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Colloids around us - class-XII

Description: colloids around us
Number of Questions: 22
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Tags: surface chemistry adsorption and colloids chemistry
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Which of the following statements are correct?
(i)   When an animal hide, which has negatively charged particles, is soaked in tannin, which contains positively charged colloidal particles, mutual coagulation does not take place.
(ii) Photographic films are prepared by coating an emulsion of the light sensitive silver bromide in gelatin over glass plates or celluloid films.
(iii) Latex is a colloidal solution of rubber particles which are negatively charged.
(iv) In Cottrell precipitator, the smoke, before it comes out from the chimney, is led through a chamber containing plates having a charge opposite to that carried by smoke particles. The particles on coming in contact with these plates acquire some charge and do not get precipitated.

  1. (i) and (iv) only

  2. (ii) and (iii) only

  3. (ii), (iii) and (iv) only

  4. All of these.


Correct Option: B
Explanation:

There are various applications of colloids-

    • Tanning: Animal hides are colloidal in nature. When a hide, which has positively charged particles, is soaked in tannin, which contains negatively charged colloidal particles, mutual coagulation takes place. This results in the hardening of leather. This process is termed as tanning. Chromium salts are also used in place of tannin.
    • Photographic plates and films: Photographic plates or films are prepared by coating an emulsion of the light-sensitive silver bromide in gelatin over glass plates or celluloid films.
    • Rubber industry: Latex is a colloidal solution of rubber particles which are negatively charged. Rubber is obtained by coagulation of latex.
    • Electrical precipitation of smoke: Smoke is a colloidal solution of solid particles such as carbon, arsenic compounds, dust, etc., in air. The smoke, before it comes out from the chimney, is led through a chamber containing plates having a charge opposite to that carried by smoke particles. The particles on coming in contact with these plates lose their charge and get precipitated. The particles thus settle down on the floor of the chamber. The precipitator is called Cottrell precipitator.
    Hence, option B shows the correct statements.

        Some medicines are more effective in the colloidal form because of:

        1. the charged colloidal particles present in it

        2. the large surface area and easy assimilation

        3. precipitation of medicine in the blood

        4. the stabilisation of medicine in colloidal form


        Correct Option: B
        Explanation:
        • A colloid is a heterogeneous system in which one substance is dispersed (dispersed phase) as very fine particles in another substance called dispersion medium.
        • Colloidal medicines are more effective because they have large surface area and are therefore easily assimilated.

        Various applications of collids are-
        • Purification of drinking water
        • Cleansing action of soaps and detergents as Medicines
        • Photographic plates and films

        Which reagent, when mixed with ammonium sulfate and then heated, liberates ammonia?

        1. aqueous bromine

        2. dilute hydrochloric acid

        3. limewater

        4. potassium dichormate (VI) in acidic solution


        Correct Option: C
        Explanation:
        Test for the ammonium ion is adding a base then warming and then ammonia gas is produced therefore answer is C because limewater is $Ca(OH) _2$ which is a base and when it reacts with an ammonium ion which ammonium sulphate it produces ammonia gas overall reaction is:
        $Ca(OH) _2 + (NH _4) _2SO _4 \rightarrow CaSO _4 + 2NH _3 + 2H _2O$

        Tanning of leather is the :

        1. colouring of leather by chemicals

        2. drying process to make the leather hard

        3. polishing of leather to make it look attractive

        4. coagulative hardening of the leather by chemicals


        Correct Option: D
        Explanation:

        Tanning is the process that converts the protein of the raw hide or skin into a stable material which will not putrefy and is suitable for a wide variety of end applications. The principal difference between raw hides and tanned hides is that raw hides dry out to form a hard inflexible material that can putrefy when re-wetted (wetted back), while tanned material dries out to a flexible form that does not become putrid when wetted back. A large number of different tanning methods and materials can be used. The choice is ultimately dependent on the end application of the leather. The most commonly used tanning material is chromium, which leaves the leather, once tanned, a pale blue colour (due to the chromium), this product is commonly called wet blue.

        Gelatin is often used as an ingredient in the manufacture of ice-cream. The reason for this is :

        1. to prevent the formation of a colloid.

        2. to stabilize the colloid and prevent crystal growth.

        3. to cause the mixture to solidify.

        4. to improve the flavour.


        Correct Option: B
        Explanation:

        Gelatin is a translucent, colourless, brittle (when dry), flavourless foodstuff derived from collagen obtained from various animal by-products. It is commonly used as a gelling agent in food, pharmaceuticals. Substances containing gelatin or functioning in a similar way are called gelatinous. Gelatin is an irreversibly hydrolyzed form of collagen. It is often used as an ingredient in the manufacture of ice-cream to stabilize the colloid and prevent crystal growth and works as protective colloid.

