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Coordinate bond - class-IX

Description: coordinate bond
Number of Questions: 55
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Tags: chemical bonding and structure chemistry chemical bonding and molecular structure chemical bond and chemical equation
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During the formation of hydronium ion, water molecule acts as _______.

  1. solvent

  2. donor

  3. acceptor

  4. none of these


Correct Option: B
Explanation:

During the formation of hydronium ion, water molecule acts as donor.

A coordinate covalent bond is represented by an arrow from donor to acceptor.

  1. True

  2. False


Correct Option: A
Explanation:

Coordinate covalent bond is represented by an arrow from donor to acceptor.

Eg:NO $[NH _3 \to H]^+$
Coordinate covalent bond means donating a lone pair of electron of one atom to a vacant orbital of another atom.

Compounds having coordinate covalent bonds are:

    • $CO$
  1. $HNO _3$

  2. $NH _4^+$

  3. All of the above


Correct Option: D
Explanation:

Compounds having coordinate covalent bonds are $CO, HNO _3, NH _4^+$.

Addition of acid to water results in the formation of:

  1. $H _2O$

  2. $H _3O^+$

  3. both A and B

  4. none of the above


Correct Option: B
Explanation:

Addition of acid to water results in the formation of $H _3O^+$.

$H^++H _2O \rightarrow H _3O^+$

Which of the following types of solid is most likely to be soft, have low melting point and don't conduct electricity when melted?

  1. Ionic

  2. Molecular

  3. Covalent

  4. Metallic


Correct Option: C
Explanation:

Covalent compunds are soft(due to presence of cloud of electrons between the bonding atoms), have low melting point(due to weak forces of attraction) and are bad conductors of electricity in the molten state(due to lack of free electrons)

In the coordinate covalency,

  1. electrons are equally shared by the atoms

  2. electrons of one atom are shared between the two atoms

  3. hydrogen bond is formed

  4. none of the above


Correct Option: B
Explanation:

The 2 electrons of an atom( generally lone pair) is donated by one atom to the other atom and it results in the formation of a coordinate bond.

In which molecule co-ordinate bond is present ?

  1. $H _2O$

  2. $NH _3$

  3. $CH _3NO _2$

  4. $CCl _4$


Correct Option: B

During the formation of hydronium ion, water molecule acts as donor.

  1. True

  2. False


Correct Option: A
Explanation:

A hydronium ion is written as ${ H } _{ 3 }{ O }^{ + }$. 

It is formed when something else donates a proton, or $H^+$ to a water molecule.
The $H^+$ will easily bond to one of the two lone pairs of electrons around the water molecule.

     ${ H }^{ + }+{ H } _{ 2 }O\longrightarrow { H } _{ 3 }{ O }^{ + }$

Which response includes only the true statements concerning the characteristics of covalent compounds?
$I$. These compounds can be gases, liquids, or solids with low melting points.
$II$. Most are soluble in polar solvents.
$III$. Liquid and molten compounds do not conduct electricity.
$IV$. Aqueous solutions of these compounds are very good conductors of electricity.

  1. $I$ and $III$

  2. $II$ and $IV$

  3. $I,III$ and $IV$

  4. $I,II$ and $III$


Correct Option: D
Explanation:

I , II and III statement about covalent compounds are correct but the IV one is not correct since the aqueous solution of the covalent compound do not contain free ions and thus are not the good conductors of electricity .

The pH of pure water at 25°C and 35°C are 7 and 6 respectively. The heat of formation  of water from ${H^ - }$  and $O{H^ - }$ will be :

  1. -77.11

  2. -84.55

  3. -92.36

  4. -66.25


Correct Option: A

If pure $'p'$ orbitals are involved in molecule formation, then the shape of ${ H } _{ 3 }{ O }^{ + }$ will be:

  1. pyramidal

  2. tetrahedral

  3. angular

  4. planar


Correct Option: A
Explanation:

$ H _3O^+$ will have three bond pairs and one lone pair and shape same as $NH _3$ is therefore pyramidal. The hydroxonium ion is isoelectronic with ammonia and has an identical shape of pyramidal. 

So option $A$ is the correct option. 

The dative bond is present in:

  1. $NH _{3}$

  2. $NH _{4}Cl$

  3. $PCl _{5}$

  4. $BF _{3}$


Correct Option: A
Explanation:

When ammonium is formed, the fourth hydrogen is formed is attached by dative covalent bond because the only hydrogen nucleus is transferred from chlorine to nitrogen. The hydrogen electron left behind on the chlorine to form the negative chloride ion.

