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Chemistry (GATE)

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Which of the following statements are not correct about boron?

  1. Boron halides do not form dimers.
  2. Boron is a bad conductor of electricity.
  3. Boron exists in amorphous form only.
  4. The hydroxides and oxides of boron are amphoteric.
  5. The melting and boiling point of boron are lower than that of aluminium.
  6. Boron forms only covalent compounds.
  1. 1, 2 and 3

  2. 1, 4 and 6

  3. 2, 3 and 4

  4. 3, 4 and 5

  5. 3, 5 and 6


Correct Option: D
Explanation:

This option is correct because boron exists in both crystalline and amorphous forms. The hydroxides and oxides of boron are acidic, not amphoteric and the melting and boiling point of boron are much higher than that of Al.

Which among the following statements is/are correct?

  1. All the noble gases, except radon, occur in the atmosphere.
  2. XePtF6 was the first noble gas compound.
  3. XeF2 has bent geometry.
  4. Noble gases have large positive values of electron gain enthalpy.
  1. 1 and 3

  2. 1, 2 and 4

  3. 1, 2, 3 and 4

  4. 2 and 3

  5. 2, 3 and 4


Correct Option: B
Explanation:

This option is correct. All the noble gases, except radon, occur in the atmosphere. XePtF6 was the first noble gas compound prepared by N. Bartlett. The noble gases have large positive values of electron gain enthalpy due to their stable electronic configuration, they have no tendency to accept the electron.

Which of the following are examples of tribasic acid?

  1. Metaphosphoric acid
  2. Pyrophosphoric acid
  3. Orthophosphoric acid
  4. Orthophosphorous acid
  5. Hypophosphorous acid
  6. Hypophosphoric acid
  7. Peroxyphosphoric acid
  1. 1 and 3

  2. 2 and 5

  3. 3 and 7

  4. 4 and 6

  5. 5 and 7


Correct Option: C
Explanation:

Orthophosphoric acid (H3PO4) is a tribasic acid. Peroxyphosphoric acid (H3PO5) is a tribasic acid.

Which of the following statements regarding phosphine are incorrect?

  1. It is a trigonal pyramidal molecule.
  2. Point group of phosphine is C2v.
  3. The length of the P-H bond is 1.42 Å.
  4. The H-P-H bond angles are 109.5°.
  5. It is a polar molecule.
  1. 1 and 2

  2. 1 and 5

  3. 2 and 3

  4. 2 and 4

  5. 3 and 4


Correct Option: D
Explanation:

Phosphine (PH3) belongs to C3v point group. The H-P-H bond angles are 93.5°.

Identify the incorrect statements.

  1. HI has lower boiling point than HCl.
  2. UF6 is more covalent than UF4.
  3. All halogens can exhibit positive oxidation states.
  4. Bleaching action of chlorine is due to oxidation.
  1. 1 and 2

  2. 1 and 3

  3. 1 and 4

  4. 2 and 3

  5. 2 and 4


Correct Option: A
Explanation:

This option is correct because with the increase in size the magnitude of intermolecular Van der Waal forces increases, thus, the boiling point also increases. Because iodide ion is larger in size than chloride ion, HI has higher a boiling point than HCl and if a metal exhibits more than one oxidation state, the halides in higher oxidation state will be more covalent than the one in a lower oxidation state. For example: SnCl4, PbCl4, SbCl5 and UF6 are more covalent than SnCl2, PbCl2, SbCl3 and UF4 respectively.

Which of the following alkaline earth metals crystallise in face centered cubic structure?

  1. Beryllium
  2. Magnesium
  3. Calcium
  4. Strontium
  5. Barium
  1. 1 and 2

  2. 1, 2 and 3

  3. 3 and 4

  4. 3, 4 and 5

  5. 4 and 5


Correct Option: C
Explanation:

Calcium and strontium crystallizes in face centered cubic structure.

Which of the following statements are correct about halogens?

