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Versatile nature of carbon - class-XI

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Which of the following statements is/are incorrect for diamond?
(a) The refractive index of diamond is highest among solids.
(b) Diamond is hard because all the valence electrons of each carbon atom are involved in bond formation.
(c) Diamond is thermodynamically more stable than graphite.
(d) One carat of diamond represents its weight.

  1. All are correct

  2. a, b and c

  3. a and b

  4. c only


Correct Option: D
Explanation:

Graphite is thermodynamically more stable than diamond, diamond is kinetically stable thus statement c is incorrect. 


Diamonds and other gemstones are weighed in metric carats: one carat is equal to 0.2 grams, about the same weight as a paperclip. Carat is just a unit to represent its weight. 


Diamond also possess an extremely high refractive index and fairly high dispersion. 

Hence, the answer is option $\text{D}$

Carbon in __________ form conducts electricity.

  1. diamond

  2. graphite

  3. coal

  4. petroleum


Correct Option: B
Explanation:

Graphite is an allotrope of carbon. It is an electrical conductor due to vast electron delocalisation within the layers. These are mobile electrons hence responsible for electrical conduction.

The carbon atoms in diamond are bonded to each other by:

  1. ionic bond

  2. coordinate bond

  3. hydrogen bonds

  4. covalent bonds


Correct Option: D
Explanation:

The bonds between carbon atoms in diamond are covalent because covalent bonding is the only option when only nonmetals are present.

The rigid network of carbon atoms, held together by strong covalent bonds, makes diamond very hard. This makes it useful for cutting tools, such as diamond-tipped glass cutters and oil rig drills.

Fullerene, an allotrope of carbon, has 60 carbon atoms joined together and no other element in it. There are various types of fullerenes. $C _{60}, C _{70}, C _{74}$ and $C _{78}$ are the members of the fullerene family. Identify the property due to which such large numbers of carbon atoms are joined together in this molecule :

  1. Isomerism

  2. Homologous

  3. Catenation

  4. Metamerism


Correct Option: C
Explanation:

Catenation is a self-linking property which is maximum present in carbon, because of this property large number of carbon atoms joined together to form molecule.

Which of the following is not an allotrope of carbon?

  1. Buckyballs

  2. diamond

  3. graphite

  4. carbon dioxide


Correct Option: D
Explanation:

Buckyballs, diamond and graphite are allotrops of carbon while carbon dioxide is a compound of carbon.

Which of the following is not an allotropic form of carbon?

  1. Fluorine

  2. Fullerene

  3. Diamond

  4. Graphite


Correct Option: A
Explanation:

Fullerene, graphite and diamond all are different allotrops of carbon.

Fluorine is an entirely different element, whose atomic number is $9$.
Option A is the correct answer.
Fluorine is not an allotrope of carbon.

Carbon forms bonds with another element by :

  1. transferring of electrons.

  2. sharing of electrons.

  3. Both A and B.

  4. None of the above.


Correct Option: B
Explanation:

Carbon shares electrons while making compounds. It do not transfers electrons to other ions.


Hence, the correct option is $B$.


Which of the following is the true statement for carbon atoms :

  1. A carbon atom loses $4$ electrons.

  2. A carbon atom forms $4$ covalent bonds.

  3. A carbon atom share the $2$ electrons in the first principal energy level.

  4. A carbon atom gains $4$ electrons.


Correct Option: B
Explanation:

Carbon atoms form 4 covalent bonds. Carbon (atomic number 6) has electronic configuration $\displaystyle 1s^2 2s^22p^4$ It has $4$ valence electrons which are shared with other atoms to form $4$ covalent bonds.

____________ is the crystalline allotrope of carbon.

  1. Coal

  2. Coke

  3. Diamond

  4. Graphite


Correct Option: C
Explanation:

Graphite is one of three forms of crystalline, or crystal-forming, carbon. Carbon also exists in an amorphous, or “shapeless,” form in substances such as coal and coke. Different forms of the same element are called allotropes. Besides graphite, the other allotropes of crystalline carbon are diamond and fullerenes


Hence, the correct options are $C$ and $D$

Which of the following elements shows allotropy ?

