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Group 17 elements - general properties - class-XII

Description: group 17 elements - general properties
Number of Questions: 54
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Tags: the p-block elements chemistry p-block elements p- block elements-ii
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Which has a lowest electron affinity among the following?

  1. I

  2. Br

  3. Cl

  4. F


Correct Option: A
Explanation:

Down the group $e^-$ affinity decreases due to increase in size. Here $I$ having large size has least $e^-$ affinity.

The electronic configuration of four atoms are given in brackets:
L : ($1s^2\,2s^2\,2p^1$);                    M : ($1s^2\,2s^2\,2p^5$);

Q : ($1s^2\,2s^2\,2p^6\,3s^1$);             R : ($1s^2\,2s^2\,2p^2$).

The element that would most readily form a diatomic molecule is :

  1. Q

  2. M

  3. R

  4. L


Correct Option: B
Explanation:

From the electronic configuration given it is clear that element M is 1 short of octet configuration. It belongs to group 17. Group 17 elements exist as diatomic molecules.


So, correct option is B.

Which is the correct arrangement of the compounds based on their bond strength?

  1. HF > HCl > HBr > HI

  2. HI>HBr>HCl>HF

  3. HCl>HF>HBr>HI

  4. HF>HBr>HCl>HI


Correct Option: A
Explanation:

Because electronegativity decreases down the group thereby $e^-$ attracting tendency decreases down the group. $F$ with high electronegativity will have strongest bond and $I$ with least electronegativity will have least bond strength.

Mark the correct statements about halogens.

  1. Electron affinity of halogens is in the order F > Cl > Br > I.

  2. HF is the strongest hydrohalic acid.

  3. $F _{2}$ has lower bond dissociation energy than $Cl _{2}$.

  4. All halogens show variable oxidation states.


Correct Option: C
Explanation:

$F _2$ has lower bond dissociation energy than $Cl _2$ due to its small size and high electronegativity.

The property of halogens which is not correctly matched is:

  1. F>Cl>Br>I (Ionisation energy)

  2. F>Cl>Br>I (Electronegativity)

  3. I>Br>Cl>F (Density)

  4. F>Cl>Br>I (Electron affinity)


Correct Option: D
Explanation:

$e^-$ affinity of $F$ is less than that of $Cl$ because of the small size and high electronegativity of $F$ it repels the incoming $e^-$ thereby decreasing its $e^-$ affinity whereas $Cl$ having bigger size than $F$ & can accommodate the new incoming extra $e^-$.

Affinity for hydrogen decreases in the group from fluorine to iodine. Which of the halogen acids should have highest bond dissociation enthalpy? 

  1. $HF$

  2. $HCl$

  3. $HBr$

  4. $HI$


Correct Option: A
Explanation:
As the size of the halogen atom decreases the bond length between halogen and hydrogen decreases ,So the bond becomes stronger and hence the energy required to break the bond ( bond dissociation enthaphy) increases.

So the compound with highest bond dissociation energy is $HF$

Hence option A is correct.

Match the column I with column II and mark the appropriate choice.

Column I Column II
(A) $H _{2}SO _{4}$ (i) Highest electron gain enthalpy
(B) $CCl _{3}NO _{2}$ (ii)Chalcogen
(C) $Cl _{2}$ (iii) Tear gas
(D) Sulphur (iv) Storage batteries
  1. (A) $\rightarrow$ (iv), (B) $\rightarrow$ (iii), (C) $\rightarrow$ (i), (D) $\rightarrow$ (ii)

  2. (A) $\rightarrow$ (iii), (B) $\rightarrow$ (iv), (C) $\rightarrow$ (i), (D) $\rightarrow$ (ii)

  3. (A) $\rightarrow$ (iv), (B) $\rightarrow$ (i), (C) $\rightarrow$ (ii), (D) $\rightarrow$ (iii)

  4. (A) $\rightarrow$ (ii), (B) $\rightarrow$ (i), (C) $\rightarrow$ (iii), (D) $\rightarrow$ (iv)


Correct Option: A
Explanation:

$H _2SO _4$ is used in storage batteries.

