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Physical Chemistry Test

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The catalyst used as a transesterification catalyst is

  1. Adams' catalyst

  2. Grubbs' Catalysts

  3. Lindlar catalyst

  4. Otera's catalyst


Correct Option: D
Explanation:

Otera's catalyst is an organostannane compound which has been used as a transesterification catalyst. This isothioscyanate compound is a member of a family of organostannanes

GAA and GAG are the codons for------------------------- amino acids.

  1. lysine

  2. arginine

  3. aspartic acid

  4. Glutamic acid


Correct Option: D
Explanation:

Glutamic acid is one of the 20 proteinogenic amino acids, and its codons are GAA and GAG. It is a non-essential amino acid.

In which of the following catalysis, multiple catalysts acts on a single molecule of a substrate?

  1. Concurrent tandem catalysis

  2. Heterogeneous catalysis

  3. Homogeneous catalysis

  4. Phase Boundary Catalysis


Correct Option: A
Explanation:

Concurrent tandem catalysis (CTC) is a technique in chemistry which uses multiple catalysts on a single molecule in a one-pot vessel to produce a product otherwise not accessible by a single catalyst.

The toxicity of exhaust emissions from an internal combustion engine is reduced by --------------------.

  1. a catalytic triad

  2. catalytic oxidation

  3. a catalytic cycle

  4. a catalytic converter


Correct Option: D
Explanation:

A catalytic converter is a device used to reduce the toxicity of exhaust emissions from an internal combustion engine.

The retardation of anodic reaction occurs in

  1. cathodic modification

  2. cathodic protection rectifiers

  3. chrome plating

  4. electroplating


Correct Option: A
Explanation:

Cathodic modification is the retardation of anodic reaction as the result of an increase in the ability of an alloy to be passivated by the introduction of an active cathode into the alloy e.g., the alloying of stainless steel and titanium with platinum group metals

In which of the following reactions, iron(II) hydroxide (Fe(OH)2) gets converted into iron(II,III) oxide (Fe3O4)?

  1. The hydroamination reaction

  2. Soai reaction

  3. The Sharpless Epoxidation reaction

  4. The Schikorr reaction


Correct Option: D
Explanation:

The Schikorr reaction formally describes the conversion of the iron(II) hydroxide (Fe(OH)2) into iron(II,III) oxide (Fe3O4). It can occur in the process of anaerobic corrosion of iron and carbon steel in various conditions.

In which of the processes, zinc plating is done on steel in order to prevent corrosion?

  1. Anodic protection

  2. Cathodic protection

  3. Anodizing

  4. Bethanization


Correct Option: D
Explanation:

Bethanization is a process to protect steel from corrosion by plating it with zinc.

In which of the following processes, a hard non-reactive surface film is formed which inhibits further corrosion?

  1. Galvanization

  2. Parkerizing

  3. Passivation

  4. Quench polish quench


Correct Option: C
Explanation:

In the context of corrosion, passivation is the spontaneous formation of a hard non-reactive surface film that inhibits further corrosion. This layer is usually an oxide or nitride that is a few nanometers thick.

Which of the following electrodes has a stable and well-known electrode potential?

  1. The Auxiliary electrode

  2. A reference electrode

  3. The Clark electrode

  4. A carbon-paste electrode


Correct Option: B
Explanation:

A reference electrode is an electrode which has a stable and well-known electrode potential. The high stability of the electrode potential is usually reached by employing a redox system with constant (buffered or saturated) concentrations of each participants of the redox reaction.

Which of the following electrodes measures carbon dioxide ?

  1. The Saturated Calomel Electrode

  2. The Severinghaus electrode

  3. A silver chloride electrode

  4. The standard hydrogen electrode


Correct Option: B
Explanation:

The Severinghaus electrode is an electrode that measures carbon dioxide. It utilizes a CO2-sensitive glass electrode in a surrounding film of bicarbonate solution covered by a thin plastic carbon dioxide permeable membrane, but impermeable to water and electrolytic solutes.

Among the following, -------------------is a type of ion-selective electrode.

  1. a reversible hydrogen electrode

  2. a rotating ring-disk electrode

  3. A rotating disk electrode

  4. a glass electrode


Correct Option: D
Explanation:

A glass electrode is a type of ion-selective electrode made of a doped glass membrane that is sensitive to a specific ion. It is an important part of the instrumentation for chemical analysis and physico-chemical studies.

Which among the following minimises the energy consumption and maximises the picture brightness?

  1. A black layer

  2. A cold cathode

  3. The control grid

  4. Hot cathode


Correct Option: A
Explanation:

A black layer is a coat on the filament of the indirectly heated hot cathode in a cathode ray tube, intended to optimise the output of electrons from the cathode, thus minimising the energy consumption and heat generated while maximising the picture brightness.