  1. Fluorine is a stronger oxidising agent than chlorine.
  2. Halogens have maximum negative electron gain enthalpy in the corresponding periods.
  3. The negative electron gain enthalpy of fluorine is more than that of chlorine.
  4. The enthalpy of dissociation of F2 is more than Cl2.
  1. 1 and 2

  2. 1 and 4

  3. 2 and 3

  4. 2 and 4

  5. 3 and 4


Correct Option: A
Explanation:

Although electron gain enthalpy of fluorine is less negative as compared to chlorine, fluorine is a stronger oxidising agent than chlorine. It is due to low enthalpy of dissociation of F-F bond and high hydration enthalpy of F-. Halogens have maximum negative electron gain enthalpy in the corresponding periods. This is because after gaining an electron, they attain the stable noble gas configuration. Thus, this option is correct.

Which of the following second row transition metals crystallise in face centred cubic lattice?

  1. Nb
  2. Mo
  3. Tc
  4. Ru
  5. Pd
  6. Ag
  1. 1 and 2

  2. 2 and 3

  3. 3 and 4

  4. 4 and 5

  5. 5 and 6


Correct Option: E
Explanation:

Palladium (Pd) and silver (Ag) crystallise in face centred cubic lattice.

Which of the following statements are not true?

  1. Sulphates and hydroxides of alkali metals are more soluble than those of alkali metals.
  2. Solubility of alkaline earth metal sulphates increases down the group.
  3. Solubility of alkaline earth metal hydroxides decreases down the group.
  4. Alkaline earth metal ions have greater hydration enthalpies than alkali metal ions.
  1. 1 and 2

  2. 1 and 3

  3. 2 and 3

  4. 2 and 4

  5. 3 and 4


Correct Option: C
Explanation:

For the sulphates of alkaline earth metals, the cations are much smaller than the anions. On moving down the group, the change in size of the cations does not cause a significant change in ∆Hlattice, but ∆Hhydration becomes less negative. As a result, ∆Hsolution becomes less negative and the solubility of alkaline earth metal sulphates decreases down the group. For the hydroxides of alkaline earth metals, the size of the anions and cations are of the same order of magnitude. On moving down the group, less energy is required to break the lattice as the size of cations increases, but the change in ∆Hhydration is comparatively small. Consequently, the ∆Hsolution becomes more negative and the solubility of alkaline earth metal hydroxides increases down the group.

Which of the following third row transition metals crystallise to form body centred cubic lattice?

  1. Tantalum
  2. Tungsten
  3. Rhenium
  4. Osmium
  5. Platinum
  6. Gold
  1. 1 and 2

  2. 2 and 3

  3. 3 and 4

  4. 4 and 5

  5. 5 and 6


Correct Option: A
Explanation:

Tantalum (Ta) and tungsten (W) crystallises to form body centred cubic lattice.

Identify the incorrect statements.

  1. Alkaline earth metals have stronger metallic bonding than the corresponding alkali metals.
  2. Alkaline earth metals have higher densities than corresponding alkali metals.
  3. Melting points in alkaline earth metals are lower than for the corresponding alkali metals.
  4. Alkaline earth metal carbonates higher thermal stability than corresponding alkali metal carbonates.
  1. 1 and 2

  2. 1 and 4

  3. 2 and 3

  4. 2 and 4

  5. 3 and 4


Correct Option: D
Explanation:

