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Matter - Nature and Behaviour : Periodic Classificat...

Description: Matter- Nature and Behaviour: Periodic Classification of Elements
Number of Questions: 15
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Tags: Matter- Nature and Behaviour: Periodic Classification of Elements Early Attempts at Classification of Elements and Periodic Law Modern Periodic Table Trends across Periods and Groups
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As we move from left to right across a period, the atomic size of the next element

  1. increases

  2. decreases

  3. approaches zero

  4. remains the same


Correct Option: B
Explanation:

On moving left to right across a period, the atomic size decreases because the effective nuclear charge increases  

Why is Newlands’ method of classification of elements known as the Law of Octaves?

  1. It could classify eight elements.

  2. It consists of eight groups.

  3. Every eighth element has properties similar to the first.

  4. The classification was based on the atomic masses of elements.


Correct Option: C
Explanation:

Newlands found that the properties of the eighth element were similar to the properties of the first element. He compared this with the octaves found in the musical scale. Therefore, this method of classification of elements is called Newlands’ Law of Octaves.

Which of the following properties does not increase while going down a group?

  1. Electronegativity

  2. Atomic mass

  3. Atomic size

  4. Atomic number

  5. Metallic character


Correct Option: A
Explanation:

Electronegativity decreases while going down a group.

Which of the following scientists discovered that the atomic number of an element is a more fundamental property of an element than its atomic mass?

  1. Newlands

  2. Mendeleev

  3. Dobereiner

  4. Henry Moseley


Correct Option: D
Explanation:

Newlands, Mendeleev and Dobereiner all tried to correlate the properties of elements with their atomic masses. Newlands, an English scientist, arranged the elements in order of their increasing atomic masses. He started with hydrogen (atomic mass 1 u), the element having the lowest atomic mass and ended with thorium, which was the 56th element. He found that the properties of the eighth element were similar to the properties of the first element. Dobereiner tried to arrange the elements with similar properties into groups called triads having 3 elements each. According to Dobereiner, when the elements of any particular triad were arranged in order of their increasing atomic masses, the atomic mass of middle element was roughly the mean or average of the atomic masses of the other two elements. Mendeleev, in his periodic table, classified the elements on the basis of their increasing atomic masses and the formula of their oxides and hydrides. Later on, Henry Moseley discovered that atomic number is a more appropriate parameter to determine the properties of an element rather than its atomic mass.

The horizontal rows in the periodic table are called

  1. valency electrons

  2. groups

  3. periods

  4. valency shells


Correct Option: C
Explanation:

The horizontal rows in the periodic table are called periods.

Which of the following is a drawback of the modern periodic table?

  1. Position of lanthanides and actinides

  2. Position of elements in relation to electric configuration

  3. Regular variation in properties along a period

  4. Position of halogens


Correct Option: A
Explanation:

It fails to accommodate lanthanides and actinides in the main body of periodic table.

Which of the following arrangements of elements is correct in terms of increasing atomic radius?

  1. Li < Be < B

  2. N < O < F

  3. Na < Mg < Al

  4. F < Cl < Br


Correct Option: D
Explanation:

On moving down a group, atomic radius increases as the number of shells increases. Li (Z = 3), Be (Z = 4) and B (Z = 5) belong to the 2nd period. On moving across the period from Li to B, size will decrease. So, their correct order in terms of increasing atomic radius is B < Be < Li. Moreover, N (Z = 7), O (Z = 8) and F (Z = 9) belong to the 2nd period. On moving from N to F, atomic radius will decrease. So, their correct order is F < O < N. Similarly, Na (Z = 11), Mg (Z = 12) and Al (Z = 13) belong to the 3rd period. On moving from Na to Al, atomic radius will decrease. So, their correct order is Al < Mg < Na. F (Z = 9), Cl (Z = 17) and Br (Z = 35) belong to the 17th group and from F to Br, the atomic radius will increase. So, their correct order in terms of increasing atomic radius is F < Cl < Br. Therefore, only option (4) is correct.

Which of the following properties was adopted as the basis of the modern periodic table?

  1. Atomic mass

  2. Atomic radius

  3. Density

  4. Atomic number


Correct Option: D
Explanation:

The earlier attempts at classification of elements was based on atomic masses. Later on, it was found that atomic number is a more appropriate parameter to determine the properties of an element. Therefore, in the modern periodic table, elements are arranged in the increasing order of their atomic number. 

At which element did Newlands’ arrangement of elements end?

  1. Helium

  2. Selenium

  3. Tin

  4. Thorium


Correct Option: D
Explanation:

Newlands, an English scientist, arranged the elements according to their increasing atomic masses. He started with hydrogen (Atomic mass = 1 u), the element having the least atomic mass and ended with thorium, which was the 56th element.

Which of the following groups of elements, discovered later, could be placed in Mendeleev’s periodic table without disturbing the existing order of groups?

  1. Alkali metals

  2. Alkaline earth metals

  3. Noble gases

  4. Halogens


Correct Option: C
Explanation:

The noble gases like helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe) and radon (Rn) were not known when Mendeleev gave his periodic table. These gases were discovered later on because they are inert and are present in extremely low concentration in our atmosphere. But, it was the strength of Mendeleev’s periodic table that these gases, when discovered, could be placed in a new group called zero group, without disturbing the existing order. Halogens (F, Cl, Br, I), alkali metals (Li, Na, K, Rb, Cs) and alkaline earth metals (Be, Mg, Ca, Sr, Ba) were already discovered when Mendeleev gave his periodic table. So, they were already occupying specific positions in his periodic table.

In Döbereiner’s triads, the elements were placed in the increasing order of their

  1. atomic masses

  2. reactivity

  3. number of protons

  4. number of neutrons


Correct Option: A
Explanation:

According to Döbereiner, when elements of any particular triad were arranged in the increasing order of their atomic masses, the mass of the middle element was roughly the mean or average of the atomic masses of the other two elements. 

The existence of which of the following elements was predicted by Mendeleev before it was actually discovered?

  1. Scandium

  2. Titanium

  3. Cesium

  4. Iodine


Correct Option: A
Explanation:

Mendeleev left some gaps in his periodic table for some undiscovered elements. Mendeleev boldly predicted that these elements would be discovered later. He even predicted the properties of these unknown elements and named these elements by prefixing a Sanskrit word ‘eka’ to the name of the preceding element in the same group, e.g. eka–boron for scandium, eka-aluminium for gallium and eka-silicon for germanium. Titanium, cesium and iodine were already discovered when Mendeleev gave his periodic table. So, option (1) is the correct answer.

Which of the following elements will be present in the shortest period?

  1. Hydrogen and lithium

  2. Hydrogen and helium

  3. Lithium and helium

  4. Beryllium and helium


Correct Option: B
Explanation:

The 1st period is the shortest period and contains hydrogen and helium.

Arrange the following elements in increasing order of atomic size.

Rb, Cs, Li, Na, K

  1. Na < K < Rb < Li < Cs

  2. Cs < Rb < K < Na < Li

  3. K < Na < Cs < Rb < Li

  4. Li < Na < K < Rb < Cs

  5. K < Rb < Cs < Na


Correct Option: D
Explanation:

Atomic size of an element increases as we move from top to bottom in the periodic table.

Why does atomic size increase down a group?

  1. Due to increase in nuclear charge

  2. Due to increase in the distance between the outermost electron and the nucleus

  3. Due to increase in the force of attraction between the outermost electron and the nucleus

  4. Due to increase in valence electrons


Correct Option: B
Explanation:

Atomic size increases down a group because the distance between the outermost electron and the nucleus increases.

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