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Chemistry (Mixed Test)

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Among the following electronegativities, ____________ is related to the charge experienced by an electron on the surface of an atom.

  1. Pauling electronegativity

  2. Mulliken electronegativity

  3. Sanderson electronegativity

  4. Allred-Rochow electronegativity


Correct Option: D
Explanation:

Allred and Rochow considered that electronegativity should be related to the charge experienced by an electron on the surface of an atom. The higher the charge per unit area of atomic surface, the greater the tendency of that atom to attract electrons. The effective nuclear charge, Z* experienced by valence electrons can be estimated using Slater's rules.

The compounds containing ______________ are called salts.

  1. halogens

  2. Pnictogens

  3. Chalcogens

  4. Noble gases


Correct Option: A
Explanation:

The halogens are five non-metallic elements found in group 17 of the periodic table. The term halogen means salt-former and compounds containing halogens are called salts. All halogens have 7 electrons in their outer shells, giving them an oxidation number of -1. The halogens exist, at room temperature, in all three states of matter:

Which of the following is a hexagonal allotrope of the carbon ?

  1. Linear acetylenic carbon

  2. Lonsdaleite

  3. Carbon nanofoam

  4. Carbene


Correct Option: B
Explanation:

Lonsdaleite is a hexagonal allotrope of the carbon allotrope diamond, believed to form from graphite present in meteorites upon their impact to Earth. The great heat and stress of the impact transforms the graphite into diamond, but retains graphite's hexagonal crystal lattice.

Among the following allotropes, which one is a predicted metastable carbon allotrope ?

  1. Chaoite

  2. Body-centered cubic carbon

  3. Body-centered tetragonal carbon

  4. Prismane C8


Correct Option: D
Explanation:

Prismane C8 is a theoretically predicted metastable carbon allotrope comprising an atomic cluster of eight carbon atoms, with the shape of an elongated triangular bipyramid- a six-atom triangular prism with two more atoms above and below its bases.

Which of the followng metals are resistant to corrosion and oxidation in moist air?

  1. Noble metals

  2. Post-transition metal

  3. Poor metals

  4. Transition metals


Correct Option: A
Explanation:

Noble metals are metals that are resistant to corrosion and oxidation in moist air, unlike most base metals.They tend to be precious, often due to their rarity in the earth's crust. The noble metals are considered to be (in order of increasing atomic number) ruthenium, rhodium, palladium, silver, osmium, iridium, platinum, and gold.

Helium is a noble gas.It is placed in __________.

  1. the s-block

  2. the p-block

  3. the d-block

  4. the f-block


Correct Option: A
Explanation:

The s-block of the periodic table of elements consists of the first two groups: the alkali metals and alkaline earth metals, plus hydrogen and helium.These elements are distinguished by the property that in the atomic ground state, the highest energy electron is in a s-orbital. Except in hydrogen and helium, these electrons are very easily lost to form positive ions.

Which of the following resembles the balls used in association football?

  1. Carbon nanotubes

  2. Fullerenes

  3. Diamond

  4. Rhenium diboride


Correct Option: B
Explanation:

A fullerene is any molecule composed entirely of carbon, in the form of a hollow sphere, ellipsoid, or tube. Spherical fullerenes are also called buckyballs, and they resemble the balls used in association football. Cylindrical ones are called carbon nanotubes or buckytubes.

The elementary particle similar to the electron is

  1. strange quark

  2. charm quark

  3. muon

  4. tau


Correct Option: C
Explanation:

The muon is an elementary particle similar to the electron, with a unitary negative electric charge and a spin of 1/2. Together with the electron, the tau, and the three neutrinos, it is classified as a lepton.

Which of the following is the lightest of all the quarks?

  1. The up quark

  2. The down quark

  3. The bottom quark

  4. The top quark


Correct Option: A
Explanation:

The up quark or u quark (from its symbol, u) is the lightest of all quarks, a type of elementary particle, and a major constituent of matter. It, along with the down quark, forms the neutrons (one up quark, two down quarks) and protons (two up quarks, one down quark) of atomic nuclei.

The metals having outstanding catalytic properties are

  1. the alkali metals

  2. the alkaline earth metals

  3. refractory metals

  4. the platinum metals


Correct Option: D
Explanation:

The platinum group metals is a term used sometimes to collectively refer to six metallic elements clustered together in the periodic table. These elements are all transition metals.The platinum metals have outstanding catalytic properties. They are highly resistant to wear and tarnish, making platinum, in particular, well suited for fine jewellery. Other distinctive properties include resistance to chemical attack, excellent high-temperature characteristics, and stable electrical properties.

The subatomic particles composed of one quark and one antiquark is

  1. neutron

  2. hadron

  3. baryon

  4. mesons


Correct Option: D
Explanation:

Mesons are subatomic particles composed of one quark and one antiquark, bound together by the strong interaction. Because mesons are composed of sub-particles, they have a physical size, with a radius roughly one femtometer: 10-15 m, which is about 2⁄3 the size of a proton or neutron.

There are several known allotropes of oxygen. Among these ___________ is the diamagnetic form of molecular oxygen .

  1. dioxygen

  2. singlet oxygen

  3. triatomic oxygen

  4. tetraoxygen


Correct Option: B
Explanation:

Singlet oxygen is the common name used for the diamagnetic form of molecular oxygen which is less stable than the normal triplet oxygen. Because of its unusual properties, singlet oxygen can persist for over an hour at room temperature, depending on the environment.

Which among the following is not a component of Boiling Water Reactor (BWR)?

  1. Containment

  2. Steam generator

  3. Pressure vessel or pressure tubes

  4. Control rods


Correct Option: B
Explanation:

Part of the cooling system where the primary coolant bringing heat from the reactor is used to make steam for the turbine. Reactors may have up to four loops, each with a steam generator. It is not a component of Boiling Water Reactor (BWR).