$CCl _3NO _2$ is chloropicrrin which is known as tear gas.
$Cl$ is the element of highest electron gain enthalpy.
Sulfur is the element belongs to 16th group which are also called as Chalcogens.
So the given data matches with option A.
Hence option A is correct.

Which one of these group off elements is also called the halogen family?

  1. Group 16

  2. Group 18

  3. Group 10

  4. Group 17


Correct Option: D
Explanation:

Group 17 is also called halogen family.

$  { I } _{ 2 }C{ l } _{  6}$ i s formed by the following reaction:


       $  2IC{ l } _{  3}\rightleftharpoons {I  } _{2  }C{l } _{ 6 }  $

On the basis of the structure of $  {I } _{2  }C{l } _{ 6 }  $, find the number of atoms lying in one plane.

  1. 4

  2. 6

  3. 8

  4. 10


Correct Option: B

In NaOX , X cannot be

  1. ${ F } _{ 2 }$

  2. ${ Cl } _{ 2 }$

  3. ${ Br } _{ 2 }$

  4. $I _{ 2 }$


Correct Option: D

The strongest oxidising agent is :

  1. ${ Cl }^{ -1 }$

  2. ${ F }^{ -1 }$

  3. $O^{ -2 }$

  4. $N^{ -3 }$


Correct Option: B

The table shows some information about elements in Group VII of the Periodic Table. 

Name State at room temperature Colour
Chlorine Gas yellow-green
Bromine liquid brown
iodine ? ?
Astaine solid black

Which information about iodine completes the table?

  1. State - liquid, colour - black

  2. State - liquid, colour - green

  3. State - solid, colour - grey

  4. State - solid, colour - yellow


Correct Option: D
Explanation:
$\text{D) State-solid,Colour-yellow}$
$\text{Iodine is solid at room temperature and appears yellow in low concentrat}$

Affinity for hydrogen is maximum for

  1. $\mathrm{F} _{2}$

  2. $ \mathrm{Cl} _{2}$

  3. $\mathrm{B}\mathrm{r} _{2}$

  4. $I _{2}$


Correct Option: A
Explanation:

Fluorine $(F _2)$ is a halogen , which is a non-metal and has highest electronegativity, so it has maximum affinity for hydrogen. 

Which requires the highest energy for excitation?

  1. F

  2. Cl

  3. Br

  4. I


Correct Option: A
Explanation:

Fluorine has a small size thus it has a high nuclear charge and its electrons are strongly attracted towards the nucleus. Thus it requires high energy for excitation. Among halogen atoms, fluorine requires the highest energy for excitation.

Halogens means:

  1. ore forming elements

  2. sea salt products

  3. inert gases

  4. rare gases


Correct Option: B
Explanation:

Sea salt $\to$ like $Mgcl _{2},\ MgBr _{2}$ have halogens.  $\therefore$  Halogens are sea salt products

Which of the following has seven valence electrons?

  1. $Na^{+}$

  2. $Al$

  3. $F$

  4. $Ti$

  5. $B$


Correct Option: C
Explanation:

We know that halogens have 7 electrons in their valence shell.

$F, Cl, Br, I$ are halogens.
Hence, option $C$ is correct.

Which of the following statement is wrong? In the reaction $2KCl{ O } _{ 3 }+{ I } _{ 2 }\rightarrow 2KI{ O } _{ 3 }+{ Cl } _{ 2 }$?

  1. ${ Cl } _{ 2 }$ is more reactive than $I _{ 2 }$

  2. When $KCl{ O } _{ 3 }$ reacts with $I _{ 2 }$, ${ Cl } _{ 2 }$ is liberated

  3. $KCl{ O } _{ 3 }+{ I } _{ 2 }$ is a redox reaction and $I _{ 2 }$ is oxidized

  4. In the above reaction, $I _{ 2 }$ is reduced


Correct Option: D
Explanation:

the given reaction is

${ 2KClO } _{ 3 }+{ I } _{ 2 }\rightarrow { 2KIO } _{ 3 }+{ Cl } _{ 2 }$
in reactant,oxidation state of iodine in ${ I } _{ 2 }=0$
in product,oxidation state of iodine in${ IO } _{ 3 }^{ - }\quad $is 3
so,oxidation state of iodine change from 0 to5,so it is oxidlsed.

