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The actinoids - class-XII

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Which of the following is not an actinoid?

  1. Curium (Z = 96)

  2. Californium (Z = 98)

  3. Uranium (Z = 92)

  4. Terbium (Z = 65)


Correct Option: D
Explanation:

Terbium (Z = 65) is a lanthanoid and all others are actinoids. Lanthanoids have atomic numbers from 58 to 71. Actinoids have atomic numbers from 90 to 103.

Identify the incorrect statement among the following. 

  1. 4f and 5f orbitals are equally shielded.

  2. 4-Block elements show irregular and erratic chemical properties among themselves.

  3. La and Lu have partially filled d-orbitals and no other partially filled orbitals.

  4. The chemistry of various lanthanoids is very similar.


Correct Option: A
Explanation:

4f and 5f orbitals are not equally shielded. 5f are poorly shielded as 5f orbitals are away from the nucleus.

Also, 5f has poor shielding effect than 4f due to the large size of f-orbital, it is more diffused.

Which of the following is not an actinoid ?

  1. Am

  2. Cm

  3. Fm

  4. Tm


Correct Option: D
Explanation:

LANTHANIDES


58Ce  59Pr  60Nd  61Pm  62Sm  63Eu  64Gd  65Tb  66Dy  67Ho  68Er  69Tm  70Yb  71Lu 

ACTINIDES

 90Th 91 Pa 92 U 93 Np 94 Pu 95 Am 96 Cm 97Bk  98Cf  99Es  100 Fm 101 Md 102No  103Lr 
          

Which of the following is not an actinide ?

  1. Curium

  2. Californium

  3. Uranium

  4. Terbium


Correct Option: D
Explanation:

LANTHANIDES


58Ce  59Pr  60Nd  61Pm  62Sm  63Eu  64Gd  65Tb  66Dy  67Ho  68Er  69Tm  70Yb  71Lu 

ACTINIDES

 90Th 91 Pa 92 U 93 Np 94 Pu 95 Am 96 Cm 97Bk  98Cf  99Es  100 Fm 101 Md 102No  103Lr 
          

Which of the following elements belongs to actinide series?

  1. Lu

  2. Gd

  3. Th

  4. La


Correct Option: C
Explanation:

Lu, Gd and La belongs to lanthanide series and Th belongs to actinide series.


Option C is correct.

The first and last elements of actinides are:

  1. Actinium and Thorium

  2. Actinium and Nobelium

  3. Actinium and Mendelevium

  4. Actinium and Lawrencium


Correct Option: D
Explanation:

We have 15 elements in actinides. They are from atomic number 89 to 103 Actinium, Thorium, Protactinium, Uranium, Neptunium, Plutonium, Americium, Curium, Berkelium, Californium, Einsteinium, Fermium, Mendelevium, Nobelium, Lawrencium. Hence, from these list we could say that Actinium is the first and Lawrencium is the last element in actinides.

5f series elements are known as_______

  1. Lanthanides

  2. Representative elements

  3. Transition elements

  4. Actinides


Correct Option: D
Explanation:

Actinides are also called the 5f series.


 Filling up of the 5f orbitals after actinium (Z = 89) gives the 5f-inner transition series known as the actinoid series.

Option D is correct.

Actiniod contraction is more than lanthanold contraction because:

  1. energy of 4f and 5f orbitals are same

  2. 5f orbitals are more diffused as compared to 4f orbitals

  3. actinoids show greater range of oxidation states than lanthanoids

  4. actinoids are highly reactive


Correct Option: B
Explanation:

$5f$ orbitals are bigger than $4f$ orbitals, in other words, $5f$ orbitals are more diffused thereby having the poor shielding effect. Hence have a more effective nuclear charge thereby having a small size. Hence actinide contraction is more than lanthanide contraction.

Assertion 


The degree of complex formation in actinides decreases in the order:

     $ \ M^{4+}>MO^{2+} _{2}> M^{3+}>MO^{+} _{2} $

Reason

Actinides form complexes with $\pi $ bonding ligands such as alkyl phosphines and thioethers.

