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Group 16 elements - general properties - class-XII

Description: group 16 elements - general properties
Number of Questions: 61
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Tags: chemistry biology the p-block elements natural resources - air, water and land p- block elements-ii metallurgy p-block elements
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Group 16 elements have a lower value of first ionization enthalpy as compared to group 15 elements because:

  1. half filled p-orbitals in group 15 elements are more stable

  2. group 16 elements have smaller size than group 15 elements

  3. group 16 elements contain double bond while group 15 elements have a triple bond

  4. group 16 elements have more number of electrons in p-orbitals


Correct Option: A
Explanation:

Group 16 elements have a lower value of first ionization enthalpy as compared to group 15 elements. As group 15 elements have half filled p-orbital due to which group 15 have got extra stability.

_______ group elements are known as chalcogens.

  1. VIA

  2. VA

  3. Zero

  4. None of these


Correct Option: A
Explanation:

VIA group or Group 16 elements belong to the oxygen family are also called chalcogens. The name is derived from the Greek word 'chalcos', which means 'ore' and 'gen', which means 'formation'. 

A group 16 element exists in the monoatomic state in the metallic lattices. It also exists in two crystalline forms. The metal is:

  1. Po

  2. S

  3. Se

  4. Te


Correct Option: A
Explanation:

polonium has two metallic allotropes, the $\alpha $ atom has the simple cubic structure in a single atom basis at STP and $\beta $ atom of it has rhombohedral structure. Po belongs to group 16.

Arrange the following elements in order of their increasing ionisation energies $O, S, Se, Te, Po$ :

  1. $Se, Te, S, Po, O$

  2. $O, S, Se, Te, Po$

  3. $Po, Te, Se, S, O$

  4. $Te, O, S, Po, Se$


Correct Option: C
Explanation:

Ionisation energy decreases from top to bottom in a group. So increasing order will be
Po < Te < Se < S < O

Which is the following order is INCORRECT?

  1. ${ Na } _{ 2 }O<{ SiO } _{ 2 }<{ Cl } _{ 2 }{ O } _{ 7 }$ Acidic character order

  2. ${ PH } _{ 3 }<{ AsH } _{ 3 }<{ SbH } _{ 3 }$ basic character order

  3. ${ PH } _{ 3 }<{ AsH } _{ 3 }={ SbH } _{ 3 }$ acidic character order

  4. $I{ EA } _{ 1 }$>$I{ EA } _{ 2 }$>$I{ EA } _{ 1 }$ Successive electron affinity order.


Correct Option: B

Group $16$ element are called:

  1. Carbon family

  2. Chalcogen family

  3. Halogen family

  4. Nitrogen family


Correct Option: B
Explanation:
The chalcogens are the chemical elements in the group $16$ of the periodic table. 

This group is also known as the oxygen family. It consists of the elements oxygen, sulfur, selenium, tellurium, and the radioactive element polonium. 

Hence, the correct answer is option $B$.

Which of the following is not a chalcogen?

  1. $Se$

  2. $O$

  3. $S$

  4. $Na$


Correct Option: D
Explanation:

Oxygen family is known as the chalcogen group.


So, $Na$ is not a chalcogen as it belongs to the alkali metal family.

Therefore, correct option is D.

Oxygen is the most abundant metal in the earth's crust.
  1. True

  2. False


Correct Option: B
Explanation:

Aluminum is the most abundant metal in the earth's crust. Oxygen is not a metal.

Which of the following sets of atomic numbers belongs to chalcogens?

  1. 8, 52, 84

  2. 9, 17, 35

  3. 20, 37, 56

  4. 14, 32, 50


Correct Option: A
Explanation:



$\underset{VI group elements so belongs to chalcogens}{\underbrace{  8:oxygen   52:Tellurium   84:Polonium}} $

Which of the following VIA group element has maximum catenation capacity?