        Example of an intrinsic colloid is:

        1. $As _2S _3 sol$

        2. S sol

        3. Egg albumin

        4. $Fe(OH _2sol$


        Correct Option: C
        Explanation:

        Lyophilic or solvent loving : When dispersed phase has a greater affinity for the dispersion medium, the colloids are termed as lyophilic and when the dispersion medium is water, they are given the name hydrophilic. They are also called natural colloids, substances like proteins, starch, egg albumin and rubber etc. are grouped under this category.The lyophilic colloids are also called Intrinsic Colloids.

        Gelatin has the minimum protective powers.

        1. True

        2. False

        3. Ambiguous

        4. Data insufficient


        Correct Option: B
        Explanation:

        As we know,
        Smaller the gold number, higher the protective power of a colloid. Gold numbers of some protective colloids are given below :
        Protective Colloid                       Gold Number    
        Heamoglobin                                0.03 to 0.07        
        Starch                                              15 to 25      
        Gum Arabic                                      15 to 25        
        Gelatin                                            0.005 to 0.1
        so gelatin have maximum protective powers.

        Smoke precipitator works on the principle of :

        1. distribution law

        2. neutralization of charge on colloids

        3. Le-Chaterlier's principle

        4. addition of electrolytes


        Correct Option: B
        Explanation:

        Smoke precipitator works on the principle of neutralization of charge on colloids.
        Smoke coming out of the chimneys contain a lot of unburnt carbon particle. Smoke is the colloidalsolution of the solid particles such as carbon, arsenic, dust particles etc. These particles areinjurious to health and have to be precipitated . Carbon particle are charged particles and can notbe precipitated. Thus, a metal plate of oppositely charged particle is used for their precipitation. This is done bythe cottrell smoke precipitator which neutralizes the charge on the carbon particles and neutralizes them. In this way, smoke coming out of the chimneys gets free from the charged particles.

        Which of these can be one of the uses of colloids?

        1. Colloids act as transport vector

        2. Colloids are used in intravenous therapy

        3. Movement of enzyme molecules in water is because of colloid action

        4. All of the above


        Correct Option: D
        Explanation:

        Colloid acts as a transport vector of different contaminants in water surfaces. For example, heavy  metals and radionucleides are absorbed on colloid surface and are carried throughout the water
        Enzymes, which are important biomolecules in human body, freely move about in the water because of colloid action.
        Colloids are used in intravenous therapy where they increase the intravascular volume and maintain a high colloid osmotic pressure in the blood

        Argyrol is a:

        1. Ferric oxide sol

        2. Silver sol

        3. Gold sol

        4. Arsenic sol


        Correct Option: B
        Explanation:

        Argyrol is a silver sol and is used as an eye lotion.It is manufactured in the chemical industry to pharmaceutical grade only, using denatured pharmaceutical-grade protein for ophthalmic application and elemental silver, to produce the silver protein molecule.

        Which of the following is NOT used in making photographic plates using colloidal sols?

        1. Silver bromide

        2. Gelatin

        3. Glass plate

        4. Argyrol


        Correct Option: D
        Explanation:

        Argyrol is a silver sol and is used as an eye lotion. Silver bromide, gelatin and glass plate are used in the making photographic plates.

        Colloidal sols are more effective for medical purposes because:

        1. they have smaller surface area

        2. they have larger surface area

        3. their assimilation is difficult

        4. they can be easily prepared


        Correct Option: B
        Explanation:

        Colloidal sols have larger surface area which provides larger sites for reactions.So,they are more effective for medical purposes.

        Delta formation at the mouth of river takes place by:

        1. coagulation of negative salt ions and positive river particles

        2. coagulation of positive salt ions and negative river particles

        3. coagulation of positive salt ions and positive river particles

        4. coagulation of negative salt ions and negative river particles


        Correct Option: B
        Explanation:

        River water contains charged colloidal particles of clay, sand and many other materials. Sea water is very big store house of a variety of electrolytes dissolved in it. As soon as river water comes in contact with sea water coagulate the suspended colloidal particles which ultimately settle down at the point of contact. Thus the level of the river bed rises. As a result, water adopts a different course and delta is formed in due course of time.

        Which of the following are adsorption indicators?

