Atom Economy

Description: Atom economy is a measure of the efficiency of a chemical reaction in terms of the amount of starting materials that are converted into the desired product. It is calculated as the ratio of the molecular weight of the desired product to the total molecular weight of all the reactants.
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What is the definition of atom economy?

  1. The ratio of the molecular weight of the desired product to the total molecular weight of all the reactants

  2. The amount of starting materials that are converted into the desired product

  3. The efficiency of a chemical reaction in terms of the amount of starting materials that are converted into the desired product

  4. The ratio of the molecular weight of the desired product to the molecular weight of the starting materials


Correct Option: A
Explanation:

Atom economy is a measure of the efficiency of a chemical reaction in terms of the amount of starting materials that are converted into the desired product. It is calculated as the ratio of the molecular weight of the desired product to the total molecular weight of all the reactants.

What is the goal of atom economy?

  1. To maximize the amount of starting materials that are converted into the desired product

  2. To minimize the amount of waste that is produced

  3. To reduce the energy consumption of a chemical reaction

  4. All of the above


Correct Option: D
Explanation:

The goal of atom economy is to maximize the amount of starting materials that are converted into the desired product, minimize the amount of waste that is produced, and reduce the energy consumption of a chemical reaction.

What are some factors that affect atom economy?

  1. The type of reaction

  2. The reaction conditions

  3. The catalyst used

  4. All of the above


Correct Option: D
Explanation:

Atom economy is affected by a number of factors, including the type of reaction, the reaction conditions, and the catalyst used.

How can atom economy be improved?

  1. By using more efficient catalysts

  2. By using milder reaction conditions

  3. By using more selective reagents

  4. All of the above


Correct Option: D
Explanation:

Atom economy can be improved by using more efficient catalysts, milder reaction conditions, and more selective reagents.

What are some examples of reactions with high atom economy?

  1. The Diels-Alder reaction

  2. The Heck reaction

  3. The Suzuki reaction

  4. All of the above


Correct Option: D
Explanation:

The Diels-Alder reaction, the Heck reaction, and the Suzuki reaction are all examples of reactions with high atom economy.

What are some examples of reactions with low atom economy?

  1. The combustion of hydrocarbons

  2. The hydrolysis of esters

  3. The Friedel-Crafts reaction

  4. All of the above


Correct Option: D
Explanation:

The combustion of hydrocarbons, the hydrolysis of esters, and the Friedel-Crafts reaction are all examples of reactions with low atom economy.

Why is atom economy important?

  1. It helps to reduce waste

  2. It helps to reduce energy consumption

  3. It helps to reduce the environmental impact of chemical reactions

  4. All of the above


Correct Option: D
Explanation:

Atom economy is important because it helps to reduce waste, reduce energy consumption, and reduce the environmental impact of chemical reactions.

How is atom economy calculated?

  1. By dividing the molecular weight of the desired product by the total molecular weight of all the reactants

  2. By dividing the molecular weight of the starting materials by the molecular weight of the desired product

  3. By multiplying the molecular weight of the desired product by the total molecular weight of all the reactants

  4. By subtracting the molecular weight of the starting materials from the molecular weight of the desired product


Correct Option: A
Explanation:

Atom economy is calculated by dividing the molecular weight of the desired product by the total molecular weight of all the reactants.

What is a good atom economy?

  1. Greater than 90%

  2. Between 70% and 90%

  3. Between 50% and 70%

  4. Less than 50%


Correct Option: A
Explanation:

A good atom economy is greater than 90%.

What is a poor atom economy?

  1. Greater than 90%

  2. Between 70% and 90%

  3. Between 50% and 70%

  4. Less than 50%


Correct Option: D
Explanation:

A poor atom economy is less than 50%.

What is the atom economy of the following reaction? $$CH_3CH_2OH + HCl → CH_3CH_2Cl + H_2O$$

  1. 63.6%

  2. 78.6%

  3. 85.7%

  4. 92.8%


Correct Option: A
Explanation:

The atom economy of the reaction is calculated as follows: $$Atom economy = rac{Molecular weight of CH_3CH_2Cl}{Molecular weight of CH_3CH_2OH + HCl} = rac{64.5}{46.0 + 36.5} = 0.636$$ Therefore, the atom economy of the reaction is 63.6%.

What is the atom economy of the following reaction? $$C_6H_6 + 3Cl_2 → C_6H_6Cl_6$$

  1. 18.2%

  2. 27.3%

  3. 36.4%

  4. 45.5%


Correct Option: A
Explanation:

The atom economy of the reaction is calculated as follows: $$Atom economy = rac{Molecular weight of C_6H_6Cl_6}{Molecular weight of C_6H_6 + 3Cl_2} = rac{290.8}{78.1 + 213.0} = 0.182$$ Therefore, the atom economy of the reaction is 18.2%.

What is the atom economy of the following reaction? $$2C_2H_5OH + 3O_2 → 4CO_2 + 6H_2O$$

  1. 90.9%

  2. 81.8%

  3. 72.7%

  4. 63.6%


Correct Option: A
Explanation:

The atom economy of the reaction is calculated as follows: $$Atom economy = rac{Molecular weight of 4CO_2 + 6H_2O}{Molecular weight of 2C_2H_5OH + 3O_2} = rac{176.0 + 108.0}{92.1 + 96.0} = 0.909$$ Therefore, the atom economy of the reaction is 90.9%.

What is the atom economy of the following reaction? $$CH_4 + 2O_2 → CO_2 + 2H_2O$$

  1. 33.3%

  2. 44.4%

  3. 55.5%

  4. 66.6%


Correct Option: A
Explanation:

The atom economy of the reaction is calculated as follows: $$Atom economy = rac{Molecular weight of CO_2 + 2H_2O}{Molecular weight of CH_4 + 2O_2} = rac{44.0 + 36.0}{16.0 + 64.0} = 0.333$$ Therefore, the atom economy of the reaction is 33.3%.

What is the atom economy of the following reaction? $$2C_6H_5CH_3 + 3O_2 → 12CO_2 + 6H_2O$$

  1. 77.8%

  2. 88.9%

  3. 99.0%

  4. 110.1%


Correct Option: A
Explanation:

The atom economy of the reaction is calculated as follows: $$Atom economy = rac{Molecular weight of 12CO_2 + 6H_2O}{Molecular weight of 2C_6H_5CH_3 + 3O_2} = rac{528.0 + 108.0}{182.2 + 96.0} = 0.778$$ Therefore, the atom economy of the reaction is 77.8%.

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