  1. S

  2. O

  3. Se

  4. Te


Correct Option: A
Explanation:

In VI group elements sulphur shows maximum no of valencies:-2,4,6

$\because $ Catenation properties is also dependent in valency 

$\therefore $ Extent of catenation:-$S>Se>O>Te$

The element with highest boiling point in the following is :

  1. Oxygen

  2. Sulphur

  3. Tellurium

  4. Polonium


Correct Option: C
Explanation:

Boiling point is a physical property so depends on van der waal forces of attraction and van der waal forces $\propto$ molecular mass $\propto$ High boiling point
$\therefore $ Boiling point order :- $Te > Se > S > O$

Which of the following is a true Chalcogen:

  1. Nitrogen

  2. Oxygen

  3. Polonium

  4. Chlorine


Correct Option: B
Explanation:


Chalcogen is VI group (Oxygen family)
having elements:-
                 O
                  S
                  Se
                   Te
                    Po

Potassium nitrate decomposes above $336^oC$ to give

  1. $NO _2$

  2. $N _2$

  3. $O _2$

  4. $NO$


Correct Option: C
Explanation:

$2KNO _3\overset{\Delta}{\rightarrow}2KNO _2+O _2\uparrow$

Joseph Priestley discovered oxygen.

  1. True

  2. False


Correct Option: A
Explanation:

Priestley discovered oxygen gas in 1774. When he heated mercuric oxide, he found that a gas was released that could reignite a glowing splinter. This gas was oxygen.

During the experiment done by Antonie Lavoisier for discovery of oxygen, the level of mercury in the bell jar rose by:

  1. one-tenth

  2. one-third

  3. half

  4. one-fifth


Correct Option: D
Explanation:

The level of mercury in the bell jar rose by one-fifth during the experiment performed by Antonie Lavoisier.

What was the observation made by Joseph Priestley during the experiment done for discovery of oxygen?

  1. A coloured gas is collected in the jar

  2. A colourless gas is collected in the jar

  3. No gas is collected in the jar

  4. None of the above


Correct Option: B
Explanation:

During the experiment performed by Joseph Priestley, the observation was that a colourless gas is collected in the jar i.e oxygen.

The things or apparatus not used by Joseph Priestley was:

  1. sun rays

  2. mercuric oxide

  3. convex lens

  4. bell jar


Correct Option: D
Explanation:

Joseph Priestley did not use bell jar in his experiment.

During discovery of oxygen by Joseph Priestley, which compound was heated by focusing the sun rays on it?

  1. Silver oxide

  2. Mercuric oxide

  3. Zinc oxide

  4. Calcium oxide


Correct Option: B
Explanation:

During discovery of oxygen, mercuric oxide was heated by focusing the sun rays on it.

Who was the first scientist who named the oxygen gas?

  1. William Scheele

  2. Priestley

  3. Antoine Lavoisier

  4. None of the above


Correct Option: C
Explanation:

Antonie Lavoisier was the first scientist who named oxygen gas.

Oxygen has ______________ number of electrons in the outermost shell. 

  1. $6$

  2. $7$

  3. $8$

  4. $9$


Correct Option: A
Explanation:

Oxygen has $6$ electrons in the outermost shell. Its configuration is $2,6$.

If a species has $16$ protons, $18$ electrons and $16$ neutrons, find the species and its charge.

  1. $S^{1-}$

  2. $Si^{2-}$

  3. $p^{3-}$

  4. $S^{2-}$


Correct Option: D
Explanation:


$16p$ means $Z=16$

$18e$ means $2$ unit negative charge is present.

Hence, species is $S^{2-}$.

Which of the following is the correct order of melting points of group $16$ elements?

  1. $O<S<Se<Te<Po$

  2. $O<Se<S<Te<Po$

  3. $O < S < Se < Te > Po$

  4. $O < S < Se >Te < Po$


Correct Option: C

Only one element of _______form hydride.

  1. group 6

  2. group 7

  3. group 8

  4. group 9


Correct Option: A
Explanation:

Only one element of chromium from group $6$,that is $CrH$.

So,the answer is only one element of group $6$ forms hydrites.
These type of hybrides are classified into metalic or non-stoichiometric type of hydrides.

The smog is essentially caused by the presence of 

  1. $ \mathrm { O } _ { 2 } \text { and } \mathrm { O } _ { 3 } $

  2. $ O _ { 3 } \text { and } N _ { 2 } $

  3. Oxides of sulphur and nitrogen

  4. $ O _ { 2 } \text { and } N _ { 2 } $


Correct Option: C
Explanation:

The atmospheric pollutants or gases that form smog are released in the air when fuels are burnt. When sunlight and its heat react with these gases and fine particles in the atmosphere, smog is formed. It is purely caused by air pollution. Ground level ozone and fine particles are released in the air due to complex photochemical reactions between volatile organic compounds (VOC), sulfur dioxide (SO2) and nitrogen oxides (NOx).