        1. fluorescin

        2. methelene blue

        3. eosin

        4. both $A$ and $B$


        Correct Option: D
        Explanation:

        Both fluorescin and methelene blue are adsorption indicator. Both are used to show the adsorption had been taken place.

        The colloidal sol found effective in the treatment of eye disease is:

        1. colloidal sulphur

        2. colloidal antimony

        3. colloidal silver

        4. colloidal gold


        Correct Option: C
        Explanation:

        Colloidal silver has also been said to help prevent eye infections in infants when colloidal silver eye drops are used. It is also used for medical purposes including as disinfectants and microbiocides. Silver has also been added to bandages and dressings, and to the coating of medical instruments.

        The colloidal solution of $X$ in gelatin is applied in glass plates to form sensitive plates in photography. Identify $X$:

        1. Silver chloride

        2. Silver bromide

        3. Sodium chloride

        4. Sodium bromide


        Correct Option: B
        Explanation:

        $AgBr$ (Silver bromide) is used in photography. The colloidal solution of it in gelatin is applied in glass plates to form sensitive plates.

        Smoke particles are actually electrically charged colloidal particles of :

        1. carbon in air

        2. water droplets in air

        3. sulphur in air

        4. titanium oxide in air


        Correct Option: A
        Explanation:

        Smoke particles are electrically charged colloidal particles of carbon in the air.

        What is the use of colloidal copper ?

        1. In treatment of cancer

        2. In treatment of syphilis

        3. Diagnostic agent for paresis

        4. None of these


        Correct Option: A
        Explanation:
        Colloidal metal supplements are used to treat deficiencies of metals in the body and boost its immune system. Colloidal copper is actually small flecks of copper mixed with purified water. The water acts as a vehicle for delivering the metal to the digestive system.
        Copper acts as an excellent anti-oxidant which helps prevents and treats diseases like.- diabetes and some cases claims, also prevents cancer., Proper Growth and Health, Copper is vital for good health and normal growth. It helps in the protection of skeletal, nervous and cardiovascular systems.

        Which of the following is absorbed efficiently in colloidal forms?

        1. Colloidal sulphur

        2. Colloidal gold

        3. Colloidal copper

        4. Colloidal mercury


        Correct Option: A
        Explanation:

        Colloidal sulfur is a suspension of fine sulfur particles, usually in a gum base. A good way to think about this is if one were to grind up pure sulfur and dust it into a gelatin mix before it firmed up. Colloidal sulfur is a homoeopathic 'natural' remedy used to treat skin conditions such as acne, psoriasis, eczema, and dermatitis. Colloidal sulfur can be taken orally or mixed with other ingredients and used as soap or shampoo.

        Sulfur is lighter weight element and can serve as a powerful antioxidant, removing free radicals of oxygen and fluorine. Overall, colloidal sulfur is a safe substance that has been used throughout human history as a treatment for skin conditions and can be used today as an effective diet supplement.

        Soap solution is colloidal in nature and remove the dust particles by which of the following process?

        1. Emulsification

        2. Adsorbtion

        3. Stripping

        4. Distillation


        Correct Option: A,B
        Explanation:

        Soap solution removes dust particles through emulsification and absorption of them.

        Silver iodide is used for producing artificial rains because $AgI$:

        1. is easy to spray at high altitude

        2. is insoluble in water

        3. is easy to synthesize

        4. has crystals similar to ice


        Correct Option: D
        Explanation:

        Solid silver iodide is preferred as a nucleator for artificially stimulated rain because its crystal lattice parameters are close to those of ice, and for that reason are more effective than other salts in causing small ice crystals in clouds to melt.

        To stop bleeding from an injury ferric chloride can be applied
        Which comment about the statement is justified?

        1. It is not true, ferric chloride is a poison

        2. It is true, ${Fe}^{3+}$ ions coagulate blood which is negatively charged sol

        3. It is not true, ${Cl}^{-}$ ions from positively charged sol, profuse bleeding takes place

        4. It is true, coagulation takes place because of formation of negatively charged sol with ${Cl}^{-}$ ions.

        5. It is not true, ferric chloride is ionic and gets into blood stream


        Correct Option: B
        Explanation:

        To stop bleeding from an injury, Ferric chloride can be applied because of the following reason:

        (A) $Fe^{3+}$ ions coagulate blood which is a negatively charged solution
        (B) $Cl^−$ ions coagulate blood which is a positively charged solution

        Blood being a colloidal solution, its coagulation by Hardy-Shuze's law states " Higher the charge on cation higher will be its efficiency to coagulate the colloidal solution" . Thus Option B is correct.

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