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Periodic Table and Periodicity (Hard)

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Which of the following elements were placed correctly in Mendeleev’s periodic table?

  1. Argon and potassium

  2. Cobalt and nickel

  3. Tillerium and iodine

  4. Oxygen and fluorine


Correct Option: D
Explanation:

Arrangement of oxygen and fluorine was correct in Mendeleev’s periodic table.

Which of the following elements belong to the actinide series?

  1. Ac, Th, Pa

  2. La, Ce, Pr

  3. F, CI, Pr

  4. Sc, Ti, V


Correct Option: A
Explanation:

Ac, Th, Pa are elements belonging to actinides series with atomic numbers 89, 90 and 91, respectively.

Modern periodic table is based on the atomic number of elements. Which of the following experiments proved the significance of the atomic number?

  1. Millikan's drop experiment

  2. Moseley's work on X-ray spectra

  3. Bragg's work on X-ray diffraction

  4. Discovery of X-ray roentgen


Correct Option: B
Explanation:

Moseley was able to show that the frequencies of certain characteristic X-rays emitted from chemical elements are proportional to the square of a number which is close to the element's atomic number; a finding which supported van den Broek and Bohr's model of the atom in which the atomic number is the same as the number of positive charges in the nucleus of the atom.

The screening effect of s orbital electron is

  1. greater than p, but lesser than d and f electrons

  2. lesser than p, d and f electrons

  3. greater than p, d and f electrons

  4. equal to p, d and f electrons


Correct Option: C
Explanation:

Screening effect decreases in the order s > p > d > f.

Which of the following statements is/are not true about the diagonal relationship of Be and Al?

(A) Both react with NaOH to liberate hydrogen. (B) Their oxides are basic. (C) They are made passively by nitric acid. (D) Their carbides give acetylene on treatment with water.

  1. Only (A)

  2. (B) and (C)

  3. Only (D)

  4. (B) and (D)


Correct Option: D
Explanation:

Oxides of Be and Al are amphoteric in nature. Their carbides give methane on treatment with water.

Which of the following is the correct order of polarising powers of cations?

  1. K+ < Be2+ < Mg2+ < Ca2+

  2. K+ < Ca2+ < Mg2+ < Be2+

  3. Ca2+ < Mg2+ < Be2+ < K+

  4. Be2+ < Mg2+ < Ca2+ < K+

  5. Be2+ < Ca2+ < Mg2+ < K+


Correct Option: B
Explanation:

The correct order of polarising powers is K+ < Ca2+ < Mg2+ < Be2+.

Which of the following is correct about ionisation potential?

  1. It is independent of atomic radii.

  2. It increases with increase in atomic radii.

  3. It remains constant with increase in atomic radii.

  4. It decreases with increase in atomic radii.


Correct Option: D
Explanation:

As the atomic radius increases, effective nuclear charge decreases and hence ionisation potential also decreases.

Which of the following statements is true?

  1. Atomic radii of elements decrease gradually from left to right.

  2. Metallic character increases across a period.

  3. Chemical reactivity increases and then decreases across a period.

  4. Chemical reactivity increases across a period.


Correct Option: A
Explanation:

Only statement in option (1) is correct. Atomic radii of elements decrease gradually from left to right because new electrons are added into the same shell and the effective nuclear charge increases across the period.

In which of the following arrangements is the order NOT according to the property indicated against it?

  1. Li < Na < K < Rb : Increasing metallic radii

  2. I < Br < F < Cl : Increasing electron gain enthalpies (with negative sign)

  3. B < C < N < O : Increasing first ionisation enthalpies

  4. Al3+ < Mg2+ < Na+ < F- : Increasing ionic size


Correct Option: C
Explanation:

The correct order is B < C < O < N.

Which of the following pairs contains an example of metalloid elements in the periodic table?

  1. Sodium and potassium

  2. Fluorine and chlorine

  3. Calcium and magnesium

  4. Boron and silicon


Correct Option: D
Explanation:

Boron and silicon are metalloid elements in the periodic table.

From the ground state of electronic configuration of various electrons, which will have the highest second ionisation energy?

  1. 1s2, 2s2, 2p6, 3s2

  2. 1s2, 2s2, 2p6, 3s1

  3. 1s2, 2s2, 2p6

  4. 1s2, 2s2, 2p5


Correct Option: B
Explanation:

The removal of second electron will be from completely filled p-orbital, so it will need the highest energy.

Which of the following elements do not belong to the same group, but show chemical similarities?

  1. Mg, Ca

  2. K, Rb

  3. Be, Al

  4. B, Al


Correct Option: C
Explanation:

Be belongs to group 2 and Al belongs to group 3, but they have chemical similarity due to diagonal relationship.

The electronic configurations of four elements are given as follows:

  1. [Xe] 6s1 2. [Xe] 4f14 5d1 6s2 3. [Ar]4s24p5 4. [Ar]3d74s2

Which of the following statements about these elements is not correct?

  1. 1 is a strong reducing agent.

  2. 2 is a d-block element.

  3. 3 has high electron affinity.

  4. 4 shows variable oxidation state.


Correct Option: B
Explanation:

[Xe] 4f145d16s2 is not a d-block element. It is lutetium and is present in lanthanide series. It is an f-block element.

The successive ionisation energy values for an element 'X' are given below:

(i) 1st ionisation energy = 410 kJ mol-1 (ii) 2nd ionisation energy = 820 kJ mol-1 (iii) 3rd ionisation energy = 1100 kJ mol-1 (iv) 4th ionisation energy = 1500 kJ mol-1 (v) 5th ionisation energy = 3200 kJ mol-1

Find out the number of valence electrons for an atom of 'X'.

  1. 4

  2. 3

  3. 5

  4. 2


Correct Option: A
Explanation:

The ionisation energy values for valence electrons are comparable. To remove electrons from inner shell, very high amount of energy is needed. Among the given values, the biggest jump is between IE4 and IE5. Hence, there are four valence electrons for an atom of 'X'.

Pick out the statement(s) which is/are not true about the diagonal relationship of Li and Mg.

(i) Polarising powers of Li+ and Mg2+ are almost the same. (ii) Both Li and Mg decompose water very quickly. (iii) LiCl and MgCl2 are deliquescent. (iv) Like Li, Mg does not form solid bicarbonates.

  1. (i) and (ii)

  2. (ii) and (iii)

  3. Only (ii)

  4. Only (i)

  5. Only (iii)


Correct Option: C
Explanation:

Lithium and magnesium show diagnol relationship. Some points of similarity are as follows: (i) Polarising power of Li+ and Mg+ are almost the same. (ii) Like Li, Mg decomposes water very slowly. (iii) LiCl and MgCl2 are deliquescent. (iv) Like Li, Mg does not form solid bicarbonates.

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