0

Chemistry (Mixed)

Attempted 0/15 Correct 0 Score 0

The hydrocarbon and the oxide of N2 reacts in presence of ultraviolet light to produce:

  1. O3, PAN

  2. Only PAN

  3. Only aldehyde

  4. O3, PAN and aldehydes

  5. PAN and aldehydes


Correct Option: D
Explanation:

This option is correct because during the reaction of hydrocarbon and oxides of N2 in presence of ultraviolet light, O3, PAN and aldehydes all are produced.

Which ore(s) contain(s) both iron and copper?

  1. Cuprite and chalcocetis

  2. Cuprite and chalocopyrite

  3. Chalocopyrite

  4. Malachite

  5. Malachite and chalocopyrite


Correct Option: C
Explanation:

This option is correct, because this ore, CuFeS2 has iron and copper both.

The trigonal bipyramidal structure occupies in which of the following pairs of the compounds?

  1. XeF2, XeF4

  2. XeO3, XeO4

  3. XeF6, XeOF4

  4. XeO2F2, XeO3F2

  5. XeF2, XeO3F2


Correct Option: D
Explanation:

This option is correct because both XeO2F2, XeO3F2 have the same trigonal bipyramidal structure.

Who among the following prepared borazine?

  1. Stock and Pohland

  2. Stock

  3. Allen and Senoff

  4. Cotton

  5. None of these


Correct Option: A
Explanation:

This option is correct,  because Stock and Pohland (1921) prepared borazine by the reaction of diborane and ammonia at -120 ˚C. In this reaction diammoniate of diborane is formed, which on decomposition at 200 ˚C gives borazine

Which species has maximum number of lone pair of electrons?

  1. PO3-

  2. ClO3-

  3. SO4--

  4. I3-

  5. None of these


Correct Option: D
Explanation:

I3- ion has three lone pair of electron because I- atom containing eight electrons instead of seven, two electron are shared with two I-atom and remaining three lone pairs are left.

The Quadruple bonds occurs in which of the followings compound?

  1. [Re2Cl8]--

  2. [Pt(Cl)2(PPh3)2]

  3. [Co(NH3)4Cl2]

  4. [Mn2(CO)10]

  5. None of these


Correct Option: A
Explanation:

This option is correct, because two Re atoms have eight electrons will occupy one sigma. Two pi and one delta bonding to form quadruple bonds between two Re atoms, i.e., Re-Re distance short to exist eclipsed form.

The styx code of B4H10 is __________.

  1. 4120

  2. 4220

  3. 3203

  4. 4012

  5. None of these


Correct Option: D
Explanation:

This option is correct,  because the B4H10 is having one B-B electron pair, four B-H-B bridge bonds and two BH2 groups. On the bases of its facts this styx code match with B4H10. (hints Styx.i.e.S=No of B-H-B bonds. T=No of B-B-B bonds. Y=No of B-B bonds X=No of BH2 groups.

Which of the following set is an example of foam, emulsion, and aerosol respectively?

  1. Froth soap lather, cod liver oil, clouds

  2. Rock salt, fog, curd

  3. Starch, cream, beaten egg white

  4. Whipped cream, mist, muddy water

  5. None of these


Correct Option: A
Explanation:

This option is correct because the froth soap lather, cod liver oil and clouds belong to set of foam, emulsion and aerosol.

In which category, the compound [Fe4C(CO)12]-2 belong to?

  1. Closo

  2. Nido

  3. Hypho

  4. Arachno

  5. None of these


Correct Option: D
Explanation:

This option is correct because in this carbonyl compound, total electron counts to be 62,  and electron used for non skeletal bonding is 48. Therefore skeletal electron pair available for frame work bonding 1/2[62 - 48]=7e pairs, i.e., m = 4,  hence occupies (4+3)e pairs,  predicted in (m+4) rule.

Which of the following is used as an anti-knocking agent?

  1. Feron

  2. Glycol

  3. Glyoxal

  4. TEL

  5. All of these


Correct Option: D
Explanation:

Anti-knocking agents are those compounds, which on adding gasoline in a very small quantity reduce knocking. TEL (C2H5)4Pb is added the extent of only 0.01% in gasoline as antiknocking compound.

Which of the following metal carbonyl absorbs lowest infrared frequency?

  1. [V(CO)6]-

  2. [Ti(CO)6]--

  3. [Mn(CO)6]+

  4. [Cr(CO)6]

  5. None of these


Correct Option: B
Explanation:

This option is correct,  because the two excess electron of metal ions shifted towards antibonding MOs of CO ligand resulting CO bond order is very low, due to this fact infrared frequency highly decreases.

Which of the following pair of coordination compound has same magnetic moments?

  1. [Mn(CN)2(NH3)4], [Fe(CN)3(H2O)3]

  2. K2[Co(Cl)2(OH)2(NH3)2], [Zn(H2O)2(Py)2(NO2)2]

  3. [V(C2H5O)2(en)2], [Ni(CN)2(NH3)4]

  4. [Fe(CN)3(NH3)3] [Cr(CO)3(Cl)3]

  5. Both 1 and 2


Correct Option: A
Explanation:

This option is correct, because the central metal ions of both the compounds have same (five) unpaired electron in their d-orbitals, on basis of this fact both compounds show the same magnetic moment.

Which of the following pairs have similar structures? (A) N3-, XeF2 (B) [ ICl4]-, [PtCl4]-- (C) [ClF2]+, [ICl2]- (D) XeO3, SO3

  1. Only A

  2. Only B

  3. Both A and B

  4. A and C

  5. A, C and D


Correct Option: C
Explanation:

This option is correct,  because the N3-, XeF2 is show the linear structure but ICl4- , PtCl4-- is show the both square planar structure. 

Which of the following is speier salt?

  1. H2PtCl6

  2. RhCl(PPh3)3

  3. Al(C2H5)3

  4. Co2(CO)8

  5. None of these


Correct Option: A
Explanation:

This option is correct,   the speier catalyst is generated from chloroplatinic acid. It is used in hydrosilyation,  i.e.,  called catalytic hydrosilylation.

Which of the following is shift reagent?

  1. (NH4)2S2O8

  2. KMnO4

  3. [Ce(NO3)4.2NH4NO3]

  4. [Eu(dmp)3]

  5. [Rh(PPh3)3Cl]


Correct Option: D
Explanation:

This option is correct,  because the shift reagent [tris-(dipivalomethanato)europium] are ion in a rare earth coordinate to organic ligand such as beta-ketone of Eu+3. These are synthesized more recent shift reagent.

- Hide questions