These VOC, SO2, and NOx are called precursors. The main sources of these precursors are pollutants released directly into the air by gasoline and diesel-run vehicles, industrial plants and activities, and heating due to human activities

In which one of the following reactions, a 16 group element will get precipitated ?

  1. $ Na _2S _2O _3 + CI _2+H _2O \longrightarrow $

  2. $ Na _2SO _3 - CI _2+H _2O \longrightarrow $

  3. $ SO _2+2H _2O+CI _2 \longrightarrow $

  4. $ 2FeSO _4+H _2SO _4+CI _2 \longrightarrow $


Correct Option: A

The one with lowest electron affinity in group 16 is 

  1. Oxygen

  2. Sulphur

  3. Selenium

  4. Tellurium


Correct Option: A

Which of the following bonds has the least energy?

  1. $Se-Se$

  2. $Te-Te$

  3. $S-S$

  4. $O-O$


Correct Option: B
Explanation:

As we move down the group, size increases and because of that M-M bond become weaker and Te-Te have least bond energy.

Among $CH _4, NH _3$ and $H _2O$, acidity of $H _2O$ is maximum because :

  1. Oxygen contains two lone pairs of electrons.

  2. Bond angle on $H _2O$ is less than $109^{\small\circ}28'$ due to $VSEPR$.

  3. Oxygen is more electronegative than $C$ or $N$.

  4. $H _2O$ is an associated liquid.


Correct Option: C
Explanation:

As oxygen is more electronegative so conjugate base in case of $H _2O$ is more stable and it is more basic than others.


The electronegativity increases along the period. Acidity of hydrides of corresponding elements also increase with increase in electronegativity of these elements. 

Identify the group 16 $(VI\space A)$ elements which is the most electronegative ?

  1. $ O $

  2. $ S $

  3. $ Te$

  4. $ Po $


Correct Option: A
Explanation:

All theses O,S,Se,Te,Po are group 16 elements from top to bottom.As we move from top to bottom in a group as the size increses the electronegativity  decreases.So most electronegative element is Oxygen
The order of electronegativity is O>S >Se>Te.Po.
Hence option A is correct.

State true or false.

Sulphur is an insulator while selenium and tellurium are semiconductors.
  1. True

  2. False


Correct Option: A
Explanation:

The trend from nonmetallic to metallic character upon going down the group is exemplified by the conductivities of these elements. Sulphur is an insulator, selenium and tellurium are semiconductors.


In addition, the conductivities of sulphur, selenium, and tellurium increase with increasing temperature, behaviour typical of non-metals.

Name of the group-16 element which shows maximum catenation.

  1. Oxygen

  2. Sulphur

  3. Selenium

  4. Tellurium


Correct Option: B
Explanation:

The greater the element-element bond strength, the higher is the tendency towards catenation. 

As the size increases from S to Te, the bond dissociation energy decreases. O - O bond energy is, however, smaller than that of S-S because of inter electronic repulsions within the smaller size of oxygen atoms. 

Thus, sulphur has a maximum tendency towards catenation.

In 16 group element, sulphur, selenium and tellurium are respectively :

  1. Insulator, Semiconductors and Semiconductor.

  2. Semiconductors , Insulator and Insulator.

  3. Insulator, Insulator and Semiconductor.

  4. Semiconductors, Insulator and Semiconductor.


Correct Option: A
Explanation:
 Sulphur is non metal.It has the properties of poor conductor of both heat and electricity.It is weak,dull and can be easily breakable.

As we  move from top to bottom in  group the conductivity of elements increases so the sulfur, selenium  and tellurium are Insulator, Semiconductors and Semiconductors respectively.

Hence option A is correct.

Which of the following bonds has the highest energy?

  1. Se-Se

  2. Te-Te

  3. S-S

  4. O-O


Correct Option: C
Explanation:

Due to lower size and less electron-electron repulsion, S-S have highest bond energy.

An element X forms an oxide $XO _3$. What is the valency of X?

  1. 1

  2. 2

  3. 3

  4. 6


Correct Option: D
Explanation:

Valency of Oxygen is 2

The colour of mercuric oxide is:

  1. blue

  2. pink

  3. red

  4. black


Correct Option: C
Explanation:

Mercuric chloride is red in colour.

As many as ______ different combinations of water are possible from $H _1^1, H _1^2, H _1^3, O _8^{16}, O _8^{17}, O _8^{17}$ ?

