ is the removal of oxygen for extraction of metal from ore.

  1. Reduction

  2. Electrolysis

  3. Oxidation

  4. Distillation


Correct Option: A
Explanation:

Reduction is the process of removal of oxygen for extraction of metals from their oxide ores.

What is electrolysis$?$

  1. Decomposition of substance by passing electricity

  2. Decomposition of substance by heating

  3. Decomposition of substance by redox reaction

  4. Addition of hydrogen


Correct Option: A
Explanation:

Electrolysis is the process of decomposition of a substance by passing electricity through it in a molten or dissolved state. 

For example, Electrolysis of fused magnesium chloride gives magnesium at cathode and chlorine at the anode.

Hence, the correct option is $A$

What is concentration of ore?

  1. Increasing the concentration of metal

  2. Reducing the concentration of metal

  3. Reducing hydrogen ions

  4. Both $A$ and $C$


Correct Option: A
Explanation:

Different processes applied in order to increase the percentage of metal in the ore is called concentration of ore.

Define roasting.

  1. Heating of sulphide ores in the presence of excess air to convert them into oxides

  2. Heating of carbonate ores in the limited supply of air to convert them into oxides

  3. Heating of oxides of metals to turn them into metal

  4. Heating of carbonate ores in the limited supply of air to convert them into sulphide


Correct Option: A
Explanation:

Ores found in the form of sulphide and carbonates are first converted to their oxides by the process of roasting and calcination. Heating of sulphide ores in the presence of excess air to convert them into oxides is known as roasting.

Ores in the form of sulphide and carbonate are converted into:

  1. water

  2. oxides

  3. aldehyde

  4. alcohol


Correct Option: B
Explanation:

It is easy to obtain metals from their oxides. So, ores found in the form of sulphide and carbonates are first converted to their oxides by the process of roasting and calcination.

Mercury has low boiling point. Therefore it can be purified by the process of:

  1. liquation

  2. polling

  3. oxidation

  4. distillation


Correct Option: D
Explanation:

Mercury has a low boiling point. Therefore it can be purified by the process of distillation because then mercury will evaporate and collected in pure form and impurities will remain back. 

During electrolytic refining of Alumina, the molten electrolyte used contains _______ .

  1. Cryolite

  2. Fluorspar

  3. Pure alumina

  4. All of the above


Correct Option: D
Explanation:

During electrolytic refining of Alumina, the molten electrolyte used contains pure alumina $(Al _2O _3)$. The electrolyte consists of alumina dissolved in fused Cryolite (Na$ _3$AlF$ _6$) and Fluorspar(CaF$ _2$).


Hence, the correct option is $D$.

During calcination:

  1. carbonate ores are changed into oixdes

  2. oxide ores are changed into carbonates

  3. carbonate ores are changed into sulhides

  4. oxide ores are changed into sulphides


Correct Option: A
Explanation:

During calcination, carbonate ores are changed into oxides by heating strongly in limited air.
$ZnCO _3 \rightarrow ZnO + CO _2$

Metal oxide can be reduced by __________.

  1. $Fe$

  2. $Sn$

  3. $C$

  4. All of these


Correct Option: C
Explanation:

Metal oxide of the low reactivity can be reduced by carbon in the simple extraction process. For example; lead oxide is reduced by carbon and it extract lead from its ore.

$2PbO(l) + C(s)  \rightarrow 2Pb (s) + CO _2 (g)$

Usually refractory metals are used in construction of furances because:

  1. they are chemically inert

  2. their melting point is high

  3. they can withstand high temperature

  4. none of the above


Correct Option: A,C
Explanation:

The walls of a furnace should not react with metals or ore. So retractory metals are used as they are chemically inert.

Given below are the steps for extraction of copper from its ore. The balance reaction involved in reduction of copper(I) oxide with copper(I) sulphide is given in the reaction below.

      $2Cu _{2}O + Cu _{2}S \xrightarrow{Heat} 6Cu + SO _{2}$. 

This reaction is known as:

  1. auto-reduction

  2. catalytic- reduction

  3. acid reduction

  4. none of these


Correct Option: A
Explanation:

Auto-reduction is a process in which sulphide ores of less electropositive metals like Hg, Pb, Cu etc., are heated in air so as to convert part of the ore into oxide or sulphate which then reacts with the remaining of sulphide ore in absence of air to give the metal and sulphur dioxide.

Which of the following gases is responsible for the flame at the mouth of Bessemer converter?

  1. Carbon monoxide

  2. Carbon dioxide

  3. Chlorine

  4. Oxygen


Correct Option: A
Explanation:

Carbon monoxide gas from coke is responsible for flame at the mouth of Bessemer converter, as it burns to form carbon dioxide.