For electron affinity of halogens which of the following is correct?

  1. $Br>F$

  2. $F>Cl$

  3. $Br>Cl$

  4. $F>I$


Correct Option: D
Explanation:

  • Electron Gain Enthalpy is the energy released when one mole of an electron is added to gaseous atoms of an element. 
  • The correct order of Electron gain enthalpy of Fluorine family is,
$Cl>F>Br>I$
The reason for this is that the size of the fluorine atom is very small. So when an electron is added in the fluorine atom it will suffer more electronegativity as all the electrons will be very close to each other and hence the electron gain enthalpy of chlorine is more negative than that of fluorine.

Chlorine has two naturally occuring isotopes $ _{ 17 }^{ 37 }{ Cl }$ and $ _{ 17 }^{ 35 }{ Cl }$ and average atomic mass of chlorine is $35.5$. The percentage of $ _{ 17 }^{ 37 }{ Cl }$ is:

  1. 25%

  2. 75%

  3. 40%

  4. 60%


Correct Option: A

Select the correct statement (s)

  1. HCI and HF do not from free radical easily due to larger bond-energy

  2. HI with a minimum bond energy is every reactive and instead from ${{\text{I}} _{\text{2}}}\,\,\,$

  3. Both (a) and (b)

  4. None of the above


Correct Option: C
Explanation:

Bond dissociation energy with hydrogen decreased down the group so HI is will be the most reactive . HI is more reative because the bond dissociation energy is low due to difference in size of hydrogen and iodine so it can be easily breaked.

Addition of halogen $(C{l _2} or B{r _2})$ to alkenes goes through formation of :

  1. Carbocation

  2. Carbanion

  3. Cyclic halonium ion

  4. Carbon free radical


Correct Option: C

In which of the following, oxidation number of chlorine is $ + 5 ?$

  1. $Cl _{2}O _{7}$

  2. $\mathrm { ClO } _ { 3 } ^ { - }$

  3. $\mathrm { CHO } ^ { - }$

  4. $\mathrm { ClO } _ { 4 } ^ { - }$


Correct Option: B
Explanation:

Oxidation number of $Cl _2O _7$:-

   $2x-14=0$
$x=7$

Oxidation number of ${ClO _3}^{-}$:-
$x-6=-1$
$x=5$
Oxidation number of $ClO^-$:-
$x-2=-1$
$x=1$
Oxidation number of ${ClO _4}^-$:-

$x-8=-1$
$x=7$
hence option B is correct.

Which of the following has highest chlorine content ?

  1. Pyrene

  2. DDT

  3. Chloral

  4. Gammaxene


Correct Option: A

Compare oxygen and flourine in Ionic radius$\quad O^{2-} , F^-$:

  1. $\space O^{2-} = F^-$

  2. $\space O^{2-} < F^-$

  3. $\space O^{2-}> F^-$

  4. $\space O^{2-} \geq F^-$


Correct Option: C
Explanation:

Among the elements of same period the ion with more number of electrons and less number of protons is having more radius.If the number of electrons are same the ion with less number of protons is having more radius.

Here $\quad O^{2-} $and $ F^-$ both are having same 10 electrons but oxygen is having 8 protons(which can atrract outer electrons with less force than florine) and florine is having 9 protons.So the ionic radius of $\space O^{2-}>  F^-$

Hence option C is correct.

Oxidation of hydrogen halide, HX affords a method for the industrial and laboratory preparation of the halogen, $X _2$, in the free state in respect of all of the following except :

  1. fluorine.

  2. chlorine.

  3. bromine.

  4. iodine.


Correct Option: A
Explanation:

Due to higher electronegativity, HF doesn't follow such reaction and fluorine doesn't form.

Which f the following atoms has the highest ionisation energy ?