  1. $16$

  2. $5$

  3. $18$

  4. $24$


Correct Option: C
Explanation:

Different combinations can be used in the preparation of water. Using these isotopes, a total of 18 combinations are possible. At first it might seem that kinds of water with the chemical structure $H _2O$ based on isotope differences only, are 9 in number:

$H^1 _2O^{16}, H^2 _2O^{16}, H^3 _2O^{16},$
$H^1 _2O^{17},H^2 _2O _{17},H^3 _2O^{17},$
$H^1 _2O^{17}, H^2 _2O^{18}, and H^3 _2O^{18}$

However, there are actually 18 differing isotope kinds of water. This is because each of the two hydrogen atoms in a particular molecule can be a different isotope, giving these 9 additional varieties of water:

$H^1H^2O^{16}, H^1H^3O^{16}, H^2H^3O^{16},$
$H^1H^2O^{17}, H^1H^3O^{17}, H^2H^3O^{17},$
$H^1H^2O^{18}, H^1H^3O^{18}, and H^2H^3O^{18}$

Assertion: Dinegative anion of oxygen $(O^{2-})$ is quite common but dinegative anion of sulfur $(S^{2-})$ is less common.

Reason: Covalency of oxygen is two.

  1. If both assertion and reason are true and the reason is a correct explanation of the assertion

  2. If both assertion and reason are true but reason is not a correct explanation of the assertion

  3. If the assertion is true but reason is false.

  4. If both the assertion and reason are false

  5. If the assertion is false but the reason is true


Correct Option: B
Explanation:

Usually, oxygen forms 2 bonds. So the covalency of oxygen is 2 as in $H _2O$. 


Oxygen is the second most electronegative element after fluorine. So, it can easily gain electrons to form dinegative anion ($O^{2-}$) while sulphur is not so electronegative element as oxygen.

Therefore dinegative anion of oxygen is common because of high electron gain enthalpy.

All the elements of oxygen family are:

  1. non-metals

  2. metalloid

  3. radioactive

  4. polymorphic


Correct Option: A,D
Explanation:

All the elements of oxygen family exist in more than one form (polymorphic).

The allotrope of this element is the primary absorber of UV solar radiation in Earth's atmosphere. The element is:

  1. carbon

  2. nitrogen

  3. oxygen

  4. neon

  5. argon


Correct Option: C
Explanation:

Allotrope of oxygen which is known as ozone, is the primary absorber of UV radiation in arth's atmosphere.

All the elements in oxygen family are:

  1. Non-metal

  2. Mettaloids

  3. Radioactive

  4. Polymorphic


Correct Option: D
Explanation:

All the elements in oxygen family are polymorphic (Polymorphism is the ability a material to exist in two or more forms or crystalline structures of the same chemical compound or element).
Hence option D is correct.

Which of the element is most poisonous to human?

  1. $O$

  2. $S$

  3. $Se$

  4. None of above


Correct Option: C
Explanation:

The long-term intake of excessive selenium may involve either organic or inorganic forms in food or water. Which affects the human health adversely. So it ispoisonous.

Hence option C is correct. 

Oxygen was discovered by:

  1. Priestly

  2. Scheele

  3. Boyle

  4. Cavendish


Correct Option: A
Explanation:

Joseph Priestley discovered oxygen in 1774, he gave the answers why and how things burn.

Hence option A is correct.

Which element is not considered as chalcogen?

  1. Selenium

  2. Oxygen

  3. Sulphur

  4. Polonium


Correct Option: D
Explanation:

In group $16$, the oxygen, sulphur, selenium are called chalcogens (ore-forming) while polonium being radioactive forms a less number of compounds and is not considered as chalcogens.

Which of the following gas is heavier than air?

  1. $N _2$

  2. $O _2$

  3. $CO _2$

  4. $H _2$


Correct Option: B,C
Explanation:

The molecular weights of the $N _2,O _2,CO _2,H _2$ are 28,32,44,2 respectively

So $CO _2$ is heavier than air ($O _2$)
Hence option $C$ is correct.

Which of the following elements behaves as a typical non metal?

  1. S

  2. Se

  3. Te

  4. Po


Correct Option: A
Explanation:

In VI A group elements metallic properties increases down the group 
$\therefore $ O,S behave as typical non-metal.

Ozone belongs to which groups of the periodic table?

  1. IV

  2. V

  3. VI

  4. VII


Correct Option: C
Explanation:

$O _3$ is an allotrope of oxygen and hence, it belongs to VI A group.

