Indicators and acid-base titration - class-XII
Description: indicators and acid-base titration | |
Number of Questions: 26 | |
Created by: Jatin Goyal | |
Tags: further aspects of equilibria equilibrium acids and bases chemistry |
1 kg of NaOH is added to 10 ml of 0.1N HCl, the resulting solution will:
From the following in which titration methyl orange is a best indicator?
Dissociation of ${ CH } _{ 3 }COOH$ is suppressed by adding
Which one of the following indicatprs works in the pH range $8-9.8$?
For the titration between oxalic acid and sodium hydroxide, the indicator used is
Select the best indicator from the given table for titration of $20\space mL$ of $0.02\space M\space CH _3COOH$ with $0.02\space M\space NaOH$. Given $pK _a\ \text{of}\ CH _3COOH= 4.74)$
Indicator | $pH$ range | |
---|---|---|
(I) | Bromothymol blue | $6.0 - 7.6$ |
(II) | Thymolphathalein | $9.3 - 10.5$ |
(III) | Malachite green | $11.4 - 13$ |
(IV) | M-Cresol purple | $7.4 - 9.0$ |
The fraction of total volume occupied by by the atoms present in a simple cube is
Assertion: In general, phenolphthalein is used as an indicator for the titration of weak acid (HA) against strong base (NaOH).
Reason: At equivalent point, solution is basic.
A certain indicator (an organic dye) has $p{K} _{a} = 5$. For which of the following titrations it may be suitable?
The amount of sodium hydrogen carbonate, $NaH{ CO } _{ 3 }$, in an antacid tablet is to be determined by dissolving the tablet in water and titrating the resulting solution with hydrochloric acid. Which indicator is the most appropriate for this titration?
Acid ${K} _{a}$
${ H } _{ 2 }{ CO } _{ 3 }$ $2.5\times { 10 }^{ -4 }$
${H{ CO } _{ 3} }^{ - }$ $2.4\times { 10 }^{ -8 }$
A solution containing $Na _{2}CO _{3}$ and $NaOH$ requires $300\ mL$ of $0.1\ N\ HCl$ using phenolphthalein as an indicator. Methyl orange is then added to the above-titrated solution when a further $25\ mL$ of $0.2\ N\ HCl$ is required. The amount of $NaOH$ present in the original solution is:
In the titration of ${ NH } _{ 4 }OH$ with $HCl$, the indicator which cannot be used is:
In the titration of nitric acid against potassium carbonate, the indicator used is:
A solution containing $Fe^{2+}$ ions is titrated with $KMnO _{4}$ solution. Indicator used will be:
In the mixture of $NaHCO _{4}$ and $Na _{2}CO _{3}$, volume of a given $HCl$ required is $x\ mL$ with phenolphthalein indicator and $y\ mL$ with methyl orange indicator in same titration. Hence, volume of $HCl$ for complete reaction of $Na _{2}CO _{3}$ present in the original mixture is
$40\ mL$ of $0.05\ M\ Na {2}CO _{3}\cdot NaHCO _{3} \cdot 2H _{2}O$ (sesquicarbonate) is titrated against $0.05\ M\ HCl.\ x\ mL$ of $HCl$ is used when phenolphthalein is the indicator and $y\ mL\ HCl$ is used when methyl orange is the indicator in two separate titrations, hence $(y - x)$ is_______.
$0.1\ N$ solution of $Na _{2}CO _{3}$ is being titrated with $0.1\ N\ HCl$, the best indicator to be used is:
Select incorrect statement(s) among the following.
A solution contains $Na _{2}CO _{3}$ and $NaHCO _{3}, 10\ mL$ of this solution required $2.5\ mL$ of $0.1\ M\ H _{2}SO _{4}$ for neutralisation using phenolphthalein indicator. Methyl orange is added after first end point, further titration required $2.5\ mL$ of $0.2\ M\ H _{2}SO _{4}$. The amount of $Na _{2}CO _{3}$ and $NaHCO _{3}$ in $1$ litre of the solution is:
When $20\ mL$ of $\dfrac {M}{10}NaOH$ are added to $10\ mL$ of $\dfrac {M}{10}HCl$, the resulting solution will:
An indicator $HIn$ has a standard ionization constant of $9.0\times {10}^{-9}$. The acid colour of the indicator is yellow and the alkaline colour is red. The yellow colour is visible when the ratio of yellow form to red form is $30$ to $1$ and the red colour is predominant when the ratio of red form to yellow form is $2$ to $1$. What is the $pH$ range of the indicator?
In the titration of $CH _{3}COOH$ against $NaOH$, we cannot use the
During the titration of mixture of $NaOH,{ Na } _{ 2 }{ CO } _{ 3 }$ and an inert substance against hydrochloric acid:
(A) In general phenolphthalein is used as an indicator for the titration of weak acid $(CH _3COOH)$ and strong base (NaOH).
(R) At equivalence point solution is basic.