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Mixed Chemistry Test

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Which one of the following statements is matched to hypotonic solution?

  1. The solution which has lower concentration

  2. The solution of higher concentration

  3. The solution which has the same osmotic pressure

  4. The solution which obeys Raoult's law at all concentrations

  5. None of these


Correct Option: A
Explanation:

This option is correct because when a solvent with lower concentration is added into a cell, the cell usually swells up because the solvent molecules enter the cell gap through the cell wall from the solution of lower concentration.

Which of the following compounds gives the iodoform test?

  1. 3-Pentanone

  2. 2-Pentanone

  3. Nitrobenzene

  4. Aniline

  5. Both (3) and (4)


Correct Option: B
Explanation:

This option is correct because the oxidation of the reaction of methyl ketones with halogen, in the presence of an alkali, gives haloform. Hence, 2-pantanone gives the iodoform test.

Which one of the following amino acids contains the thoil group?

  1. Cystein

  2. Proline

  3. Alanine

  4. Asparagine

  5. Glycine


Correct Option: A
Explanation:

This option is correct because cystein is an amino acid.which contains the thiol group along the side chain. This group participates in the enzymatic reaction and behaves as a nucleophile.

Which of the following statements is incorrect about liquid SO2?

  1. SO2(liq) is used as a non-aqueous solvent.

  2. SO2(liq) is a good solvent for phosphorus, iodine, sulphur, etc.

  3. SO2(liq) is used in antirefrigerating agent.

  4. Both (1) and (2) are correct.

  5. None of these


Correct Option: C
Explanation:

This option is correct because sulphur dioxide liquid has a high latent heat of vapourisation and hence, is used as a refrigerating agent. 

Which of the following compounds belongs to aziridine?

  1. Chlorophenamine

  2. Impramine

  3. Chloprazine

  4. Ethylene imine

  5. Ethylamine


Correct Option: D
Explanation:

This option is correct because aziridine is a three-membraned heterocyclic compound and this compound is less basic than acyclic aliphatic amine.

Which of the following types of smell is produced by ethyl acetate?

  1. Fruity smell

  2. Gasoline smell

  3. Flowering smell

  4. Vinegar smell

  5. None of these


Correct Option: A
Explanation:

This option is correct because when liquid acetic acid is mixed with ethanol and a drop of concentrated sulphuric acid, it forms ethyl acetate which emits a fruity odour.

Caprolactam is obtained from

  1. hexane

  2. adipic acid and hexamethylene diamine

  3. adipic acid

  4. cyclohexane

  5. None of these


Correct Option: D
Explanation:

This option is correct because cyclohexane is mainly used for the industrial production of adipic acid and caprolactam which are the precursors of nylon.

When para-nitroso N,N dimethyl aniline is decomposed in the presence of a caustic soda, which of the following is formed?

  1. Trimethyl amine and methyl alcohol

  2. Only dimethyl nitrosoamine

  3. Dimethyl amine and Para-nitrosophenol

  4. Only dimethyl amine

  5. None of these


Correct Option: C
Explanation:

This option is correct because when para-nitroso N,N dimethyl amine is decomposed with caustic soda, it forms dimethyl amine and para-nitrosophenol.

What is Vitamin H called?

  1. Thiamine

  2. Cyanocobalamine

  3. Riboflavin

  4. Pyridoxine

  5. Biotin


Correct Option: E
Explanation:

This option is correct because bioten is also called Vitamins H or coenzyme R. It is composed of ureido biotin and is necessary for cell growth and the production of fatty acid as well as the metabolism of fats and amino acid.

Which of the following is the chemical formula of superphosphate?

  1. Ca(H2PO4)2, CaSO4.2H2O

  2. Ca3(PO4)3

  3. Ca(NO3)2, NH4NO3

  4. Ca(H2PO4)2

  5. None of these


Correct Option: A
Explanation:

This option is correct because when calcium phosphate is heated with concentrated H2SO4, it forms a mixture of primary phosphates of calcium and gypsum. Hence, it is called the superphosphate of lime.

Which of the following statements is correct about isochlorogenic acid?

  1. Isochlorogenic is an important intermediate in lignin biosynthesis.

  2. Isochlorogenic acid also gives the laxative effect.

  3. It gives caffice acid and (-)-quinic acid.

  4. It can be found in coffee.

  5. Both (2) and (3)


Correct Option: D
Explanation:

This option is correct because the isomer containing two caffice acid molecules is called the isochlorogenic acid. It can be found in coffee.

Choose the suitable compound formed, when urea and hydrazine react at 100oC.

  1. Semicarbazide

  2. Barbeturic acid

  3. Biuret

  4. Dimethyl urea

  5. Methylol urea


Correct Option: A
Explanation:

This option is correct because when urea reacts with hydrazine at 1000C, semicarbazide is formed.

Niacin behaves as

  1. carbohydrate

  2. protein

  3. fat

  4. vitamin

  5. Both (1) and (2)


Correct Option: D
Explanation:

This option is correct because niacin is called as vitamins B3 or nicotinic acid.

When glucose is added in monolignol, which of the following reaction takes place?

  1. Monolignol forms phenyl propane

  2. Monolignol polymerised

  3. Monolignol forms lignin

  4. Reduces toxicity

  5. None of these


Correct Option: D
Explanation:

This option is correct because glucose is added in monolignol to make it water soluble and reduce its toxicity.

Which of the following pairs of the silicates compounds is called the ortho silicates?

  1. Be2SiO4, Ca3Si3O9

  2. BaTi(Si3O9), Be3Al2Si6O18

  3. LiAl(SiO3)2, MgSiO3

  4. Zn2SiO4, Mg2SiO4

  5. Both (1) and (2)


Correct Option: D
Explanation:

This option is correct because these silicate compounds are simple silicates, which contain discrete SiO4-4 tetrahedral unit. SiO4-4 tetrahedral do not share an oxygen atom with another. Hence, both the units of the silicates are matched to the ortho silicates.

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