Which of the following property is commonly exhibited by a covalent compound?

  1. High solubility in water

  2. Low melting point

  3. High electrical conductance

  4. High boiling point


Correct Option: B
Explanation:

Covalent compounds are very resistant, they do not conduct heat and electricity, mostly insulators. They have low boiling points as they are gases at room temperature. It is very hard to molten the covalent compounds because of high bond energy. Therefore the covalent compound turns liquid from solid state easily. They show low melting points and are non polar hence insoluble in water.

"Hybridisation of central atom does not always change due to back bonding". This statement is valid for which of the following compounds ? 
(i) $CCl^- _3$                      (ii) $CCl _2$
(iii) $(SiH _3) _2 O$              (iv) $N(SiH _3) _3$

  1. (i), (ii)

  2. (i), (iii)

  3. (ii), (iii)

  4. All


Correct Option: A
Explanation:

When there is back bonding from central to side atom change in hybridization takes place. Back bonding takes place when one atom has vacant orbital and one has lone pairs. 
So central atom has a lone pair and side atom must have vacant orbital 
So : $CCl^- _3$
$N (SiH _3) _3$
$Sp^3 - Sp^2$

Which of the following compound has coordinate (dative) bond :

  1. $CH _3NC$

  2. $CH _3OH$

  3. $CH _3Cl$

  4. $NH _3$


Correct Option: D

Dative bond is present in ____________.

  1. Carbon monoxide

  2. Carbon dioxide

  3. Nitric oxide

  4. Dichlorine monoxide


Correct Option: A,C
Explanation:

Carbon monoxide and nitric oxide contains dative bond or coordinate covalent bond whereas carbon dioxide and dichlorine monoxide contains covalent bonds.

Which of the following molecules does not have co-ordinate bonds?

  1. $PH _{4}^{+}$

  2. $NO _2$

  3. $O _3$

  4. $CO _{3}^{2-}$


Correct Option: D

In the cyanide, the negative charge is on :

  1. $C$

  2. $N$

  3. both $C$ and $N$

  4. resonate between $C$ and $N$


Correct Option: A
Explanation:

Hetrolytic bond dissociation of $HCN$:
$H-CN\rightarrow H^++ ^-C\equiv N$.
So here, negative charge is on $C$.

Which of the following does not have coordinate bond? 

  1. $S{O _2}$

  2. $HN{O _3}$

  3. ${H _2}S{O _3}$`

  4. $HN{O _2}$


Correct Option: B

Co-ordinate covalent bond is formed by:

  1. transfer of electrons

  2. sharing of electrons

  3. donation of electrons

  4. none of these process


Correct Option: C
Explanation:

Both the electrons of a coordinate bond are donated by one atom, and then shared by both the atoms of the bond.

In potassium ferrocyanide, the nature of bond between iron and cyanide ions is :

  1. ionic bond

  2. covalent bond

  3. dative bond

  4. polar bond


Correct Option: C
Explanation:

In potassium ferrocyanide, iron atom has vacant orbitals and cyanide ions have unpaired electrons. Hence, in potassium ferrocyanide, the bond between iron and cyanide ions is dative bond.

Phosphorus forms a compound with hydrogen called phosphine, $PH _{3}$. This compound can react
with a hydrogen ion, $H^{+}$.
Which type of interaction occurs between $PH _{3}$ and $H^{+}$?

  1. Dative covalent bond

  2. Dipole- dipole forces

  3. Hydrogen bond

  4. Ionic bond


Correct Option: A
Explanation:

The bond formed between $P{H} _{3}$ and ${H}^{+}$ is dative covalent bond in which the bonding electrons are coming from phosphine.

Coordinate compounds are formed by

  1. Transfer of electrons

  2. Sharing of electrons

  3. Donation of electron pair

  4. None of these


Correct Option: C

Co-ordinate covalent compounds dissolve more in:

  1. polar solvents

  2. non polar solvents

  3. both polar and nonpolare compounds

  4. water only


Correct Option: A
Explanation:

Coordinate covalent components have la slight dipole moment. So they are less solube in nonpolar solvents compared to polar solvents.

In which of the following, all four types of bonds, i.e., ionic, covalent, dative and hydrogen bonds are present?

