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Solid State (KVPY)

Description: Solid State(KVPY)
Number of Questions: 15
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Tags: Solid State (KVPY) Solid State
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Which of these defects is known as Thermodynamic defect?

  1. Vacancy

  2. Frenkel

  3. Schottky

  4. Interstitial

  5. Metal deficiency


Correct Option: A
Explanation:

Vacancy defect is called a thermodynamic defect because this defect arises due to the absorption of heat from the surroundings.

Which of the following solids is a good conductor of electricity?

  1. Quartz

  2. Ammonia

  3. Diamond

  4. Graphite

  5. Hydrochloric acid


Correct Option: D
Explanation:

Graphite is a good conductor of electricity because in each layer every carbon atom is linked to three carbon atoms, the fourth electron is free to move about. Presence of these electrons makes it a good conductor.

Which of the following solids is called a supercooled liquid?

  1. Graphite

  2. Alum

  3. Iron

  4. Copper

  5. Quartz glass


Correct Option: E
Explanation:

Quartz glass is said to be amorphous, and hence a supercooled liquid due to its high viscosity.

Which of the following is not a crystalline solid?

  1. Copper

  2. Tin

  3. Rubber

  4. Iron

  5. Carbon


Correct Option: C
Explanation:

Rubber is an amorphous solid as there is no regular arrangement of its constituents particles.

What is the colour of LiCl when excess Li is added?

  1. Green

  2. Orange

  3. Violet

  4. Pink

  5. Yellow


Correct Option: D
Explanation:

On heating electrons are trapped at the anionic sites forming F-centres, which absorb energy from light and radiate pink colour.

Which of the following have maximum packaging efficiency?

  1. Simple cubic

  2. BCC

  3. HCP

  4. FCC

  5. None of these


Correct Option: D
Explanation:

FCC has maximum packaging efficiency, as it has a closed packed structure.

Which of the following solids conduct electricity in molten state, but not in solid state?

  1. Network solids

  2. Ionic solids

  3. Non polar solids

  4. Hydrogen bonded solids

  5. Metallic solids


Correct Option: B
Explanation:

In the molten state, ionic solids dissociate to give free ions, and hence can conduct electricity.

Which of these defects are not found in pure alkali metal halides?

  1. Frenkel

  2. Vacancy

  3. Schottky

  4. Interstitial

  5. Metal excess


Correct Option: A
Explanation:

Alkali metals have large size, which cannot fit into the interstitial sites.

Which substances show permanent magnetism?

  1. Paramagnetic

  2. Ferromagnetic

  3. Anti-ferromagnetic

  4. Diamagnetic

  5. Ferrimagnetic


Correct Option: B
Explanation:

The reason behind such magnetic behaviour is that metal ions in these substances are grouped together into domains. Each domain acts as a tiny magnet having a definite magnetic moment.

What is the effect of pressure on NaCl crystal's coordination number?

  1. Decreases from 6:6 to 4:4

  2. Increases from 6:6 to 8:8

  3. Remains same

  4. First decrease then increases

  5. First increase then decreases


Correct Option: B
Explanation:

Increases from 6:6 to 8:8 as NaCl structure gets converted to CsCl structure.

Which of these defects is called dislocation defect?

  1. Schottky

  2. Frenkel

  3. Vacancy

  4. Metal excess

  5. Interstitial


Correct Option: B
Explanation:

As the smaller ions get dislocated from the normal site to an interstitial site.

What kind of defects are introduced by doping?

  1. Dislocation

  2. Line

  3. Point

  4. Impurity

  5. Electronic


Correct Option: E
Explanation:

As doping is done with electron rich or electron deficient impurities. Hence, it introduces electronic defects.

The total number of tetrahedral voids per unit cell in NaCl is

  1. 4

  2. 8

  3. Twice the number of octahedral voids

  4. Four times the number of octahedral voids

  5. None of these


Correct Option: B
Explanation:

NaCl has FCC arrangement of Cl ions. Hence, the number of Cl ions in packaging per unit cell= 4 Tetrahedral is double of octahedral voids. Thus, 2n= 8.

What is the effect of an increase of temperature on the electrical conductivity of a metal?

  1. Conductivity decreases

  2. Conductivity increases

  3. Conductivity remains same

  4. Conductivity increases and decreases both

  5. All of the above


Correct Option: A
Explanation:

Electrical conductivity decreases with an increase of temperature because on heating, the positive ions of the metal atoms start vibrating and produce resistance in the flow of electrons.

Which of the following defect does not cause a change in density of the crystal?

  1. Schottky

  2. Interstitial

  3. Frenkel

  4. Vacancy

  5. Metal deficiency


Correct Option: C
Explanation:

Since, no ions are missing from the crystal as a whole, therefore density of the solid remains unchanged.

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