  1. Mg

  2. Cs

  3. Sn

  4. Zn


Correct Option: C
Explanation:

Allotropy is a phenomenon wherein an element especially from group $13$ to group $16$ exists in more than one form. These forms differ in arrangement of atoms in their crystalline form. Few list of various elements showing allotropy -

 

Forms | | --- | --- | | Carbon : | Graphite, Diamond, Fullerenes | | Sulphur $(S _{8})$: | Rhombic, Monocline, Triclinic sulphur | | Phosphorous $(P _{4})$:  | Red, Black, Yellow | | Tin $(Sn)$: | White, Grey |

Diamond and graphite are the covalent compounds of carbon element (C).

  1. True

  2. False


Correct Option: A
Explanation:
The giant molecular structure of carbon is lattices made up of carbon which are covalently bonded. These bonds are very strong due to which they are hard and have high melting points. 

Diamond is an allotrope of carbon in which the carbon atoms are arranged in cubic lattice or diamond lattice. In diamond, each carbon atom has four neighbors joined to it with covalent bonds. 

In graphite, the carbon atoms are arranged hexagonally in a planar condensed ring system. The layers are stacked parallel to each other.  The atoms within the rings are bonded covalently, whilst the layers are loosely bonded together by van der Waals forces. 

Therefore, Diamond and graphite are the covalent compounds of carbon element (C).

$C _{graphite}+O _{2(g)}\rightarrow CO _{2(g)}; \Delta H=-393.5kJ, \Delta H$ of the reaction cannot be:

  1. Heat of formation of $CO _{2}$

  2. Heat of combustion of $CO _{2}$

  3. Heat of reaction

  4. Heat of transition


Correct Option: D
Explanation:

$C(graphite)+O _2(g)\longrightarrow CO _2(g)$


Now, here $\Delta H$ of the reaction cannot be the heat of transition, because there is no transition between phase take place at constant temperature and pressure.

For example: transition of $C _{diamond}\to C _{graphite}$

Select the compound from the following which dissolves in water:

  1. $CCl _4$

  2. $CS _2$

  3. $C _6H _6$

  4. $C _2H _5OH$


Correct Option: D

Which of the following statements are incorrect?


I.  Diamond is the hardest natural substance known and has very high melting and boiling point. 

II. Iodine is a metal like lithium, sodium, and potassium are so hard that they cannot be cut with a knife. They have high densities and high melting point. 

III. Graphite is a metal.


IV. Most of the non- metals produce acidic oxides while most of the metals produce basic oxides.

V. Graphite is a conductor of electricity.
  1. I, IV and V only

  2. I, III, IV and V only

  3. II and III only

  4. None of these


Correct Option: C

The property of catenation is strongest in carbon because?

  1. Its ionisation potential is low

  2. Its electronegativity is low

  3. The C-C bond energy is high

  4. Its atomic radius is small


Correct Option: C
Explanation:

Carbon shows the property of catenation as it is small in size and has the ability to form stable covalent bonds with other carbon atoms to form a chain-like structure. The bond energy between the C-C bond is very high which enables them to form a long chain of C-C stable bonds.

What are the two properties of carbon which led to the huge number of carbon compounds we see around us?

  1. (i) Catenation (ii) Tetravalency

  2. (i) Catenation (ii) Tri valency

  3. (i) Catenation (ii) Penta valency

  4. (i) Co valency (ii) Di valency


Correct Option: A
Explanation:

Carbon can form huge number of carbon compounds due to following properties: 

Catenation is  a self linkage property, present in carbon. Because of catenation, carbon can form long chains, branched chains and closed chains.

Tetravalence: It is the state of an atom with four electrons available for covalent chemical bonding in its valence 

Buckminsterfullerene is an allotropic form of:

  1. phosphorus

  2. sulphur

  3. carbon

  4. tin


Correct Option: C
Explanation:

Carbon is capable of forming many allotropes due to its valency.  
Sixty carbon atoms form the shape of a ball like a football with a carbon atom at each corner of the 20 hexagons and 12 pentagons. The buckminsterfullerenes, is also called fullerenes, Fullerenes are molecules of varying sizes composed entirely of carbon, which take the form of a hollow sphere, ellipsoid, or tube.
Option "C" is correct.