  1. $Ice$

  2. $BeSO _{4}.4H _{2}O$

  3. $CuSO _{4}.5H _{2}O$

  4. $BaCl _{2}.2H _{2}O$


Correct Option: C
Explanation:

$CuSO _4\cdot 5H _2O$ exists as $[Cu(H _2O) _4]^{2+} SO _{4}^{2-}\cdot H _2O$.
It has dative bonds in $[Cu(H _2O) _4]^{2+}$, which is between water molecules and Cu. There is an ionic bond between the coordination sphere and $SO _4^{2-}$ ion. Covalent bond between S and O in  in $SO _4^{2-}$ ions and between H and O in water molecules Within the molecules of $H _2O$, there is hydrogen bonding. 

Which of the following contains a coordinate covalent bond?

  1. Water

  2. Ammonia

  3. Ammonium ion

  4. Ethylene


Correct Option: C
Explanation:

In $NH _4^+$ the $N$ forms a co-ordinate covalent bond with one $H$ by utilizing the lone pair of electrons.

Name an ion which combines with a polar covalent molecule to form an ammonium ion?

  1. Hydrogen

  2. Chlorine

  3. Fluorine

  4. All of these


Correct Option: A
Explanation:

Ammonium ions are formed by transfer of a hydrogen ion from HCl to the lone pair of electrons on the ammonia molecule.

Two elements have electronegativity of $1.2$ and $3.0$. Bond formed between them would be :

  1. ionic

  2. polar covalent

  3. co-ordinate

  4. metallic


Correct Option: A
Explanation:

The electronegativity difference between the two atoms is $3.0 - 1.2 = 1.8$. It is large, hence, the bond formed is an ionic bond. The more electronegative atom gains one or more electrons to form an anion and the less electronegative atom loses one or more electrons to form a cation. 

A co-ordinate bond is formed when atom in a molecule has:

  1. all its valency shell electrons shared

  2. a single unshared electron

  3. one or more unshared electron pair

  4. electric charge on it


Correct Option: C
Explanation:

A co-ordinate or dative bond is a covalent bond(a shared pair of electrons) in which both the electrons come from the same atom. It is shown by an arrow and the arrow points from atom donating the lone pair to accepting atom.$\quad \quad H\ \quad \quad \quad |\ H-{ N }^{ + }\rightarrow H\ \quad \quad \quad |\ \quad \quad H$

The type of bonds present in $CuSO 4.\, 5H _2O$ are__________.

  1. electrovalent, covalent and coordinate

  2. electrovalent and covalent

  3. electrovalent and coordinate

  4. covalent and coordinate


Correct Option: A
Explanation:

A covalent bond is formed between sulfur and oxygen as they both are non metals and the bond between copper and sulfate is ionic one is metal and other non metal. Hydrated coppersulfate is a complex which is bonded to water molecules acting as ligands forming coordinate bond.

What is a coordination compound?

  1. A metal atom or ion bonded by covalent bonds to ligands.

  2. Any atom bonded by ionic bonds to other atoms.

  3. Any atom bonded by covalent bonds to other atoms.

  4. A compound with covalent bonds.

  5. A metal atom bonded by ionic bonds to ligands.


Correct Option: A
Explanation:

A coordination compound is a metal atom or ion bonded by covalent bonds to ligands. For example, tetra carbonyl nickel $\displaystyle  Ni(CO) _4$ is a coordination compound with the metal atom ($Ni$ atom) which forms covalent bonds with $4$ $CO$ ligands.

Which of the following molecule can combine with a proton $(H^{+})$?

  1. $NH _{3}$

  2. $Na^{+}$

  3. $HCl$

  4. $H _{3}O^{+}$

  5. $H$


Correct Option: A
Explanation:

The molecules already having positive charge $(Na^+ $ and $ H _3O^+) $ means that they are electron deficient and they can not combine with another proton $(H^+)$. $HCl$ is an acid, that releases a proton. Ammonia $NH _3$ acts as a base because, the unshared pair of electrons in the ammonia molecule can combine with a proton, forming the ammonium $(NH _4^+)$ ion. 

Assertion: The weakest of the bonds between molecules are coordinate covalent bonds.
Reason: Coordinate covalent bonds represent the weak attractive force of the electrons of one molecule for the positively charged nucleus of another.