  1. Both Assertion and Reason are correct and Reason is correct explanation for Assertion.

  2. Both Assertion and Reason are correct and Reason is not correct explanation for Assertion

  3. Both Assertion is correct but Reason incorrect.

  4. Both Assertion and Reason are incorrect


Correct Option: B

Which of the following forms stable oxidation state?

  1. Ce+ , Yb+

  2. Eu + , Tb+

  3. Lu+, Gd

  4. Pr5+ ,Nd2+


Correct Option: A

Actinoids belongs to following type of elements:

  1. s -block element

  2. d -block element

  3. f -block element

  4. p -block element


Correct Option: C
Explanation:

The two rows that are generally placed underneath the main Periodic Table are called the lanthanide series and the actinide series.

These two rows are produced when electrons are being added to f orbitals.

Therefore, this block of elements are referred to as the "f block".

Which of the following elements is placed just after actinide series?

  1. Rutherfordium

  2. Unnilpentium

  3. Unnilquadium

  4. Ununbium


Correct Option: A,C
Explanation:

Actinide series starts with actinium (Z=89) and contains fourteen elements from thorium (Z=90) to lawrencium (Z=103). This is followed by Rutherfordium (Z=104). There Rutherfordium (Z=104) also known as Unnilquadium.

Hence, both a and c are the correct option.

The bonds generally formin compounds of Actinoids are:

  1. convalent

  2. ionic

  3. coordinate covalent

  4. metallic


Correct Option: B

Actinide element that exhibits highest oxidation state in its compounds (atomic numbers Th(90), U*, Np(93), Fm(100)

  1. Th

  2. U*

  3. Np

  4. Fm


Correct Option: B

Which one of the following elements shows maximum number of different oxidation states in its compounds ?

  1. Eu

  2. La

  3. Gd

  4. Am


Correct Option: D
Explanation:

Am shows +2, +3, +4, +5, +6, +7 oxidation states.

In the general electronic configuration,
$(n-2)f^{1-14} (n-1)d^{01} ns^2$ (where n = 7) the configuration will be of:

  1. lanthenides

  2. actinides

  3. transition elements

  4. none


Correct Option: B
Explanation:

General electronic configuration is given:
$(n -2) f^{1 -14} (n -1) d^{0 1} ns^2 ,where ( n =7 )$
$5f^{1 -14} 6d^{0 1 }ns^2$
The seventh period $(n=7)$ is similar to the sixth period with the successive filling up of the 7s, 5f, 6d and 7p orbitals and includes most of the man-made radioactive elements. This period will end at the element with atomic number 118 which would belong to the noble gas family. Filling up of the 5f orbitals after actinium $(Z=89)$ gives the 5f-inner transition series known as the Actinoid Series.

Most of the radio active elements are present in__________

  1. Lanthanoids

  2. Actinoids

  3. Representative elements

  4. Second transition series


Correct Option: B
Explanation:
The actinoids are radioactive elements and the earlier members have relatively long half-lives.

The most common and known element is Uranium, which is used as nuclear fuel when its converted into plutonium, through a nuclear reaction.

Option B is correct.

_________ form oxocations.

  1. Lanthanides

  2. Actinides

  3. Noble gas

  4. Alkali metals


Correct Option: B
Explanation:

Oxidations are the polyatomic cations contain one or more oxygen atoms. Actinides have a strong tendency towards the complex formation and form oxocations like oxides and hydroxides and are basic in nature.

The actinide contraction is due to:

  1. perfect shielding of $5f$ election

  2. imperfect shielding of $4f$ election

  3. imperfect shielding of $5f$ electron

  4. perfect shielding of $4f$ election


Correct Option: C
Explanation:

The actinide contraction is due to imperfect shielding of $5f$ electron. The valence shell electronic configuration of actinoids is $\displaystyle 5f^{1-14}6d^{0-1}7s^2$. With an increase in atomic number, the positive charge on the nucleus increases by $+1$, and one more electron enters in the same $5f$ subshell. There is imperfect shielding of one electron by another electron in the same $5f$ subshell. Due to this, the atomic and ionic radii show a gradual decrease with increase in atomic number.