In diamond, the bonding between carbon atoms is :

  1. co-ordinate

  2. ionic

  3. electrostatic

  4. covalent


Correct Option: D
Explanation:

In diamond, each carbon atom is covalently bonded to four other carbon atoms. A lot of energy is needed to separate the atoms in diamond. 


This is because covalent bonds are strong and diamond contains many covalent bonds. 

Hence, the correct option is $D$

Diamond is not a good conductor of electricity because :

  1. it is very hard

  2. it is structure is very compact

  3. it is not water soluble

  4. it has no free electrons to conduct electric current


Correct Option: D

Which is/are the characteristic(s) of Diamond?

  1. Opaque

  2. Hardness

  3. Both $A$ and $B$

  4. Conductor of electricity


Correct Option: B
Explanation:

Diamond is transparent, hard and poor conductor of electricity. In-fact, diamond is hardest known substance on earth. The hardness is due to the presence of strong covalent bonds between C atoms. Hence, the option (B) is the correct answer.

Two adjacent layers in graphite are bonded by comparatively _______ forces.

  1. strong

  2. weak

  3. both A and B

  4. none of these


Correct Option: B
Explanation:

Graphite is an allotrope of carbon. Each carbon is covalently bobded to other three carbon atoms, it contains layers of carbon. The layers slid over each other easily because of the weak Van der Walls' forces between them.

Crystalline fullerene has __________ properties.

  1. semiconducting

  2. insulating

  3. both $A$ and $B$

  4. none of these


Correct Option: A
Explanation:

Fullerene is an allotrope of carbon in the form of hollow sphere and called as buckyballs. $C-60$ is the crystalline form and is used as semiconductor.

Density of graphite is :

  1. $0.5\ g/cm^3$

  2. $2.266\ g/cm^3$

  3. $1.08\ g/cm^3$

  4. none of the above


Correct Option: B
Explanation:

Crystal density of graphite is $2.266 g/cm^3$ as compared with $3.53 g/cm^3$ for diamond.
In the graphite structure, only three of the four valence electrons of carbon form regular covalent bonds with adjacent carbon atoms.

The most stable fullerene is :

  1. $C _{60}$

  2. $C _{70}$

  3. $C _{100}$

  4. $C _{90}$


Correct Option: A
Explanation:

C-60 is the most stable form and it led the scientists to the conclusion that the cluster must be a spheroidal closed cage in the form of icosahedron.

The first fullerene was discovered in :

  1. $1970$

  2. $1967$

  3. $1997$

  4. $1985$


Correct Option: D
Explanation:

The first fullerene was discovered in 1985 by Sir Harold W.Kroto, Smalley and Robert F.Curl. They obtained a cage like molecules composed of 60 carbon atoms.

The most common fullerene is $C {60}$. 60 C-atoms are arranged in _____ pentagons and ______ hexagons.

  1. $12, 20$

  2. $16, 26$

  3. $12, 40$

  4. $16, 40$


Correct Option: A
Explanation:

60 carbon atoms are joined together by single and double bonds to form a hollow sphere with 12 pentagonal and 20 hexagonal faces, a design that resembles a football.

Chemically, diamond is :

  1. a mixture of metal carbonates

  2. pure carbon

  3. a pure form of sand

  4. a mixture of calcium and magnesium phosphates


Correct Option: B
Explanation:

Diamond is an allotrope of carbon and it is present in pure form since it contains carbon atoms tetrahedrally bonded to each other.

Which of the following statement is true for graphite?


(a) In graphite, each carbon atom is bonded to four other carbon atoms.
(b) Graphite is very hard.
(c) It is a good conductor of electricity.
(d) It is bad conductor of electricity.

  1. a, b and d

  2. only c

  3. a and d

  4. a and c


Correct Option: B
Explanation:

The  statement C is  true for graphite.
(a) In graphite, each carbon atom is bonded to three other carbon atoms.
(b) Graphite is soft.
(c) It is a good conductor of electricity as delocalised electrons are free to move in delocalised molecular orbitals.

Which of the following substance consists of only one element?

  1. Diamond

  2. Glass

  3. Marble

  4. Sand


Correct Option: A
Explanation:

Diamond is the purest form of carbon while glass is composed of silica, sodium carbonate. Marble is calcium carbonate and sand is silicon dioxide.

