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Chemistry Test

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The effect describing that warmer water sometimes freezes faster than colder water is

  1. The Leidenfrost effect

  2. The Mpemba effect

  3. The Thermo-dielectric effect

  4. The Barnett effect


Correct Option: B
Explanation:

The Mpemba effect is the observation that warmer water sometimes freezes faster than colder water. Although the observation has been verified, there is no single scientific explanation for the effect.

Which among the following can be excluded from the postulates of kinetic theory?

  1. The molecular collisions are perfectly inelastic in nature.

  2. The actual volume of the molecules is negligible as compared to the total volume of the gas.

  3. The molecules are in a state of constant rapid motion.

  4. All gases are made up of molecules.


Correct Option: A
Explanation:

The molecular collisions are perfectly elastic with no loss of energy and only redistribution of energy during collision.

The vapour pressure of the liquid becomes equal to the environmental pressure at

  1. boiling point

  2. critical point

  3. lambda point

  4. melting point


Correct Option: A
Explanation:

The boiling point of an element or a substance is the temperature at which the vapor pressure of the liquid equals the environmental pressure surrounding the liquid.

Which of the following effects describes that the properties of a molecule are affected by its surroundings?

  1. The cage effect

  2. The common ion effect

  3. The de Haas-van Alphen effect

  4. The Ettingshausen effect


Correct Option: A
Explanation:

The cage effect in chemistry describes how properties of a molecule are affected by its surroundings. In a solvent a molecule is often more accurately described existing in a cage of solvent molecules, the so-called solvent cage. Reactions occur when a molecule occasionally jumps out and meets another molecule. Typical cage lifetime in a solvent cage is 10−11 s .

Which of the following statement is wrong regarding the solids?

  1. Solids are almost incompressible.

  2. The rate of diffussion is very high.

  3. Most solids become liquids when heated.

  4. Many solids have a crystalline appearance .


Correct Option: B
Explanation:

Solids diffuse very slowly as compared to liquids and gases. Constituent particles are very closely packed in solids permitting very little space for their movement.

The constituents of ------------------- crystals are held together by strong electrostatic forces.

  1. molecular

  2. ionic

  3. covalent

  4. metallic


Correct Option: B
Explanation:

The ionic crystals consist of positively and negatively charged ions arranged in a regular fashion throughout the crystal. They form a network of positive and negative ions in three dimension in such a way that cations and anions occupy alternate sites. These are held together by strong electrostatic forces.

In which of the following phenomenons a substance posses exactly zero electrical resistance ?

  1. Supercooling

  2. Superconductivity

  3. superheating

  4. Superfluidity


Correct Option: B
Explanation:

Superconductivity is a phenomenon of exactly zero electrical resistance occurring in certain materials below a characteristic temperature. It was discovered by Heike Kamerlingh Onnes on April 8, 1911 in Leiden. Like ferromagnetism and atomic spectral lines, superconductivity is a quantum mechanical phenomenon.

Which among the following is a particular form of quark matter?

  1. Nuclear matter

  2. Quark matter

  3. Strange matter

  4. Rydberg matter


Correct Option: C
Explanation:

Strange matter is a particular form of quark matter, usually thought of as a liquid of up, down, and strange quarks. It is to be contrasted with nuclear matter, which is a liquid of neutrons and protons (which themselves are built out of up and down quarks), and with non-strange quark matter, which is a quark liquid containing only up and down quarks.

Which of the following is a type of stellar remnant ?

  1. Compact star

  2. Neutron star

  3. Quark star

  4. Preon star


Correct Option: B
Explanation:

A neutron star is a type of stellar remnant that can result from the gravitational collapse of a massive star during a Type II, Type Ib or Type Ic supernova event. Such stars are composed almost entirely of neutrons, which are subatomic particles without electrical charge and with a slightly larger mass than protons.

Which among the following can be excluded from the characteristics of catalysis ?

