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Chemistry Mixed Test - 2 (Engineering Entrance)

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If ' r ' is the radius of first orbit , the radius of nth orbit of the H - atom will be ?

  1. r n .

  2. r n2 .

  3. r / n .

  4. r2 n2 .


Correct Option: B
Explanation:

This option is correct because radius of nth orbit is given by , r n= ( 0.529 n2 ) / Z . Radius of first bohr's orbit is , r  =  0.529 . Hence, radius of nth orbit will be = r n2 . Hence, this option is correct  .

Configuration of 5 p1 ?

  1. n = 5 , l = 1 .

  2. n = 4 , l = 1 .

  3. n = 5 , l = 0 .

  4. n = 5 , l = 2 .


Correct Option: A
Explanation:

This option is correct because it is clearly seen that n = 5. In this case l value of ' p ' orbital is 1 . Hence, this option is correct .

The orbital angular momentum for an electron revolving in an orbit is give by square root [l ( l + 1 ) ] h / 2π . This momentum for a p - electron will be given by ?

  1. h / square root (2 ) π .

  2. 0 .

  3. square root [ 6 ] h / 2π .

  4. square root [ 3 ] h / 2 π .


Correct Option: A
Explanation:

This option is correct because  L value of ' p ' orbital is 1 . Hence, this option is correct .

what is the circumference of the fourth orbit ?

  1. 5λ .

  2. 2λ .

  3. 4λ .

  4. 3λ .


Correct Option: C
Explanation:

This option is correct because;  , λ = h / mv . and from conservation of angular momentum we have = mvr = nh / 2π . => 2πr = nλ . in this case value of n is 4 . hence, this option is correct.

If uncertainity in the position of the electron is zero , the uncertainity in its momentum would be:

  1. zero .

  2. ∆p ≥ h / 4π .

  3. ∆p < h / 4 π .

  4. Infinite .


Correct Option: D
Explanation:

This option is correct because uncertainity principal states that the minimun uncertainity will be  h / 4 π . Hence, if uncertainity in one quantity is 0 then uncertainty of other quantity must be infinite . Hence, this option is correct .

The quantum number value for the designation 3d are ?

  1. n = 2 , m = - 3 .

  2. n = 3 , l = 3 .

  3. n = 4 , l = 1 .

  4. n = 3 , l = 2 .


Correct Option: D
Explanation:

this option is correct because , l value of ' d ' orbital is 2 hence this option is correct .

With increasing principle quantum number, the energy diffrence betwen adjacent energy levels in H - atoms ?

  1. Decreases

  2. Increases

  3. Remain constant

  4. Decreses for low value of Z and increases for higher value of Z .


Correct Option: A
Explanation:

This option is correct because ,

energy is given by , En = -13.6 / n2 eV / atom .

En -En-1 = -13.6 [ (1 / n2 ) - (1 / (n-1)2 ) ] .

This diffrence is decreases with the increase in value of ' n ' .

Hence, this option is correct .

When azimuthal quantum number l = 1 , the shape of the orbital will be ?

  1. spherical .

  2. Dumb- bell .

  3. Double dumb - bell .

  4. more complicated .


Correct Option: B
Explanation:

this option is correct because , ' p ' orbital shows this shape whose l value is  = 1  . hence this option is correct .

Which of the folowing sets of quantum numbers belongs to highest energy ?

  1. n = 4 , l = 0 , m = 0 , s = + 1/ 2 .

  2. n = 3 , l = 0 , m = 0 , s = + 1/ 2 .

  3. n = 3 , l = 1 , m = 1 , s = + 1/ 2 .

  4. n = 3 , l = 2 , m = 1 , s = + 1/ 2 .


Correct Option: D
Explanation:

this option is incorrect because , according to n+l rule , highest energy is possesed by that set which has highest value of n + l . so , in this case , n = 3 , l = 2 . hence n+l = 5 . which is not the highest among the options . hence this option is incorrect .

The maximum number of electons in p - orbital with n = 6 , m = 0 is ?

  1. 2 .

  2. 6 .

  3. 8 .

  4. 18 .


Correct Option: A
Explanation:

this option is correct because , each value of m implies 1 orbital and each orbital can only accommodate 2 electrons . hence this option is correct .

For ' d ' orbital , the value of m are ?

  1. -2 , -1 , 0 , 1 , 2 .

  2. 0 .

  3. 0 , 1 , 2 .

  4. -3 ,-2 , -1 , 0 , 1 , 2 , 3 .


Correct Option: A
Explanation:

this option is correct because , value of ' m '  are from  - l to  + l including 0 . and l value of ' d ' orbital is 2 . hence this option is correct .

The quantum number for the outer electrons of an atom are given by n = 2 , l = 0 , m = 0 , s = + 1 / 2 . ?

  1. lithium .

  2. beryllium .

  3. hydrogen .

  4. boron .


Correct Option: A
Explanation:

this option is correct because , lithium has electronic configuration - 1s2 2s1 . hence according  to the question n = 2 means principle quantum number is 2  . l =0 means ' s ' orbital . s = + 1 / 2 means 1 electrons . all these characters are exhibited by lithium . therefore this option is correct .

For how many orbitals , the quantum number n = 3 , l = 2 , m = + 2 are possible ?

  1. 1 .

  2. 3 .

  3. 2 .

  4. 9 .


Correct Option: A
Explanation:

this option is correct because , for every value of  ' m ' only one orbital exist  . hence this option is correct  .

Which of the following electronic configuration is not possible ?

  1. 1s2 2s2 2p6 .

  2. 1s2 2s2 2p7 .

  3. 1s2 2s2 .

  4. 1s2 2s2 2p5 .