The allotrope of carbon which is a good conductor of heat and electricity is:

  1. diamond

  2. sugar charcoal

  3. graphite

  4. wood charcoal


Correct Option: C
Explanation:

Graphite is an allotrope of carbon other than diamond. 


It has planar structure in which three electrons are covalently bonded while the fourth electron is free to migrate in the layered structure and makes graphite electrically conductive.

Hence, option $C$ is correct.

Rhombic and monoclinic sulphur are:

  1. isomers of sulphur

  2. isotopes of sulphur

  3. allotropes of sulphur

  4. isobars of sulphur


Correct Option: C

The allotrope of carbon used in nuclear reactor is :

  1. graphite

  2. diamond

  3. coke

  4. sugar charcoal


Correct Option: A
Explanation:

Graphite is the most stable form of carbon under standard conditions. Special grades of synthetic graphite also used as neutron moderator within nuclear reactor. Its low neutron cross-section also recommends its use in proposed fusion reactors.

Some elements show the property of existing in two or more distinct physical form which show different physical properties but same chemical properties. These distinct forms of an element are called :

  1. isomers

  2. allotropes

  3. compounds

  4. isobars


Correct Option: B
Explanation:

Allotropes of carbon have a different physical form but chemically they are similar, e.g., diamond and graphite are allotropes of carbon which are chemically carbon compounds but physically diamond is the hardest material known while graphite is soft material.


Hence, option $B$ is correct,

An allotropic form of carbon used for cutting and drilling is which of the following?

  1. charcoal

  2. bone charcoal

  3. graphite

  4. diamond


Correct Option: D
Explanation:

The dominant industrial use of diamond is in cuttingdrilling (drill bits), grinding. It is used for these purposes due to its hardness.

The allotrope of carbon used in nuclear reactor is:

  1. diamond

  2. suger charcoal

  3. graphite

  4. wood charcoal


Correct Option: C
Explanation:

Graphite is the most stable allotrope of carbon.Contrary to popular belief, high-purity graphite does not readily burn, even at elevated temperatures. For this reason,it is used in nuclear reactor and for high-temperature crucibles for melting metals.


 Hence,graphite is used in nuclear reactor and it is a allotrope of carbon.

Graphite is a ______ conductor of electricity whereas diamond is a ______ conductor of electricity.

  1. bad, bad

  2. good, bad

  3. bad, good

  4. good, good


Correct Option: B
Explanation:

Carbon has a valency of 4. In graphite, each carbon atoms 3 electrons are strongly bonded to other carbon atoms forming a hexagonal structure while one of the electrons of graphite is loosely bound and can thus conduct electricity. 


In diamond, each carbon atom is attached to four other carbon atoms forming a tetrahedral structure and has no free or loosely bound electrons. Thus diamond cannot conduct electricity.

Hence, option B is correct.

Some elements show the property of existing in two or more distinct physical form which shows different physical properties but same chemical properties. These distinct forms of an element are called:

  1. isomers

  2. allotropes

  3. compounds

  4. isobars


Correct Option: B
Explanation:

The term allotrope refers to one or more forms of a chemical element that occur in the physical state. Graphite and diamond are both allotropes of carbon that occur in the solid state. Allotropism only refers to different forms of chemical elements.

Due to the weak Van der Waals' forces and less distance between the layers, graphite :

  1. show lubricating property

  2. has lusture

  3. is hexagonal

  4. is a good conductor of electricity


Correct Option: A
Explanation:

Because the layers are only weakly held together they can easily slip over one another, hence, show lubricating property.

(i) It is used in making leads of pencils.
(ii) It is used as dry lubricant.
(iii) It is used in making black paint and printers ink.
(iv) It is used in nuclear reactors as moderator.


Which is this substance?

  1. Diamond

  2. Buckminister fullerene

  3. Lampblack

  4. Graphite


Correct Option: D
Explanation:

The substance with the following applications is graphite. It is an allotrope of carbon.
(i) It is used in making leads of pencils.
(ii) It is used as a dry lubricant.
(iii) It is used in making black paint and printers ink.
(iv) It is used in nuclear reactors as a moderator.