  1. Both Assertion and Reason are correct and Reason is the correct explanation of Assertion

  2. Both Assertion and Reason are correct and Reason is not  the correct explanation of Assertion

  3. Assertion is correct but Reason is not correct

  4. Assertion is not correct but Reason is correct

  5. Both the Assertion and Reason are not correct


Correct Option: E
Explanation:

Assertion: The weakest of the forces between molecules are dispersion forces or London forces.
Reason: Dispersion forces or London forces represent the weak attractive forces that originate as a result of instantaneous dipoles induced in atoms or molecules.
Hence, both the assertion and reason are not correct.

Which of the following species cannot act as an electron pair donor for the formation of dative bond?

  1. H$ _3$I$^+$

  2. NH$ _4^+$

  3. OH$^-$

  4. NH$ _3$


Correct Option: B
Explanation:

In a dative bond, the shared pair of electrons come from the same atom. In $NH _{4}^{+}$ all the 4 valence electrons of N are bonded to the hydrogen atoms, thus it cannot act as an electron pair donor for the formation of dative bond.

What is unique about the bonds in coordination compounds?

  1. One of the atoms or ions donates both shared electrons

  2. Both of the atoms or ions donate both shared electrons

  3. The metal is bonded to ligands

  4. The bond is a covalent bond

  5. The bond is an ionic bond


Correct Option: A
Explanation:

The unique thing about the bonds in coordination compounds is that one of the atoms or ions donates both shared electrons. Thus, the bond is covalent coordinate bond.

Dative bond is present in the molecule:

  1. ${NH} _{3}$

  2. ${CO} _{2}$

  3. $NaCl$

  4. $P{Cl} _{5}$


Correct Option: D
Explanation:

Dative bond is present in the $\displaystyle PCl _5$ molecule.
In the solid state, $\displaystyle PCl _5$ molecule exists in the form of $\displaystyle [PCl _4]^+$ $\displaystyle [PCl _6]^-$
Dative bond is present in $\displaystyle [PCl _6]^-$ ion. The chloride ion is the donor atom and P atom is acceptor atom. The dative bond is also called co ordinate covalent bond.

A coordinate covalent bond is represented by an ______ from donor to acceptor.

  1. single arrow

  2. line

  3. double arrow

  4. double line


Correct Option: A
Explanation:

A coordinate covalent bond is represented by an single arrow from donor to acceptor.
A coordinate bond is formed when one atom donates its pair of electrons to the other atom. For example, a lone pair of electrons on N atom of ammonia is donated to a proton to form ammonium ion with a coordinate bond between N and H.

Which of the following statements is/are true regarding $NH _4^+$?

  1. $NH _4^+$ contains a dative bond

  2. Bond angle increases when a bond is formed between $NH _3$ and $H^+$.

  3. $NH _4^+$ has pyramidal shape.

  4. The type of hybridisation changes when a bond is formed between $NH _3$ and $H^+$


Correct Option: A,B
Explanation:

 (A) $\displaystyle NH _4^+$ ion contains a dative bond (co-ordinate covalent bond) between $\displaystyle N$ atom and  $\displaystyle H$ atom.
$\displaystyle H _3N \rightarrow H^+$

(B) Bond angle increases when a bond is formed between $\displaystyle NH _3$ and $\displaystyle H^+$. In $\displaystyle NH _3$ molecule, due to repulsion between lone pair and bond pair of electrons, the bond angle decreases. When $\displaystyle NH _4^+$ ion is formed, lone pair is converted into bond pair. The inter electron repulsion decreases and bond angle increases.

(C) $\displaystyle NH _4^+$ ion has tetrahedral shape. $\displaystyle NH _3$ molecule has pyramidal shape.

(D) The type of hybridisation is not changed when bond is formed between $\displaystyle NH _3$ and $\displaystyle H^+$

The pair of compounds having coordinate covalent bonds is:

  1. $Br _{2}$ and $Hg$

  2. $Cl _{2}$ and $F _{2}$

  3. $NH _{4}^{+}$ and $H _{3}O^{+}$

  4. $Fe$ and $CO$

  5. Diamond and Graphite


Correct Option: C
Explanation:

$\displaystyle  NH^+ _4$  and $\displaystyle  H _3O^+$  have coordinate covalent bonds.
$\displaystyle  NH^+ _4$ is formed by a coordinate covalent bond between $\displaystyle  NH _3$  and $\displaystyle  H^+$.
$\displaystyle  H _3O^+$ is formed by a coordinate covalent bond between $\displaystyle  H _2O$  and $\displaystyle  H^+$. 

Which of the following compounds contain a coordinate covalent bond?