Carbon cannot be used to produce magnesium by chemical reduction of $MgO$ because:

  1. carbon is not a powerful reducing agent

  2. magnesium reacts with carbon to form carbides

  3. magnesium is less electropositive than carbon

  4. carbon does not react with magnesium


Correct Option: B

Which of the following metals occurs in nature principally oxide ores.

  1. $Ca$

  2. $Co$

  3. $Cr$

  4. $Cu$


Correct Option: A
Explanation:
$Ca$ occurs aa calcium oxide.So the naturally occuring oreof calcium is calcium oxide $ CaO$.
Hence option A is correct.

When $FeCr _2O _4$ (chromite) is reduced with Carbon in an electric-arc furnace:

  1. Cr and $Fe _2O _3$ are formed

  2. Fe and $Cr _2O _3$ are formed

  3. Fe and Cr (ferrochrome) are formed

  4. $FeCrO _4$ is formed


Correct Option: C
Explanation:

When chromite $(FeCr _2O _4)$ is reduced with carbon in an electric-arc furnace, ferrochrome (Fe and Cr) is obtained.

Carbon reduction process is not comrnerically applicable for which of the following set of oxides to extract the respective metal?
(I) ZnO  (II)$Fe _2O _3$   (III)$Al _2O _3$  (IV) $SnO _2$  (V) MgO

  1. $ZnO, Fe _2O _3, SnO _2$

  2. $ZnO, SnO _2, MgO$

  3. $MgO, AI _2O _3$

  4. $MgO, SnO _2, Al _2O _3$,


Correct Option: C
Explanation:

Carbon reduction process is used to reduce less electropositive metals.
$Mg, Al$ have high electropositivity. Hence, cannot be extracted from oxides through carbon reduction process.

Carbon can be used to reduce the number of oxides and other compounds, and because of the low cost and availability of coke, this method is widely used. But the disadvantages are that:

  1. high temperature is needed, which is expensive

  2. many metals combine with carbon to form carbides

  3. low temperature is needed, which is expensive

  4. many metal combine with carbon and do not form carbides


Correct Option: A,B

Metals which can be obtained by carbon reduction of their oxides are _________.

  1. Cu

  2. Fe

  3. Al

  4. Pb


Correct Option: A,B,D
Explanation:

 Aluminium being more electropositive than carbon, hence it is not reduced by carbon. Other metal oxides can be reduced by carbon.

From the following identify the correct ones.

  1. $Fe _2O _3 + 3CO \rightarrow 2Fe + 3CO _2$

  2. $ZnO + C \rightarrow Zn + CO$

  3. $Ca _3(PO _4) _2 + C \rightarrow P$

  4. $PbO + C \rightarrow Pb$


Correct Option: A,B,D
Explanation:

The correct reactions are as follows-

$Fe _2O _3+3CO\longrightarrow 2Fe+3CO _2$ in Blast furnace.
$ZnO+C\longrightarrow Zn+CO$
$PbO+C\longrightarrow Pb$
$ZnO+C$ and $PbO+C$ can be reduced with carbon.

Lead is extracted from its chief ore galena by both carbon reduction as well as self-reduction.
  1. True

  2. False


Correct Option: A
Explanation:

$2PbS+3O _2\rightarrow 2PbO+2SO _2$
$PbS+2PbO\rightarrow 3Pb+SO _2$ (self reduction)
$PbO+C\rightarrow Pb+CO$
$PbO+CO\rightarrow Pb+CO _2$ (carbon reduction)

Identify the metal $M$ whose extraction is based on the following reactions:
$MS+2{ O } _{ 2 }\longrightarrow M{ SO } _{ 4 }$
$2MS+3{ O } _{ 2 }\longrightarrow 2MO+2S{ O } _{ 2 }$
$MS+2MO\longrightarrow 3M+S{ O } _{ 2 }$
$MS+M{ SO } _{ 4 }\longrightarrow 2M+2S{ O } _{ 2 }\quad $

  1. magnesium

  2. aluminium

  3. lead

  4. tin


Correct Option: A

Which of the following oxides cannot be reduced to metal by carbon?

  1. $ZnO$

  2. $Al _2O _3$

  3. $CuO$

  4. $CaO$


Correct Option: B,D
Explanation:

Generally carbon is more reactive than $Zn$ and $Cu$. Hence, $ZnO$ and $CuO$ can be reduced by carbon leading to the formation of corresponding metals,  but carbon is less reactive than $Ca$ and $Al$, so $CaO$ and $Al _2O _3$ can not be reduced by carbon .

- Hide questions