  1. F

  2. Cl

  3. Br

  4. I


Correct Option: A
Explanation:

Halogens have little tendency to lose electron. Thus they have very high ionisation enthalpy. Due to increase in atomic size, ionisation enthalpy decreases down the group.

Which of the following is incorrect statement? 

  1. Bond dissociation energy of Bromine is more than that of chlorine.

  2. The standard electrode potential of chlorine is more than that of fluorine.

  3. The percentage of chlorine in bleaching powder compound is 35-38%.

  4. All


Correct Option: D
Explanation:

Bond dissociation:
$Cl _{2} > Br _{2}$
Standard electrode potential:
$F>Cl$
Bleaching powder $(Ca(ClO) _{2})$             

Percentage of $Cl = \frac{35.5\times 2}{(35.5+16)\times 2 +40}$
$=\frac{71}{143}\times 100 \simeq 50$%

The correct order of reactivity is:

  1. $\mathrm{F}>\mathrm{Cl}>\mathrm{B}\mathrm{r}> \mathrm{I} $

  2. $\mathrm{F}<\mathrm{Cl}<\mathrm{B}\mathrm{r}<\mathrm{I}$

  3. $\mathrm{F}<\mathrm{Cl}>\mathrm{B}\mathrm{r}>\mathrm{I}$

  4. $\mathrm{F}>\mathrm{Cl}<\mathrm{B}\mathrm{r}<\mathrm{I}$


Correct Option: A
Explanation:

As we move down the group chemical reactivity decreases due to decrease in electronegativity

The outer most electronic configuration of the most electronegative element is:

  1. $\mathrm{n}\mathrm{s}^{2}\mathrm{n}\mathrm{p}^{3}$

  2. $\mathrm{n}\mathrm{s}^{2}\mathrm{n}\mathrm{p}^{4}$

  3. $\mathrm{n}\mathrm{s}^{2}\mathrm{n}\mathrm{p}^{5}$

  4. $\mathrm{n}\mathrm{s}^{2}\mathrm{n}\mathrm{p}^{6}$


Correct Option: C
Explanation:

Halogens are most electronegative.


Therefore outer electronic configuration is $ns^{2}\ np^{5}$

Option C is correct.

Generally non-metals are non-lustrous. Exception to this property is-

  1. Flourine

  2. Chlorine

  3. Bromine

  4. Iodine


Correct Option: D
Explanation:

Lime water is calcium hydroxide and is a base so it turns phenolphthalein solution (an indicator) pink.

The halogen $($Group $17$ elements$)$:

  1. have an electron configuration of a noble gas less seven electrons

  2. are highly electro positive

  3. show variable oxidation state of $-1, +1, +3, +5$ and $+7$ in their various compounds

  4. forms a volatile, covalent hydrides $HX$ in which the halogen $(X)$ shows an oxidation state of $+1$


Correct Option: C
Explanation:

Fluorine is the most electronegative in halogen family so it has oxidation number of -1 in all its compounds but Cl,Br and I are less electronegative so these elements prepare compounds with oxidation number of +1,+3,+5 and +7.

Which of the following have large electronegativity values?

  1. Alkali metals

  2. Alkaline Earth metals

  3. Metalloids

  4. Halogens

  5. Rare earth metals


Correct Option: D
Explanation:

Electronegativity is a chemical property that describes the tendency of the atom to attract electrons towards itself.

Halogens have 7 electrons in their valence shell.
They need only 1 electron to complete their octet.
Hence, halogens are highly electronegative.

Assertion: Fluorine has the highest value for electronegativity.
Reason: Fluorine has the greatest attraction for electrons.

  1. Both Assertion and Reason are true and Reason is the correct explanation of Assertion

  2. Both Assertion and Reason are true but the Reason is not the correct explanation of Assertion

  3. The Assertion is true but Reason is false

  4. The Assertion is false but the reason is true

  5. Both Assertion and Reason are false


Correct Option: A
Explanation:

Both Assertion and Reason are true and the Reason is the correct explanation of the Assertion. 


Fluorine has the highest electronegativity. This is because its electrons are held very strongly by the nucleus as it has a small atomic radius and high nuclear charge density.