The ferrite characterised by needle shaped crystallites is

  1. acicular ferrite

  2. ausferrite

  3. martensite

  4. zinc ferrites


Correct Option: A
Explanation:

Acicular ferrite is a microstructure of ferrite that is characterised by needle shaped crystallites or grains when viewed in two dimensions. The grains, actually three dimensional in shape, have a thin lenticular shape. This microstructure is advantageous over other microstructures because of its chaotic ordering, which increases toughness.

Among the following ___________ is commonly referred to as solutions.

  1. chemical element

  2. homogenous mixture

  3. compound

  4. hetrogenous mixture


Correct Option: B
Explanation:

A homogeneous mixture has the same uniform appearance and composition throughout. Many homogeneous mixtures are commonly referred to as solutions.

Among the following allotropes, the thermodynamically stable form of phosphorus at room temperature is

  1. diphosphorus

  2. white phosphorus

  3. red phosphorus

  4. black phosphorus


Correct Option: D
Explanation:

Black phosphorus is the thermodynamically stable form of phosphorus at room temperature and pressure. It is obtained by heating white phosphorus under high pressures (12,000 atmospheres). In appearance, properties and structure it is very like graphite, being black and flaky, a conductor of electricity, and having puckered sheets of linked atoms.

Which among the following are the second generation of British gas-cooled reactors?

  1. Boiling Water Reactor

  2. Pressurized Water Reactors

  3. Liquid-Metal Fast-Breeder Reactor

  4. Advanced Gas-cooled Reactor (AGR)


Correct Option: D
Explanation:

These are the second generation of British gas-cooled reactors, using graphite moderator and carbon dioxide as coolant. The fuel is uranium oxide pellets, enriched to 2.5-3.5%, in stainless steel tubes. The carbon dioxide circulates through the core, reaching 650°C and then past steam generator tubes outside it, but still inside the concrete and steel pressure vessel. Control rods penetrate the moderator and a secondary shutdown system involves injecting nitrogen to the coolant.

Among the following which one is a newly discovered allotrope of carbon ?

  1. Graphene

  2. Carbon nanotubes

  3. Carbon nanobuds

  4. Glassy carbon


Correct Option: C
Explanation:

Carbon nanobuds are a newly discovered allotrope of carbon in which fullerene like buds are covalently attached to the outer sidewalls of the carbon nanotubes. This hybrid material has useful properties of both fullerenes and carbon nanotubes. For instance, they have been found to be exceptionally good field emitters.

The allotrope of boron containing unit cell of twelve boron atoms is

  1. amorphous boron

  2. β-rhombohedral boron

  3. α-rhombohedral boron

  4. γ-boron


Correct Option: C
Explanation:

α-rhombohedral boron has a unit cell of twelve boron atoms. The structure consists of B12 icosahedra in which each boron atom has five nearest neighbors within the icosahedron. If the bonding were the conventional covalent type then each boron would have donated 5 electrons.

Which of the following is processed to make it extremely porous and have a very large surface area ?

  1. Chaoite

  2. Activated carbon

  3. Carbon black

  4. Charcoal


Correct Option: B
Explanation:

Activated carbon, also called activated charcoal, activated coal or carbo activatus, is a form of carbon that has been processed to make it extremely porous and thus to have a very large surface area available for adsorption or chemical reactions.

Which of the following is consists of extremely thin fibers?

  1. Char

  2. Biochar

  3. Carbon fiber

  4. Aggregated diamond nanorods


Correct Option: C
Explanation:

Carbon fiber alternatively graphite fiber, carbon graphite or CF, is a material consisting of extremely thin fibers about 5-10 μm in diameter and composed mostly of carbon atoms. The carbon atoms are bonded together in microscopic crystals that are more or less aligned parallel to the long axis of the fiber.

Inside the nuclear reactor, the nuclear fuel assemblies are located in

  1. the nuclear reactor core

  2. the reactor vessel

  3. a neutron moderator

  4. a steam generator


Correct Option: A
Explanation:

The nuclear reactor core is the region with in a nuclear reactor where the nuclear fuel assemblies are located and the nuclear reaction consequently takes place. The core of the reactor contains all the nuclear fuels and generates all of the heat. It contains low-enriched uranium, controls systems and structural materials.The core contain hundreds of thousands of individual fuel pins.

The neutron moderator materials are found in ___________.

  1. thermal reactors

  2. fast neutron reactors

  3. pressurized heavy water reactor (PHWR)

  4. molten salt reactor


Correct Option: A
Explanation:

Thermal reactors use slowed or thermal neutrons. Almost all current reactors are of this type. These contain neutron moderator materials that slow neutrons until their neutron temperature is thermalised, that is, until their kinetic energy approaches the average kinetic energy of the surrounding particles.

The acid used as a bleach, a deodorant and a disinfectant is

  1. chlorous acid

  2. hypochlorous acid

  3. chloric acid

  4. perchloric acid


Correct Option: B
Explanation:

Hypochlorous acid is a weak acid with the chemical formula HClO. It forms when chlorine dissolves in water. It cannot be isolated in pure form due to rapid equilibration with its precursor. HClO is an oxidizer, and as its sodium salt; sodium hypochlorite, (NaClO), or its calcium salt calcium hypochlorite, is used as a bleach, a deodorant, and a disinfectant.

Among the following properties, which can be determined in gaseous state only?

  1. The ionisation energy

  2. The electron affinity

  3. Electronegativity

  4. The atomic radius


Correct Option: B
Explanation:

The electron affinity of a molecule or atom is the energy change when an electron is added to the neutral atom to form a negative ion. This property can only be measured in an atom in gaseous state.

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