  1. $Ba{Cl} _{2}$

  2. $CaCl$

  3. ${K} _{2}O$

  4. ${N} _{2}{H} _{3}^{+}$


Correct Option: D
Explanation:

$\displaystyle {N} _{2}{H} _{3}^{+}$ contain a coordinate covalent bond.
$\displaystyle H-N=\underset{\displaystyle \underset{\displaystyle H}{\downarrow}}{N}^+-H$
The N atom is the donor atom and H atom is the acceptor atom.

The bonds present in $K _4[Fe(CN) _6]$ are:

  1. all ionic

  2. all covalent

  3. ionic and covalent

  4. ionic, covalent and coordinate covalent 


Correct Option: D
Explanation:

The bonds present in  $\displaystyle K _4 [Fe(CN) _6]$ are ionic, covalent and coordinate covalent bonds. Ionic bonds are present between $\displaystyle K^+$ ion and $\displaystyle [Fe(CN) _6]^{4-}$ ion.
Covalent bonds are present in $\displaystyle C \equiv N$ ligand.
Co-ordinate covalent bonds are present between $\displaystyle Fe$ and $\displaystyle C$ and also in between $\displaystyle C$ and $\displaystyle N$.

Which one of the following statements is true for ammonium ion?

  1. All bonds are ionic.

  2. All bonds are dative bonds.

  3. Hydrogen atoms are situated at the corners of a tetrahedron.

  4. None of the above


Correct Option: C
Explanation:

In $\displaystyle ammonium $ ion $\displaystyle NH _4^+$ three $\displaystyle N-H$ bonds are covalent and one $\displaystyle N-H$ bond is coordinate covalent (dative). $Hydrogen$ atoms are situated at the corners of a tetrahedron as $\displaystyle N$ atom is $\displaystyle sp^3$ hybridised.

Coordinate bond is present in:

  1. Hydronium ion

  2. Water

  3. Sulphur dioxide

  4. Ammonia


Correct Option: A
Explanation:


From the given compounds only Hydronium ion forms a coordinate or dative bond, where $O$ is the donor atom and $H$ is the acceptor.

Hydronium ion can be shown as:
$\displaystyle H _2O \rightarrow H^+$  or $\displaystyle H _3O^+$.
Hence, the correct option is A. 

Which of the following species contain coordinate covalent bond :

  1. $AlCl _3$

  2. $CO$

  3. $[Fe(CN) _6]^{4-}$

  4. $N _3^-$


Correct Option: B,C,D
Explanation:
$:C\equiv O:$ $\rightarrow $ In Carbonyl two covalent bonds are present and one coordinate bond is present from O$\rightarrow $C.
in $[Fe(N{ ) } _{ 6 }{ ] }^{ 4- }\rightarrow $ All bonds are coordinate bond between ${ CN }^{ - }$ and ${ Fe }^{ +2 }$ metal ion.
in ${ N } _{ 3 }^{ - }$$\rightarrow [\overset { \cdot \cdot  }{ \underset { \cdot \cdot  }{ N }  } =N=\overset { \cdot \cdot  }{ \underset { \cdot \cdot  }{ N }  } { ] }^{ - }\longleftrightarrow [\ddot { N } \equiv N-\overset { \cdot \cdot  }{ \underset { \cdot \cdot  }{ N }  } :{ ] }^{ - }$
In ${ N } _{ 3 }^{ - }$ covalent and coordinate both type of bonds are present.
in $Al{ Cl } _{ 3 }$$\rightarrow $ Icovalent bond is present only between $Al $ and $Cl$.

Coordinate bond is denoted and named respectively as:

  1. arrow, dative bond

  2. dots, dative bond

  3. arrow, covalency

  4. dots, hydrogen bond


Correct Option: A
Explanation:

Coordinate covalent bond is a special type of covalent bond in which only one of the bonded atoms contributes the electron pair for sharing.

The coordinate covalent bond is denoted by an arrow and the arrow point towards the acceptor. The other name for it is the dative bond. 

For example, the coordinate covalent bond in $\displaystyle \displaystyle ammonia : boron : trifluoride$ is denoted by an arrow as $\displaystyle \displaystyle H _3N \rightarrow BF _3$.

Hence, the correct option is A.

The covalency of oxygen in hydronium ion is equal to number of:

  1. covalent bonds

  2. coordinate bonds

  3. covalent bonds and coordinate bonds

  4. valence electrons


Correct Option: C
Explanation:

No. of covalent bonds and coordinate bonds.