Hence, the correct option is A.

Among the following which has higher electron affinity value ?

  1. Fluorine

  2. Chlorine

  3. Bromine

  4. Iodine


Correct Option: B
Explanation:

Electron Affinity: decreases down the group. Since the atomic size increases down the group, electron affinity generally decreases$ ( I < Br < F < Cl)$. An electron will not be as attracted to the nucleus, resulting in a low electron affinity. However, fluorine has a lower electron affinity than chlorine.

With which of the following halogen,germanium does not form a dihalide?

  1. Fluorine

  2. Chlorine

  3. Bromine

  4. Iodine


Correct Option: C
Explanation:

Germanium forms tetrahalides with all halogens except astatine and forms dihalides with all halogens except bromine and astatine.

Which of the following chalcogen does not make bonds with germanium?

  1. Sulfur

  2. Selenium

  3. Tellurium

  4. Polonium


Correct Option: D
Explanation:

Chalcogens are chemical elements in group 16 of the periodic table. Germanium bonds to all natural single chalcogens except polonium.

Which of the following element has metallic lustre?

  1. $F$

  2. $Cl$

  3. $Br$

  4. $I$


Correct Option: D
Explanation:

As we move down the group the metallic character increases which impart lustrousness to the elements.

So the iodine is most lustrous.

Which of the following has most ionisation enthalpy?

  1. $F$

  2. $Cl$

  3. $Br$

  4. $I$


Correct Option: A
Explanation:

As the atomic size of the Florine is less it has more nuclear charge. So it requires more energy to remove the electron from its outer most orbit. So Florine has high ionization enthalpy and as we move down the group size increases nuclear charge decreases hence Ionization potential.

Hence option A is correect.

Which of the following is most electronegative?

  1. $F$

  2. $Cl$

  3. $Br$

  4. $I$


Correct Option: A
Explanation:

Florine is most electronegative than the other elements of that group because it has less atomic size so it attracts electrons more towards itself (Electronegativity).

Hence option A is correct.

The elements with atomic numbers 9, 17, 35, 53 and 85 belong to noble gases columnz__________.

  1. True

  2. False


Correct Option: B
Explanation:

The atomic number of elements are 9,17,35,53,85.
Electronic configuration of elements will be
9  = 2,7
17= 2,8,7
35= 2,8,18,7
53=2,8,18,18,7
85=2,8,18,18,32,7
The pattern shows that all elements have 7 electron in their outermost valence shell and all these elements belong to halogens.

Elements of which group form anions most readily:

  1. oxygen family

  2. nitrogen group

  3. halogen family

  4. carbon group


Correct Option: C
Explanation:

Halogens need to lose only one electron to form an anion, and thus, their tendency to form an anion is highest. 

In the third excited state the number of unpaired electrons in chlorine atom is:

  1. 5

  2. 7

  3. 3

  4. 1


Correct Option: B
Explanation:

The general electronic configuration of chlorine is $[Ne] 3s^{2} 3p^{5}$

When electrons are excited in chlorine, the electrons enter into 3d subshell then electronic configuration of chlorine is given as:
$[Ne] 3s^{1} 3p^{3} 3d^{3}$
Thus the number of unpaired electrons will be 7.

Which of the following shows only one oxidation state in its compounds:

  1. F

  2. Cl

  3. Br

  4. I


Correct Option: A
Explanation:

F does not have empty d-orbitals o it show only one oxidation state. In othens electrons can excite to empty d-orbitals and show variable oxidation state

The number of p-electrons in bromine atom is:

  1. 17

  2. 7

  3. 15

  4. 13


Correct Option: A
Explanation:

$Br - 35$

Its electronic configuration is given as:
$1s^22s^22p^63s^23p^64s^23d^{10}4p^5$
So, total p-electrons =6+6+5
= 17

Which one of the following is the correct order for the bond energies of halogen molecules?