  1. A catalyst is needed in small amounts.

  2. The catalyst initiates the reaction.

  3. The catalyst is generally specific in nature.

  4. The catalyst cannot change the position of equilibrium.


Correct Option: B
Explanation:

The function of the catalyst is to alter the speed of the reaction rather than to start it.

The rate of oxidation of oxalic acid by acidified potassium permanganate increases as the reaction progresses. Which type of catalysis is this?

  1. Auto catalysis

  2. Induced catalysis

  3. Acid base catalysis

  4. Electro catalysis


Correct Option: A
Explanation:

In certain reactions, one of the product acts as a catalyst. In the initial stages the reaction is slow but as soon as the products come into existence the reaction rate increases. This type of phenomenon is known as auto-catalysis. For examples The rate of oxidation of oxalic acid by acidified potassium permanganate increases as the reaction progresses. This acceleration is due to the presence of Mn2+ ions which are formed during reaction. Thus Mn2+ ions act as auto-catalyst.

Among the following which one is also known as Vander Waal's adsorption?

  1. Positive adsorption

  2. Negative adsorption

  3. Physical adsorption

  4. Chemical adsorption


Correct Option: C
Explanation:

If the forces of attraction existing between adsorbate and adsorbent are Vander Waal's forces, the adsorption is called physical adsorption. This type of adsorption is also known as physisorption or Vander Waal's adsorption. It can be easily reversed by heating or decreasing the pressure.

The Pauli Exclusion Principle is applicable to ----------------------- .

  1. quark degeneracy

  2. neutron degeneracy

  3. proton degeneracy

  4. electron degeneracy


Correct Option: D
Explanation:

In ordinary gas, most of the electron energy levels (n-spheres) are unfilled and the electrons are free to move . As particle density is increased electrons progressively, fill the lower energy states and additional electrons are forced to occupy states of higher energy. Degenerate gases strongly resist further compression because the electrons cannot move to lower energy levels, which are already filled. The Pauli Exclusion Principle causes this.

In which of the following state of matter a substance flows with zero viscosity?

  1. Superfluid

  2. Supersolid

  3. Superglass

  4. Supercritical fluid


Correct Option: B
Explanation:

A supersolid is a spatially ordered material with superfluid properties. Superfluidity is a special quantum state of matter in which a substance flows with zero viscosity.

Oxidation of benzaldehyde is an example of ----------------------- catalysis.

  1. homogeneous

  2. heterogeneous

  3. positive

  4. negative


Correct Option: D
Explanation:

There are certain, substance which, when added to the reaction mixture, retard the reaction rate instead of increasing it. These are called negative catalyst or inhibitors and the phenomenon is known as negative catalysis. Some examples are as follows. (i) Oxidation of sodium sulphite (ii) Oxidation of benzaldehyde

Streaming potential is produced when a liquid is forced to flow through a capillary or a porous solid. It is a reverse process of

  1. sedimentation

  2. electro-osmosis

  3. electrophoresis

  4. tyndall effect


Correct Option: B
Explanation:

Electro-osmosis is a phenomenon in which dispersion medium is allowed to move under the influence of an electrical field, whereas colloidal particles are not allowed to move. The existence of electro-osmosis has suggested that when liquid forced through a porous material or a capillary tube, a potential difference is setup between the two sides called as streaming potential. So the reverse of electro-osmosis is called streaming potential.

Which among the following is a type of electromagnetic spectroscopy ?

  1. Atomic absorption spectroscopy

  2. Atomic emission spectroscopy

  3. Fluorescence spectroscopy

  4. Absorption spectroscopy


Correct Option: C
Explanation:

Fluorescence spectroscopy is a type of electromagnetic spectroscopy which analyses fluorescence from a sample. It involves using a beam of light, usually ultraviolet light, that excites the electrons in molecules of certain compounds and causes them to emit light of a lower energy, typically, but not necessarily, visible light.