Which of the following is true regarding derivation of the name of californium?

  1. The name of californium was derived from the name of the place.

  2. The name of californium was derived from its color.

  3. The name of californium was derived from the name of the scientist who discovered it.

  4. The name of californium was derived from mythological character name.


Correct Option: A
Explanation:

The name of californium was derived from the name of the state and University of California.

Beryllium resembles Aluminium in properties. This is mainly due to:

  1. equal electro negativity values of elements

  2. equal atomic volumes of the elements

  3. equal electron affinity

  4. equal nuclear charges in their atoms


Correct Option: A
Explanation:

Beryllium resembles Aluminium in properties. This is due to similar electronegativity, similar atomic size and they diagonal relationship.

Amphoteric behaviour is shown by the oxides of :

  1. $Al$ and $Ca$

  2. $Pb$ and $Ba$

  3. $Cr$ and $Mg$

  4. $Sn$ and $Zn$


Correct Option: D
Explanation:

Amphoteric oxides can behave as an acid as well as base. They react with both acids and bases to form salts. Tin oxide although doesn't dissolve in water but it is amphoteric in nature. Zinc oxide is also amphoteric in nature.

$ZnO+HCl \rightarrow ZnCl _2+H _2O$
$ZnO+NaOH \rightarrow Na _2ZnO _2+H _2O$
$SnO _2+HCl \rightarrow SnCl _4+H _2O$
$SnO _2+NaOH+H _2O \rightarrow Na _2[Sn(OH) _6]$

If the IP of hydrogen in its ground state is 2.18 x$10^{-18}$ J/atom, then the electron affinity of $Li^{3+}$ ion is :

  1. $-2.18\times$$10^{-18}$J/atom

  2. $-6.54 \times$$10^{-18}$J/atom

  3. $-3.488 \times$$10^{-18}$J/atom

  4. $-1.962\times$$10^{-17}$ J/atom


Correct Option: D
Explanation:

E.A of $Li^{+3} = -$I.P of $Li^{+2}$
I.P of $Li^{+2}  = $I.P of $H \dfrac{Z^2}{n^2}$
Therefore, I.P of $Li^{+2}$=$2.18 \times 10^{-18} J/atom \times 9 $ as Z=3
Thus, E.A of $Li^{+3} =-1.962 \times 10^{-17}$ J/atom

If the seventh period is completed, the atomic number of the last element would be:

  1. $118$

  2. $112$

  3. $107$

  4. $120$


Correct Option: A
Explanation:

As the seventh period will be completely filled its electronic configuration must be in the manner of noble gas configuration i.e., $ns^2,: np^6$ because the last element in every period is noble gas element. Hence, the electronic configuration of last element of seventh period is (Rn) $5f^{14} 6d^{10} 7s^27p^6$ as the electronic configuration contains $118$ electrons, the last element in the seventh period will have the atomic number $118$.

Stable electronic configuration of a transition metal is:

  1. $1s^{2} 2s^{2}2p^{6} 3s^{2} 3p^{6} 3d^{9} 4s^{2}$

  2. $1s^{2} 2s^{2} 2p^{6} 3s^{2} 3p^{6} 4s^{2} 3d^{5}$

  3. $1s^{2} 2s^{2} 2p^{6} 3s^{2} 3p^{6} 4s^{2}$

  4. $1s^{2} 2s^{2} 2p^{6} 3s^{2} 3p^{6} 4s^{2} 3d^{10} 4p^{6}$


Correct Option: B
Explanation:

Generally the elements having  half filled and completely filled outer electronic configurations are stable  elements,here in given options the configuration $1s^22s^22p^63s^23p^64s^23d^5$ contains half filled outer electronic configuration $(3d^5)$.


Hence option B is correct.

The element with $Z = 106$ belongs to :

  1. $3^{rd}$ period

  2. $ 5^{th}$ period

  3. $7^{th}$ period

  4. $6^{th}$ period


Correct Option: C
Explanation:

$Z=106$ is seaborgium and its electronic configaration is $(Rn) 5f^{14}6d^{4}7s^{2}$. as the differenting electron enter into $7s$, 7 is the principle quantum number which represents the number of period to which the element belongs hence, the element belongs to 7th period.

