Understanding chemical kinetics - class-XII
Description: understanding chemical kinetics | |
Number of Questions: 19 | |
Created by: Girish Devgan | |
Tags: chemistry electrochemistry and chemical kinetics chemical reactions and equations chemical kinetics |
Fill up the following with suitable terms.
Chemical kinetics a branch of physical chemistry deals with:
If reaction A and B are given with Same temperature and same concentration but rate of $A$ is double than $B$. Pre exponential factor is same for both the reaction then difference in activation energy $E _{A} - E _{B}$ is?
Which of the following theory is not related to the chemical kinetics?
Chemical kinetics, a branch of physical chemistry, deals with:
If the door of a refrigerator is kept open in a dosed room then room:
A chemist puts a sample of dilute aqueous hydrochloric acid into beaker $1$. She adds a sample of zinc and measures the rate of production of hydrogen gas.
She then puts a different sample of dilute aqueous hydrochloric acid into beaker $2$. She adds a different sample of zinc and measure the rate of production of hydrogen gas.
The rate of the reaction in beaker $2$ is greater than the rate of the reaction in beaker $1$.
Which factors could help to explain this observation?
$1$. The reaction in beaker $1$ has a higher activation energy than the reaction in beaker $2$.
$2$. The zinc in beaker $1$ is in larger pieces than the zinc in beaker $2$.
$3$. The acid in beaker $1$ is at a lower concentration than the acid in beaker $2$.
The approach to the following equilibrium was observed kinetically from both directions:
$ Pt{ Cl } _{ 4 }^{ -2 }+H _{ 2 }O\rightleftharpoons Pt(H _{ 2 }O)CI _{ 3 }+Cl^{ - } $
At $ 25^o C,$ it was found that $ -\dfrac { d[PtC{ l } _{ 4 }^{ 2- }] }{ dt } =(3.9 \times 10^{ -5 } s^{ -1 }) [PtC{ l } _{ 4 }^{ 2- }]-(2.1 \times 10^{ -3 } L mol^{ -1 }s^{ -1 }) [Pt(H _{ 2 }O)C{ l } _{ 3 }^{ - }][Cl^{ - }] $
The value of $ K _{eq} $ (equilibrium constant) for the complexation of the fourth $ cl^- $ by $ Pt( II ) $ is
Which statements are correct in terms of chemical kinetic stuides?
What does the exponential factor represent?
In a reaction mechanism consisting of elementary reaction steps where the relative rate of each is given, which of the following is most likely to be the rate-determining step?
Statement: The rate of instantaneous reactions can be determined experimentally.
Rate of formation of ${ SO } _{ 3 }$ according to the reaction $2{ SO } _{ 2 }+O _{ 2 }\rightarrow 2{ SO } _{ 3 }\quad is\quad 1.6\times { 10 }^{ -3 }kg\quad min^{ -1 }$. Hence rate at which $SO _{ 2 }$ reacts is:
For a reaction
$2A+B\rightarrow C+D$, the active mass of $B$ is kept constant but that of $A$ is tripled. The rate of reaction will -
The study of chemical kinetics becomes highly complicate if there occurs:
The container of $2$ litrer contains $4$ mole of $N _{2}O _{5}$. On heating to $100^{\circ}C, N _{2}O _{5}$ undergoes complete dissociation to $NO _{2}$ and $O _{2}$. Select the correct answers if rate constant for decomposition of $N _{2}O _{5}$ is $6.2\times 10^{-4}sec^{-1}$.
1. The mole ratio before and after dissociation is $4 : 2$
2. Half life of $N _{2}O _{5}$ is $1117\ sec$ and it is independent of concentration.
3. Time required to complete $40$% of reaction is $824\ sec$.
4. If volume of container is doubled, the initial rate of decomposition becomes half of the initial rate.