The artificial kidney machine works on the principle of

  1. Dialysis

  2. Electrodialysis

  3. Ultrafiltration

  4. Ultracentrifugation


Correct Option: B
Explanation:

The ordinary process of dialysis is slow. To increase the process of purification, the dialysis is carried out by applying electric field. This process is called electrodialysis. The important application of electrodialysis process in the artificial kidney machine used for the purification of blood of the patients whose kidneys have failed to work. The artificial kidney machine works on the principle of electrodialysis.

In true Solution, the solute in solvent has the particle size of less than 10-9 m or 1 nm. Which of the following colloids resemble true solutions in many respects?

  1. Multimolecular colloids

  2. Macromolecular colloidal

  3. Associated colloids

  4. Lyophilic colloids


Correct Option: B
Explanation:

Macromolecular colloidal particles are formed when on dissolution in a suitable solvent, the macromolecules have sizes which are in the colloidal range. Naturally occurring macromolecules are starch, proteins and cellulose. Man made macromolecules are polymers such as polyethylene, nylon and polystyrene. These colloids are quite stable and resemble true solutions in many respects.

In which of the following processes, a proton is converted into a neutron?

  1. Positron emission

  2. Proton emission

  3. Neutron emission

  4. Electron capture


Correct Option: A
Explanation:

Positron emission is a type of beta decay in which a proton is converted, via the weak force, to a neutron, releasing a positron (the antimatter counterpart of an electron) and a neutrino. Isotopes which undergo this decay and thereby emit positrons include carbon-11, potassium-40, nitrogen-13, oxygen-15, fluorine-18, and iodine-121.

The metals like silver, gold and platinum, have been obtained in colloidal state by

  1. by excessive cooling

  2. by exchange of solvent

  3. by hydrolysis

  4. by reduction


Correct Option: D
Explanation:

A number of metals such as silver, gold and platinum, have been obtained in colloidal state by treating the aqueous solution of their salts, with a suitable reducing agent such as formaldehyde, phenyl hydrazine, hydrogen peroxide, stannous chloride etc.

Which of the following decay processes is mediated by the weak force?

  1. Cluster decay

  2. Beta decay

  3. Double beta decay

  4. Alpha decay


Correct Option: B
Explanation:

Beta decay is a type of radioactive decay in which a beta particle (an electron or a positron) is emitted. In the case of electron emission, it is referred to as beta minus while in the case of a positron emission it is referred as beta plus.In electron emission, an electron antineutrino is also emitted, while positron emission is accompanied by an electron neutrino. Beta decay is mediated by the weak force.

Graphite is sometimes used as

  1. fuel rods

  2. moderator

  3. coolant

  4. shield


Correct Option: B
Explanation:

The speeds of the neutrons produced in the fission have to be slowed down so that they are easily captured by the fuel and the fission process can take place most effectively. This is done by surrounding the fuel rods with heavy water .The material used to slow down the neutrons (without absorbing them) is called a moderator. Graphite is also used as a moderator sometimes.

The radiactive isotope used for locating brain tumors and damaged heart cells is

  1. iodine-131

  2. thallium-201

  3. technetium-99m

  4. sodium-24


Correct Option: C
Explanation:

Technetium-99m is used for locating brain tumors and damaged heart cells.Technetium-99m is probably the most widely used radioisotope in medicine today; it is a decay product of molybdenum-99.

The pressurized water reactor (PWR), the boiling water reactor (BWR), and the supercritical water reactor (SCWR)are the varieties of

  1. a pressurised heavy water reactor (PHWR)

  2. the light water reactor

  3. a molten salt reactor

  4. a liquid metal cooled nuclear reactor


Correct Option: B
Explanation:

The light water reactor (LWR) is a type of thermal reactor that uses normal water as its coolant and neutron moderator. Thermal reactors are the most common type of nuclear reactor, and light water reactors are the most common type of thermal reactor. There are three varieties of light water reactors- the pressurized water reactor (PWR), the boiling water reactor (BWR), and (most designs of) the supercritical water reactor (SCWR).

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