Heterogeneous graphite, graphene and graphene oxide are used in -------------------- catalysis.

  1. acid catalysis

  2. autocatalysis

  3. biocatalysis

  4. carbocatalysis


Correct Option: D
Explanation:

Carbocatalysis is a form of catalysis that uses heterogeneous graphite, graphene, graphene oxide, or closely related carbon materials for the transformation or synthesis of organic or inorganic substrates. The catalysts are characterized by their high surface areas, surface functionality and large, aromatic basal planes.

The catalyst used for the hydrogenation of vegetable oils is

  1. raney nickel

  2. hopcalite

  3. aliquat 336

  4. cerium (IV) oxide


Correct Option: A
Explanation:

Raney nickel is a solid catalyst composed of fine grains of a nickel-aluminium alloy, used in many industrial processes. It is used as an  catalyst for the hydrogenation of vegetable oils in industrial processes.

Mandrel is used in ---------------------- process.

  1. electrowinning

  2. electrorefining

  3. electroplating

  4. electroforming


Correct Option: D
Explanation:

Electroforming is a metal forming process that forms thin parts through the electroplating process. The part is produced by plating a metal skin onto a base form, known as a mandrel, which is removed after plating.

The individual half-cells are separated by a porous membrane in

  1. a concentration cell

  2. an electrolytic cell

  3. a galvanic cell

  4. a lemon battery


Correct Option: C
Explanation:

A galvanic cell, derives electrical energy from chemical reactions taking place within the cell. It generally consists of two different metals connected by a salt bridge, or individual half-cells separated by a porous membrane.

The hydrogen-absorbing alloy is used by

  1. alkaline battery

  2. nickel-cadmium battery

  3. lithium-ion battery

  4. nickel-metal hydride cell


Correct Option: D
Explanation:

A nickel-metal hydride cell is a type of rechargeable battery similar to the nickel-cadmium cell. The NiMH battery uses a hydrogen-absorbing alloy for the negative electrode instead of cadmium.

An analyte is a substance being determined in an analytical process. Among the following, --------------------- is used in the detection of an analyte?

  1. biofuel

  2. biogas

  3. biosensor

  4. bioreactor


Correct Option: C
Explanation:

Biosensor is a device for the detection of an analyte that combines a biological component with a physicochemical detector component.

In -------------------- process, a power station is restored to operate without relying on external energy sources.

  1. back pressure

  2. baffle

  3. busbar

  4. black start


Correct Option: D
Explanation:

A black start is the process of restoring a power station to operation without relying on external energy sources.

-------------------- is the industrial process for the production of aluminium.

  1. The Castner process

  2. The Castner-Kellner process

  3. The Chloralkali process

  4. The Hall-Héroult process


Correct Option: D
Explanation:

The Hall-Héroult process is the major industrial process for the production of aluminium. It involves dissolving alumina in molten cryolite, and electrolysing the molten salt bath to obtain pure aluminium metal.

The --------------------------------- enzymes can bring rearrangement in the substrate molecules.

  1. oxidoreductases

  2. transferases

  3. isomerases

  4. ligases


Correct Option: C
Explanation:

Isomerases just rearrange the existing atoms of a molecule, that is, create isomers of the starting material.

Which of the following helps in reducing the dynatron effect?

  1. Static dischargers

  2. A suppressor grid

  3. A tunnel junction

  4. ISFET


Correct Option: B
Explanation:

A suppressor grid is a grid used in a thermionic valve (also called vacuum tube) to suppress secondary emission. A suppressor grid is also called the antidynatron grid, as it helps to reduce the dynatron effect.

Which among the following is a type of ion selective electrode ?

  1. The dropping mercury electrode

  2. A dynamic hydrogen electrode

  3. A fluoride selective electrode

  4. Gas diffusion electrodes


Correct Option: C
Explanation:

A fluoride selective electrode is a type of ion selective electrode sensitive to the concentration of the fluoride ion. A common example is the lanthanum fluoride electrode.

The enzyme which helps the break down of milk in human body is

  1. caseinase

  2. catalase

  3. horseradish peroxidase

  4. oxidoreductase


Correct Option: A
Explanation:

Caseinase is an enzyme that is produced by the human body to help break down milk.

Which of the following is an enzyme?

  1. Chymotrypsin

  2. Tyrosine

  3. Tryptophan

  4. Phenylalanine


Correct Option: A
Explanation:

Chymotrypsin is a digestive enzyme that can perform proteolysis. It is synthesized in the pancreas by protein biosynthesis as a precursor called chymotrypsinogen that is enzymatically inactive.

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