  1. $Cl _2>Br _2>I _2$

  2. $Br _2>Cl _2>l _2$

  3. $l _2>Cl _2>Br _2$

  4. $I _2>Br _2>Cl _2$


Correct Option: A
Explanation:

Bond energy is inversely proportional to molecular mass as van der wall forces exist  between molecules of halogens
$\therefore$ Bond Energy order:
$Cl _2>Br _2>I _2$

The electro valency theory explains that atoms are held together by an attractive force.

  1. True

  2. False


Correct Option: A
Explanation:

Electrovalency theory (valence band theory) explains two atoms that have an unpaired electron in their orbitals can overlap to give rise to chemical bond and chemical bond nothing but an attractive force between two atoms.

Arrange the following atoms in the order of increasing atomic radius.
F, Cl, C, O

  1. F, Cl, O, C

  2. C, O, F,Cl

  3. O, C, F, Cl

  4. F, O, C, Cl


Correct Option: D
Explanation:

As we move along a period from left to right, number of proton increases and valence shell remains same, so, radius of atom decreases.
Also, as we move down the group, number of valence shell increases, so, size of atom increases so order of radii is
 F < O < C < CI.

Sea weeds are an important source of :

  1. Iron

  2. Chlorine

  3. Iodine

  4. Bromine


Correct Option: C
Explanation:

Iodine is a component of almost every living plant and animal. No standard measurements of iodine in food exist because iodine concentrations vary across the world. In general, foods from the sea contain the most iodine, followed by animal foods, then plant foods. Of all foods, seaweed (like kelp), is the most well known and reliable source of natural iodine. Egg and dairy products can also be good sources.

Which is the most active element among folllowing?

  1. Chlorine

  2. Oxygen

  3. Sulfur

  4. Fluorine


Correct Option: D
Explanation:

Most active element is Fluorine. The reduction potential of fluorine is very high. Hence, it is extremely reactive in nature. Also F-F bond energy is low (38 kcal/mol). The valence shell electron configuration of fluorine $2s^22p^5$  indicates that it has very strong tendency to take up one electron to attain stable noble gas configuration. Hence, it has high reactivity.

Which of the following is correct?

  1. Iodine is solid

  2. Chlorine is insoluble in water.

  3. Iodine is more reactive than bromine.

  4. Bromine is more reactive than chlorine.


Correct Option: A
Explanation:

The reason is that the attractive forces between the molecules of these elements increase from top to bottom of the Group.

In iodine, the electrons are so far from the nuclei that the electron clouds can easily distort. The London dispersion forces are strong. So the Iodine is solid.

Hence option A is correct.

Formula of Freon is:

  1. $CCl _2F _2$

  2. $COCl _2$

  3. $SO _2Cl _2$

  4. none of these


Correct Option: A
Explanation:

$CCl _2F _2$ is called as freons or chloro floro carbons.

Hence option A is correct.

Have you ever noticed the fact that two siblings can have different personalities? Even though two people may be members of the same family, it does mean that they will behave in similar ways.
The same thing can be said about elements in a group ("family") on the periodic table. For example, fluorine and iodine are members of the halogen family, but their physical properties are different, as shown in the table below.

Element Melting Point $(^{\circ}C)$ Boiling Point $(^{\circ}C)$
Fluorine $-220$ $-188$
Iodine $+118$ $+184$

Which of the following is the BEST explanation for these differences in melting and boiling point?

  1. Fluorine has a higher value for electronegativity than iodine.

  2. The covalent bond in the fluorine molecule is stronger than the covalent bond in the iodine molecule.

  3. Iodine molecules are larger and more polarizable than fluorine molecules.

  4. Fluorine is a nonpolar molecule, but iodine is a polar molecule.


Correct Option: C
Explanation:

As we move down the group of halogens the size of elements increases thereby increasing the Van der Waal forces; hence boiling and melting point of Iodine is more than Fluorine molecule.

Which is soluble in water :

  1. AgCl

  2. AgBr

  3. AgI

  4. AgF


Correct Option: D
Explanation:

Ionic compounds are soluble in water
In AgF  $F^-$ is small onion with high charge density so less polarisation and less covalent character in the whole group of Ag holdies.  AgF is most Ionic in nature.

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