In hydronium ion there are $2$ covalent bonds and $1$ coordinate bonds. 

Which of the following molecules contains covalent and coordinate bonds?

  1. $CCl _4$

  2. $H _2SO _4$

  3. $NaCl$

  4. $Mg(OH) _2$


Correct Option: B
Explanation:

Coordinate bond is formed between electron rich and electron deficient atoms. The donor atom should have at least one lone pair of electrons and the acceptor atom should have at least one vacant orbital.

In $NH _4^+$, the nitrogen in $NH _3$ is electron rich and $H^+$ ion do not contain any electron. Thus nitrogen from $NH _3$ share pair of electrons with $H^+$ to make a coordinate bonds.
Other bonds in $NH _3$ are covalent bonds.
$NH _3 + H^+ \rightarrow NH _4^+$

Which of the following will form a coordinate covalent bond with a hydronium ion?

  1. $\displaystyle Na{ C } _{ 2 }{ H } _{ 3 }{ O } _{ 2 }$

  2. $\displaystyle { HC } _{ 2 }{ H } _{ 3 }{ O } _{ 2 }$

  3. $\displaystyle KCl$

  4. $\displaystyle { NH } _{ 3 }$

  5. $\displaystyle HCl$


Correct Option: D
Explanation:

$NH _3$ forms coordinate  bond with the Hydronium ion.

Which one of the following contains just one sigma bond?

  1. $\displaystyle { H } _{ 2 }$

  2. $\displaystyle { CO } _{ 2 }$

  3. $\displaystyle { H } _{ 2 }O$

  4. $\displaystyle NaCl$

  5. $\displaystyle { CH } _{ 2 }{ CH } _{ 2 }$


Correct Option: A
Explanation:


As the valence shell of $H$ atom has single electron and it forms single sigma bond with itself.


Hence the correct option is A.

Which of the following compounds contain(s) both ionic and covalent bonds?

  1. $NH _{4}Cl$

  2. $KCN$

  3. $CuSO _{4}\cdot 5H _{2}O$

  4. $NaOH$


Correct Option: A,B,C,D

Consider following compounds:


$I: K _4[Fe(CN) _6], II:NH _4Cl, III: H _2SO _4$ 

Ionic, covalent and coordinate bonds are present in :

  1. I, II and III

  2. I and III

  3. II and III

  4. I and II


Correct Option: A
Explanation:

$H _{2}SO _{4}$  has $3$ types of bonds- ionic, covalent and coordinate. Sulphur is the central atom,surrounded by $4$ oxygen atoms and $2$ hydrogen atoms places on left of any $2$ oxygen atoms. Now, oxygen shares one electron each with the sulphur and hydrogen atom. But by this only $2$ oxygen atoms will be able to complete octet. The remaining $2$ will complete by coordinate bonding. Both the oxygen atoms will take electrons from sulphur but sulphur won't take theirs ie sharing from only one end. This is called coordinate bond. Hydronium ions are attached with sulphate ions using ionic bonding
${ K } _{ 4 }[{ Fe(CN) } _{ 6 }]\ $: has ionic bond between ${ K }^{ + }and  { [{ Fe(CN) } _{ 6 }] }^{ 4- }$, coordinate bonding in $CN$ and covalent bond in ${ [{ Fe(CN) } _{ 6 }] }^{ 4- }$
$\ { NH } _{ 4 }Cl\ $: has ionic bond between $\ { { NH } _{ 4 } }^{ + }and  { Cl }^{ -}$, coordinate bonding in $\ { { NH } _{ 4 } }^{ + }$ and covalent bond in $\ { { NH } _{ 3 } .}^{  }\quad \$

Which of the following contains a coordinate covalent bond ?

  1. $N _2H^{+} _{5}$

  2. $BaCl _2$

  3. $HCl$

  4. $H _2O$


Correct Option: A
Explanation:

${ N } _{ 2 }{ H } _{ 5 }^{ + }$ is formed from ${ N } _{ 2 }{ H } _{ 4 }$ which has a lone pair of electrons on $'N'$ and positive charge on $'H'$ takes away its electron and to complete duplet, a co-ordinate bond is present from $N$ to $H$.

$H _4N _2 + H^+ \rightarrow[H _4N _2\to H]^+$

Which of the following molecule has dative bond?

  1. CO

  2. $CO _3^{2-}$

  3. $SO _4^{-2}$

  4. All of these


Correct Option: A
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