Which of the following does not have oxygen?

  1. Glass

  2. Limestone

  3. Carbohydrates

  4. Ammonia


Correct Option: D
Explanation:

Glass is made up of silicates, limestone is calcium carbonate. Ammonia does not contain oxygen. 

Nearly half the mass of earth's crust is ________ .

  1. oxygen

  2. nitrogen

  3. hydrogen

  4. none of the above


Correct Option: A
Explanation:

Nearly half the mass of earth's crust is oxygen in the form of silicates, limestone, metallic nitrates. 

Occurrence of oxygen is in:

  1. silicates

  2. pencil lead

  3. ammonia

  4. carbohydrates


Correct Option: A,D
Explanation:

Oxygen occurs in silicates and carbohydrates. 

________ bacteria are microbes that work in the absence of oxygen.

  1. Anaerobic

  2. Aerobic

  3. Gram-positive 

  4. Gram-negative


Correct Option: A
Explanation:
Anaerobic bacteria works in the absence of oxygen. 
Example is yeast.

What is the symbol for the element oxygen?

  1. $Os$

  2. $O$

  3. $Ox$

  4. $Ge$

  5. $N$


Correct Option: B
Explanation:
$O$ is the symbol for oxygen. It is having the atomic number 8. It is a highly reactive non  metal. It has oxidising nature.

Which one of the following elements is not detected by Lassaigne's test?

  1. Sulphur

  2. Nitrogen

  3. Oxygen

  4. Chlorine


Correct Option: C
Explanation:

It is a general test for the detection of halogens, nitrogen and sulphur in an organic compound. These elements are covalently bonded to the organic compounds. In order to detect them, these have to be converted into their ionic forms. This is done by fusing the organic compound with sodium metal. 

State True or False.
Before 1961, the atomic weight standard for elements was based on oxygen and not carbon.

  1. True

  2. False


Correct Option: A
Explanation:

True.

Before 1961, oxygen was used as the reference standard, with an assigned value of 16. The unit of atomic mass was thereby defined as $ 1/16$ the mass of an oxygen atom.

The most abundant non-metal in the earth's crust is:

  1. chlorine

  2. hydrogen

  3. silicon

  4. oxygen


Correct Option: D
Explanation:

Aluminium is the first most abundant metal while iron is the second most abundant metal on earth. It is the fourth most common element in the earth's crust. Oxygen is the most abundant non metal and second is silicon present on earth's crust.

The element name 'oxygen' comes from Greek words which means: 

  1. Fire-starter

  2. Rust

  3. Air

  4. Acid-producing


Correct Option: D
Explanation:

The element name "oxygen" came from the greek words $oxys$ and $genes$, which together mean $"acid \ forming"$.

Statement 1: By mass, oxygen is the most abundant element in the human body.
Statement 2: It is principally found as $O _2$ in the bloodstream.

  1. Both Statement 1 and Statement 2 are correct and Statement 2 is the correct explanation of Statement 1.

  2. Both Statement 1 and Statement 2 are correct, but Statement 2 is NOT the correct explanation of Statement 1.

  3. Statement 1 is correct, but Statement 2 is not correct.

  4. Statement 1 is not correct, but Statement 2 is correct.


Correct Option: C
Explanation:

By mass, oxygen is the most abundant element in the human body.

Oxygen is found in the human body as oxy-haemoglobin in the bloodstream but not as $O _2$

So statement 1 is correct but not 2.
Hence option C is correct.

Which of the following has highest ionic radius :

  1. $F^-$

  2. $B^{3+}$

  3. $O^{2-}$

  4. $Li^+$


Correct Option: C
Explanation:

Anions are of larger radius than neutral atom and smallest is cation
$O^{3-}  >  F^-  >  Li^+  >  Bi^{3+}$

Which of the following is illustration of pyrosilicate?

  1. Zircon

  2. Hemimorphite

  3. Beryl

  4. Asbestos


Correct Option: A
Explanation:
Zircon is a pyrosilicate named as Zirconium silicate whose chemical formula is  $ZrSiO _4$.Which is used  as gem stone.
Hence option  A is correct.

Chalcogens are :

  1. hydrocarbons

  2. ore forming elements

  3. oxide forming elements

  4. those having ability to catenate


Correct Option: B
Explanation:

The chalcogen means "ore former," derived from the Greek words chalcos ("ore") and -gen ("formation").

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