Correct Option: B
Explanation:

this option is correct because , p subshell has 3 orbital each can accommodate 2 electrons hence ' p '  orbital can accommodate 6 electrons . in this case p has 7 electrons . hence this statement is wrong and therefore  this option is correct .

Two electrons in the same atomic orbital can be distinguished by their ?

  1. principal quantum number .

  2. orbital quantum number .

  3. magnetic quantum number .

  4. spin quantum number .


Correct Option: D
Explanation:

this option is correct because , according to pauli exclusion principal - no two electrons in an atom can have same sets of 4 quantum number . this shows that no 2 electrons in an atom are alike or orbital can be accommodate a maximum of two electrons that too with opposite spin . hence this option is correct .

The correct set of quantum number for 4d - electrons is ?

  1. n= 4 , l = 3 , m = 2 , s = +1 / 2 .

  2. n= 4 , l = 2 , m = 1 , s = 0 .

  3. n= 4 , l = 3 , m = - 2 , s = +1 / 2 .

  4. n= 4 , l = 2 , m = 1 , s = +1 / 2 .


Correct Option: D
Explanation:

this option is correct because , l value 2 is shown by ' d ' orbital . this configuration represent an electron in 4d   orbital . hence this option is correct .

Which is incorrect about primary standard?

  1. They are hygroscopic and deliquescent

  2. They are stable in air.

  3. They exist in highly pure state.

  4. They readily dissolve in water.


Correct Option: A
Explanation:

This option is correct as we know that primary standards are neither hygroscopic nor deliquescent. This can be explained as follows: these are the reagents whose weight is true representative of the number of moles of the substance contained so if they would have been hygroscopic or deliquescent then they will undergo some change in their properties and will not represent the true no. of moles of the substance contained and hence these substances cannot be deliquescent of hygroscopic. Hence, this option is correct.

The ratio of the ionisation energy of 1st bohr's orbit of H atom and Be+3 is ?

  1. 1 / 16 .

  2. 1 / 4 .

  3. 1 / 9 .

  4. 1 / 25 .


Correct Option: A
Explanation:

this option is correct because , E1 / E2 = Z12 / Z22 x n22 / n12  . since n values is 1 in this question . and  Z1 = 1 ,  Z2 = 4 . E1 / E2 = 1 / 16 . hence this option is correct  . 

The indicator used in titrating oxalic acid with caustic soda solution is

  1. methyl orange

  2. Methyl red

  3. Fluorescein

  4. Phenolphthalein


Correct Option: D
Explanation:

This option is correct and can be explained as follows: In titration, between oxalic acid and caustic soda of sodium hydroxide we find that oxalic acid is weak acid while caustic soda is a strong base hence equivalence point will lie at pH above 8 or basic. We know that phenolphthalein gives a transition from colourless to fuchsia colour at pH above 8.2. Hence, we can use phenolphthalein indicator for this reaction.

Which indicator is used in the titration of sodium carbonate with hydrocholric acid taken in burette?

  1. Phenolphthalein for first equivalence point and methyl orange for second equivalence point

  2. Methyl orange for first equivalence point and phenolphthalein for second equivalence point

  3. Either methyl orange or phenolphthalein for both equivalence points

  4. Thymol blue for both equivalence points


Correct Option: A
Explanation:

This option is correct and can be explained a follows: In the titration of sodium carbonate with hydrochloric acid, first equivalence point appears at pH of about 8.3 and we know that phenolphtahein turns from colourless to fuchsia color at pH>8.2, hence phenolphthalein is used as an indicator for the first equivalence point whereas second equivalence point appears at pH of about 3.9 hence we use methyl orange as indicator for second equivalence point.

Which of the following indicators should be used for titration of NH4OH with HCl solutions?

  1. Methyl orange

  2. Phenolphthalein

  3. Thymol blue

  4. Alizarin yellow


Correct Option: A
Explanation:

Titration of NH4OH (weak base) with HCl (strong acid) solution results in acidic solution at equivalence point. Hence, methyl orange can be used as indicator which changes colour in pH range of 3.1 to 4.4.

Bromothymol is used as an indicator in titration between

  1. strong base & weak acid

  2. strong base & strong acid

  3. weak base & strong acid

  4. it can be used as indicator in any of the cases


Correct Option: B
Explanation:

For choosing an indicator in titration, we must note that pK (indicator) = pH of solution at equivalence point. pK value of bromothymol is 7.0 and pH value of solution at equivalence in titration of strong acid vs strong base is also 7.0, hence bromothymol is used as an indicator in reaction between strong base and strong acid.

For a given principal level n= 4 , the energy of its sub shell is of the order ?

  1. s < p < d < f .

  2. s < p > d < f .

  3. s > p > d > f .

  4. s = p = d = f .


Correct Option: A
Explanation:

This option is correct because , from n + l  rule . higher the value of this term higher is the energy . Now n value is 4 in this case . and l values are in the order of  s ( 0 ) < p ( 1 ) < d ( 2 ) < f ( 3 ) . Therefore, the correct order  is  s < p < d < f . Hence, this option is correct .

Principal quantum number ' n ' describes ?

  1. shape of the orbital .

  2. subshell .

  3. Main energy shell of electron .

  4. spin of electrons .


Correct Option: C
Explanation:

this option is correct because , energy is given by , E = -(13.6 Z2 ) / n2 . hence energy is dependent on principal quantum number . hence this option is correct .

4 f orbital has:

  1. one node .

  2. two nodes .

  3. three nodes .

  4. four nodes .


Correct Option: C
Explanation:

This option is correct becausI radial node = n - l -1 . planar node =  l . total nodes = n - 1 . in this case n = 4, hence, total number nodes = 3 .

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