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Newland's law of octaves - class-XI

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Law of octaves stated :

  1. every eighth element had properties similar to the first element

  2. every third element had properties similar to the first element

  3. the properties of the middle element were in between the other two members

  4. the properties of the elements were repeated after regular intervals of 3,4 or 8 elements


Correct Option: A
Explanation:

Newland's Law of octaves stated that if elements (known at Newland's time) were arranged in increasing order of their atomic weights, every eighth element had properties similar to the first element. For example, Li and Na have similar properties.

What were the limitations of Newlands' classification?

  1. It was applicable only for lighter elements

  2. He adjusted two elements on the same place

  3. The pattern was only observed up to calcium

  4. All of the above


Correct Option: D
Explanation:

The limitations of Newlands' classification were:

  • It was only applicable for lighter elements.
  • He adjusted two elements in one place.
  • The pattern was only observed up to calcium.

Newlands' law of octaves worked well only with :

  1. heavier elements

  2. lighter elements

  3. Both A and B

  4. Neither A nor B


Correct Option: B
Explanation:

Newlands' law of octaves worked well with lighter elements only. As the weight is increased, the pattern started changing and was no longer following the law.

The placement of elements in the Newlands' table was compared to :

  1. weeks of a month

  2. notes of music

  3. months of a year

  4. days of a month


Correct Option: B
Explanation:

The placement of elements in the Newlands' periodic table was compared to the notes of music where the first note and the eighth note are same. Similarly, in Newlands' periodic table, the chemical properties also repeat after $7$ elements.

In Newlands' table, which of the following elements was not placed in the same group in which cobalt and nickel were present?

  1. Chlorine

  2. Bromine

  3. Fluorine

  4. None of the above


Correct Option: D
Explanation:

In Newlands' table, chlorine, bromine and fluorine were placed in the same group in which cobalt and nickel were present.

If X and Y are two elements which belong to same group of Newland's periodic table, how many elements exists between X and Y?

  1. $4$

  2. $5$

  3. $6$

  4. $7$


Correct Option: C
Explanation:

In Newland's periodic table, $1$st element and the $8$th element have the same chemical property, i.e., they belong to the same group. So, the table will look like:
$\begin{equation}X\;1\;2\;3\;4\;5\;6 \ Y\end{equation}$
So, there are $6$ elements between X and Y.

Dobereiner grouped the elements into triads and Newland gave the:

  1. law of Octaves

  2. mass number

  3. atomic number

  4. valency


Correct Option: A
Explanation:

In 1864 newlands in chemistry, the generalization made by the English chemist J.A.R. Newlands in 1865 that, if the chemical elements are arranged according to increasing atomic weight, those with similar physical and chemical properties occur after each interval of seven elements. Newlands was one of the first to detect a periodic pattern in the properties of the elements and anticipated later developments of the periodic law. Hence called law of octaves.

Newland could classify elements only upto :

  1. copper

  2. chlorine

  3. calcium

  4. chromium


Correct Option: C
Explanation:

He observed that every eighth element had properties similar to the first element. Elements after atomic no. 40 do not fit in this rule.

The discovery of which of the following group of elements gave a death blow to the Newland's Law?

  1. Inert gases

  2. Alkali metals

  3. Transuranic element

  4. Halogens


Correct Option: A
Explanation:

The discovery of zero group of elements (inert gases) gave a death blow to the Newland's Law.
According to Newlands Law of octaves, when the elements are arranged in the increasing order of atomic weights, the properties of every eighth element are similar to the first one.


Hence, the correct option is $\text{A}$

Which of the following pairs of elements do not follow octave rule?

  1. $Be, B$

  2. $Ca, Sr$

  3. $F, Cl$

  4. $O, S$


Correct Option: A

X and Y are two elements having similar properties which obey Newlands law of octaves. The number of elements in between X and Y respectively are:

  1. 8

  2. 6

  3. 7

  4. 9


Correct Option: B

The Newland's law of octaves for the classification of elements was found to be applicable only up to the element ______________________.

  1. potassium

  2. calcium

  3. cobalt

  4. phosphorous


Correct Option: B
Explanation:

The Newland's law of octaves for the classification of elements was found to be applicable only up to the element calcium.


Law of octaves, in chemistry, the generalization made by the English chemist J.A.R. Newlands in 1865 that, if the chemical elements are arranged according to increasing atomic weight, those with similar physical and chemical properties occur after each interval of seven elements.

 Newlands was one of the first to detect a periodic pattern in the properties of the elements and anticipated later developments of the periodic law.

The elements $A$ and $B$ obey Newland's law of octave. How many elements are there between $A$ and $B$?

  1. 7

  2. 8

  3. 5

  4. 6


Correct Option: D
Explanation:

According to the law of octavesthose with similar physical and chemical properties occur after each interval of seven. 


Thus if $A$ is the first element and $B$ is the eighth element, the number of elements in between $A$ and $B$ is 6.

Hence, option D is correct.

The element which resembled cobalt, nickel and was placed in Newland's table far away from those elements was:

  1. sodium

  2. calcium

  3. iron

  4. chlorine


Correct Option: C
Explanation:

Iron resembled cobalt and nickel and in Newlands' table was placed far away from those elements. It was placed in the last group in Newlands' table.

The element placed with nickel in the table formed by Newlands was :

  1. iron

  2. cobalt

  3. chromium

  4. copper


Correct Option: B

John Newlands arranged the known elements in a/an  ______ order of their atomic _______ .

  1. increasing, masses

  2. decreasing, masses

  3. increasing, numbers

  4. decreasing, numbers


Correct Option: A
Explanation:

John Newlands arranged the known elements in an increasing order of their atomic masses. He started with the element having the lowest atomic mass ( hydrogen ) and ended at thorium which was the $56^{th}$ element. Some of the elements satisfying this order are arranged as $H, Li, Be, B, C, N, O$.

The given arranged sequence on the basis of their increasing atomic masses represents which law of classification of elements?  

$F, Na, Mg, Al, Si, P, S, Cl$ & $K$
  1. Modern table

  2. Newton's law

  3. Newland's law of octaves

  4. Mendeleev's periodic table


Correct Option: C
Explanation:

Elements have been arranged in the following sequence on the basis of their increasing atomic masses.

    $F, Na, Mg, Al, Si, P, S, Cl$ & $K$

Law of octaves is given by the English chemist J.A.R. Newlands in 1865.
It states that if chemical elements are arranged according to increasing atomic weight, similar physical and chemical properties occur after each interval of seven elements.

Newlands was the first to detect a periodic pattern in the properties of the elements and anticipated later developments of the periodic law.

For which of the pair Newland octave rule is not applicable?

  1. $Li,\ Na$

  2. $C,\ Si$

  3. $Mg,\ Ca$

  4. $Cl,\ Br$


Correct Option: D
Explanation:

According to Newland Octave law, when elements are arranged in increasing atomic mass every eighth element has similar properties to the first element.

Further the law was not applicable to elements of higher atomic masses. So, law was applicable till calcium.
Hence, $Cl,Br$ is not applicable to Newland Octave Rule.

Who presented the law of octave? 

  1. Dobereiner

  2. Newland

  3. Lother Meyer

  4. Mendeleev


Correct Option: B
Explanation:
According to Newland's law of octaves, when elements are arranged by increasing atomic mass, the properties of every eighth element starting from any element are a repetition of the properties of the starting element.
Option B is correct.
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