Because their atoms are significantly smaller than those of alkali metals, alkaline earth metals have higher densities. Alkaline earth metal ions are much smaller in size than corresponding alkali metal ions and carry a higher charge. Thus, their polarizing power is greater. Electron cloud of carbonate anions are more easily distorted by alkaline earth metal ions than by alkali metal ions. Therefore, alkaline earth metal carbonates are less stable to heat and decompose to form metal oxide and carbon dioxide. Thus, this option is wrong. This option is correct because melting points in alkaline earth metals are higher than for the corresponding alkali metals. Alkaline-earth metals contribute two electrons per atom to the mobile electron cloud whereas alkali metals contribute only one electron per atom. The greater number of electrons and the smaller ionic size of the alkaline earth metals helps to increase the density of the electron cloud and thus increase the attractive forces between the mobile electrons and the cationic lattice. Alkaline earth metal ions are much smaller in size than corresponding alkali metal ions and carry a higher charge. Thus, their polarizing power is greater. Electron cloud of carbonate anions are more easily distorted by alkaline earth metal ions than by alkali metal ions. Therefore, alkaline earth metal carbonates are less stable to heat and decompose to form metal oxide and carbon dioxide.

Directions: In the question given below, there are two statements labelled as Assertion (A) and Reason (R). Mark your answer as per the codes provided below: Assertion: NF3 has dipole moment but, BF3 has not. Reason: If the molecule is unsymmetrical, the resultant dipole moment of the molecule is not zero.

  1. Both A and R are true and R is the correct explanation of A.

  2. Both A and R are true but R is not the correct explanation of A.

  3. A is true but R is false

  4. A is false but R is true.

  5. Both A and R are false.


Correct Option: A
Explanation:

This option is correct because NF3 has dipole moment as it is unsymmetrical but, BF3 has zero dipole moment because BF3 is a symmetrical molecule.

For which following properties Li has higher value than Na?

  1. Hydration enthalpy
  2. Thermal stability of hydride
  3. Stability of carbonate
  4. Basic character of hydroxide
  1. 1 and 2

  2. 1 and 3

  3. 1 and 4

  4. 2 and 3

  5. 3 and 4


Correct Option: A
Explanation:

The hydration enthalpies of alkali metal ions decrease with increase in ionic sizes. The correct order of hydration enthalpies of alkali metal ions is Li+> Na+ > K+ > Rb+ > Cs+. The thermal stability of alkali metal hydrides decreases from LiH to CsH.

Match the column A with B ||| |---|---| |Column A |Column B| |A. Caffeine|1. β-Lactam antibiotic| |B. Adrenaline|2. A non-peptide hormone| |C. Clavulanic acid|3. A flavouring agent| |D. Naproxen|4. An alkaloid| | | 5. Analgesic|

  1. A - 4, B - 2, C - 1, D - 5

  2. A - 5, B - 3, C - 2, D - 1

  3. A - 1, B - 4, C - 3, D - 2

  4. A - 2, B - 5, C - 4, D - 3

  5. A - 3, B - 1, C - 5, D - 4


Correct Option: A
Explanation:

This option is correct because caffeine is an alkaloid, adrenaline is a non peptide hormone, clavulanic acid is a beta lactam antibiotic and naproxen is an analgesic.

Match the components in Column-I with the Column-II accordingly and select the correct answer using the codes given below ||| |---|---| |Column I |Column II| |A. Erythrocytes|1. Blood coagulation| |B. factor I|2. Maintenance of osmotic pressure of blood plasma| |C. Saccharide|3. Transports of O2 from lungs to the tissues| |D. Globulins|4. Transport of lipids as lipoproteins| |E. Albumins|5. Source of energy| |F. Thrombocytes| |

  1. A - 3, B - 1, C - 5, D - 4, E - 2, F - 1

  2. A - 3, B - 5, C - 1, D - 2, E - 4, F - 1

  3. A - 1, B - 3, C - 5, D - 4, E - 2, F - 1

  4. A - 3, B - 1, C - 5, D - 4, E - 1, F - 2

  5. A - 3, B - 1, C - 4, D - 5, E - 2, F - 1


Correct Option: A
Explanation:

The function of erythrocytes is transport of O2 from lungs to the tissues, the function of factor I (fibrinogen) and thrombocytes is blood coagulation, saccharide-source of energy, globulins-transport of lipids as lipoproteins and albumins-maintenance of osmotic pressure of blood plasma. Thus, this option is correct.

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