An atom of element has $2K, 8L$ and $3M$ electrons. Then the element belongs to :

  1. IA group

  2. IIA group

  3. IIIA group

  4. IVA group


Correct Option: C
Explanation:

The total number of electrons present in all the shells are $2+8+3=13$, hence the atomic number of element is $13$ and the electronic configuration would be $1s^22s^22p^63s^23p^1 $. Element belongs to $|||A$ group.

Most of the man-made synthetic elements occur:

  1. in actinide series

  2. in lanthanide series

  3. in coinage metals

  4. in alkaline earth metals


Correct Option: A

Maximum oxidation state of uranium and plutonium are respectively:

  1. $4$ and $6$

  2. $5$ and $6$

  3. $6$ and $7$

  4. $6$ and $8$


Correct Option: C
Explanation:
Solution:- (C) $6$ and $7$
Uranium has maximum oxidation number $= +6$ 
Plutonium has maximum oxidation number $= +7$

Lanthanides and actinides resemble in:

  1. electronic configuration

  2. oxidation state

  3. ionization energy

  4. formation of complexes


Correct Option: A
Explanation:

Lanthanides and actinides resemble in electronic configuration:

$(n-2)f^{1-14}(n-1)d^{1-10}ns^{1-2}$

More number of oxidation states are exhibited by the actinoids than by lanthanoids. The main reason for this is:

  1. greater metallic character of the lanthanoids than that of the corresponding actinoids.

  2. more active nature of the actinoids.

  3. more energy difference $5f$ and $6d$-orbitals than that between $4f$ and $5d$-orbitals.

  4. lesser energy difference between $5f$ and $6d$-orbitals than that between $4f$ and $5d$-orbitals.


Correct Option: D
Explanation:

Actinoids display more oxidation states because of very small energy gap between 5f, 6d and 7s sub shells. Thus, the outermost electrons get easily excited to the  higher energy level giving variable oxidation state.

Hence,option D is correct.
 

Statement 1: Lanthanides have much less tendency to form complexes than actinides.
Statement 2: Compared to actinides, the lanthanides have relatively larger size of atoms and less nuclear charge.

  1. Statement 1 is True, statement 2 is True, statement 2 is a correct explanation of statement 1.

  2. Statement 1 is True, statement 2 is True, statement 2 is not a correct explanation of statement 1.

  3. Statement 1 is true, Statement 2 is False.

  4. Statement 1 is False, Statement 2 is True.


Correct Option: A
Explanation:

Because of higher effective nuclear charge and smaller size of atoms the actinides have higher charge density and because of that they have greater tendency to form complexes than the lanthanides.

The main reason for larger number of oxidation states exhibited by the actinoids than the corresponding lanthanoids, is:

  1. the lesser energy difference between 5f and 6d orbitals than between 4f and 5d orbitals

  2. more energy difference between 5f and 6d orbitals than between 4f and 5d orbitals

  3. greater reactive nature of the actinoids than the lanthanoids

  4. larger atomic size of actinoids than the lanthanoids


Correct Option: A
Explanation:

Actinoids shows larger oxidation states due to poor shielding of both $4f$ and $5f$ orbital electrons as a result these orbital have almost similar energy and hence take part in bond formation. Also, there is very small energy between $5f, 6d$ and $7s$ subshells.

The number of oxidation states is exhibited by the actinoids more than by the lanthanide. The main reason for this is:

  1. more energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals.

  2. the lesser energy difference between 5f and 6d orbitals than between 4f and 5d orbitals.

  3. the greater metallic character of the lanthanoids than that of the corresponding actinoids.

  4. more active nature of the actinoids.


Correct Option: B
Explanation:

Actinides show larger oxidation states due to poor shielding of both $4f$ and $5f$ orbital electrons, as a result, their orbitals have almost similar energy and hence take part in bond formation. Thus the energy gap between $5f, 6d$ and $7s$ become very small.

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