Graphite is also used in making electrodes and carbon arcs and in the refractory crucible.

Carbon can form a maximum of _____ bonds.

  1. 1

  2. 2

  3. 3

  4. 4


Correct Option: D

Which of the following can conduct electricity in the solid state ?

  1. Sucrose, $C _{12}H _{22}O _{11}$(s)

  2. Graphite, C(s)

  3. Sodium hydroxide, NaOH(s)

  4. Iron(III) chloride, $FeCl^3$(s)

  5. Iodine, $I _2$(s)


Correct Option: B
Explanation:

Graphite, C(s) can conduct electricity in the solid state.
Ferric chloride and sodium hydroxide are ionic solids which do not conduct electricity in solid state.
They conduct electricity in molten state or in aqueous solution.
Iodine and sucrose are molecular solids which do not conduct electricity.
Graphite is a network solid and conducts electricity as it has delocalised molecular orbitals in which delocalised electrons are free to move.

Which one has an allotrophic form that is a good electrical conductor at standard conditions ?

  1. Carbon

  2. Nitrogen

  3. Oxygen

  4. Neon

  5. Argon


Correct Option: A
Explanation:

Carbon has an allotrophic form that is a good electrical conductor at standard conditions.
This allotrope is graphite.

Which of the following element's allotrop is the primary absorber of UV solar radiation in Earth's atmosphere ?

  1. Carbon

  2. Nitrogen

  3. Ozone

  4. Neon

  5. Argon


Correct Option: C
Explanation:

Ozone, an allotrope of oxygen is the primary absorber of UV solar radiation in Earth's atmosphere.


Hence option C is correct.

In which of the given pairs the two compounds are allotropes of the same element?

  1. $Br _{2}$ and $Hg$

  2. $Cl _{2}$ and $F _{2}$

  3. $NH _{4}^{+}$ and $H _{3}O^{+}$

  4. $Fe$ and $CO$

  5. Diamond and graphite


Correct Option: E
Explanation:

Diamond and graphite are allotropes of each other.
They are are allotropes of carbon. Allotropes are different forms of same element. Another allotrope of carbon is fullerene.

The number of free electrons in the outermost shell of carbon in graphite is:

  1. four

  2. one

  3. two

  4. three


Correct Option: B
Explanation:

The number of free electrons in the outermost shell of carbon in graphite is one. Each $\displaystyle C$ atom is $\displaystyle sp^2$ hybridised. Each $\displaystyle C$ atom forms 3 covalent bonds with 3 other $\displaystyle C$ atoms. Thus, each $\displaystyle C$ atom has one electron in unhybridized $\displaystyle 2p$ orbital which it uses for $\displaystyle \pi $ bonding.

Select the correct statement.

  1. Carbon-carbon bond order in graphite is more than diamond

  2. Carbon-carbon bond order in graphite is less than diamond

  3. Hybridization of each carbon in diamond is ${sp}^{2}$

  4. Hybridization of each carbon in graphite is ${sp}^{3}$


Correct Option: A
Explanation:

Hybridization of carbon is $sp^2$ in graphite as $1$ carbon atom is joined to $3$ other carbon atoms. In diamond, the hybridization is $sp^3$ as $1$ carbon atom is joined to $4$ other carbon atoms.

Bond order= $\cfrac {\text {Total number of valence electrons of carbon}}{\text {number of }\sigma\text { bonds}}$
For graphite, $B.O= \cfrac {4}{3}= 1.33$,
For diamond, $B.O= \cfrac {4}{4}=1$ .
Hence, Bond order for graphite is more than that for diamond.

Which of the following statements is/are correct?


(1) Graphite is used in making electrodes because it can conduct electricity.
(2) Graphite is used as a solid lubricant.
(3) Graphite is used in the manufacture of crucibles.
(4) Graphite is also known as black lead.

  1. 1 and 4

  2. 2 and 3

  3. 1 and 2

  4. All of them


Correct Option: D
The phenomenon of existence of an element in more than one physical form is called allotropy.
  1. True

  2. False


Correct Option: A
Explanation:

Allotropy or allotropism is the property of some chemical elements to exist in two or more different forms, known as allotropes of these elements.

Example : Graphite and diamond

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