0

Surface Chemistry

Description: This test contains 25 multiple choice questions on surface chemistry.
Number of Questions: 25
Created by:
Tags: Adsorbtion absobtion colloids gel etc Physical and Chemical Adsorption Surface Chemistry Applications of Adsorption Catalysis Applications of Colloids Preparation and Properties of Colloids Emulsions
Attempted 0/25 Correct 0 Score 0

Which of the following is the measure of the amount of gas a surface contains?

  1. Substrate

  2. Exposure

  3. Coverage

  4. Adsorption


Correct Option: B
Explanation:

It is a measure of the amount of gas which a surface contains; more specifically, it is the product of the pressure and time of exposure (normal unit is the Langmuir, where 1 L = 10-6 Torr s).

Which of the following factors does not affect adsorption of a gas on a solid adsorbent?

  1. Nature of adsorbate

  2. Nature of the adsorbent

  3. Specific area of adsorbent

  4. None of these


Correct Option: D
Explanation:

Adsorption of gases on solids depends on all the above factors.

In which of the following phenomena, a substance is released from or through a surface?

  1. Desorption

  2. Absorption

  3. Adsorption

  4. Sorption


Correct Option: A
Explanation:

Desorption is a phenomenon whereby a substance is released from or through a surface. This occurs in a system being in the state of sorption equilibrium between bulk phase (fluid, i.e. gas or liquid solution) and an adsorbing surface (solid or boundary separating two fluids).

Which of the following does not characterise chemical adsorption?

  1. The heat of adsorption is low.

  2. It is specific in nature.

  3. It increases with increase in temperature.

  4. Only single layer adsorption is possible.


Correct Option: A
Explanation:

Due to strong chemical bonds formed between adsorbent and adsorbate, the heat of adsorption is generally high.

Haber process is an example of

  1. heterogeneous catalysis

  2. homogeneous catalysis

  3. electrocatalysis

  4. organocatalysis


Correct Option: A
Explanation:

Heterogeneous catalysts act in a different phase than the reactants. Most heterogeneous catalysts are solids that act on substrates in a liquid or gaseous reaction mixture. For example, in the Haber process, finely divided iron serves as a catalyst for the synthesis of ammonia from nitrogen and hydrogen.

Which of the following statements regarding the uses of catalysts are wrong?

  1. They can be used in energy processing

  2. They can not be used for large-scale production of chemicals

  3. They can be used in the preparation of fine chemicals

  4. They can be used in food processing


Correct Option: B
Explanation:

Some chemicals are produced on large scale via catalytic oxidation, often using oxygen. Examples include nitric acid (from ammonia), sulphuric acid (from sulphur dioxide to sulphur trioxide by the chamber process), terephthalic acid from p-xylene, and acrylonitrile from propane and ammonia.

Which of the following statements is wrong regarding the catalysts?

  1. The catalyst is generally specific in nature

  2. The catalyst cannot change the position of equilibrium

  3. The catalyst cannot initiate the reaction

  4. Needed in large quantities


Correct Option: D
Explanation:

A small quantity of the catalyst is generally sufficient to catalyse a reaction.  (i) For example, in the decomposition of hydrogen peroxide, one gram of colloidal platinum can catalyse 108 litres of hydrogen peroxide.

Which of the following catalytic processes takes place inside a living cell?

  1. Phase Boundary Catalysis

  2. Homogeneous catalysis

  3. Enzyme catalysis

  4. Autocatalysis


Correct Option: C
Explanation:

Enzyme catalysis is the catalysis of chemical reactions by specialized proteins known as enzymes. Catalysis of biochemical reactions in the cell is vital due to the very low reaction rates of the uncatalysed reactions.

Enzymes catalysed reactions are the examples of _________ catalysis.

  1. acid base catalysis

  2. biocatalysis

  3. photocatalysis

  4. autocatalysis


Correct Option: B
Explanation:

Biocatalysis is the use of natural catalysts, such as protein enzymes, to perform chemical transformations on organic compounds. Both the enzymes that have been more or less isolated and enzymes still residing inside living cells are employed for this task.

Which of the following is not an application of colloids?

  1. Purification of water by alum

  2. In rubber and tanning industry

  3. Artificial rain

  4. None of these


Correct Option: D
Explanation:

All are applications of colloids.

Which of the following catalytic mechanisms is found in enzymes?

  1. Catalysis by proximity and orientation

  2. Electrostatic catalysis

  3. Covalent catalysis

  4. Catalysis by bond strain


Correct Option: C
Explanation:

Covalent catalysis involves the substrate forming a transient covalent bond with residues in the active site or with a cofactor. This adds an additional covalent intermediate to the reaction, and helps to reduce the energy of later transition states of the reaction. This mechanism is found in enzymes such as proteases like chymotrypsin and trypsin, where an acyl-enzyme intermediate is formed.

Which of the following properties regarding the colloids are wrong?

  1. They are known as bio-chemical catalysts.

  2. Smoke precipitation

  3. Formation of deltas

  4. Clot formation


Correct Option: A
Explanation:

Numerous reactions occur in the bodies of animals and plants to maintain the life process. These reactions are catalysed by enzymes. The enzymes are thus, termed as bio-chemical catalysts and the phenomenon is known as bio-chemical catalysis.

Which of the following statements regarding the zeolites is false?

  1. Zeolite have low porosity

  2. The pore size in zeolites generally varies from 260 pm to 740 pm

  3. Open structure

  4. The void space forms more than 50% of the total volume


Correct Option: A
Explanation:

Zeolite have high porosity due to the presence of one, two, or three dimensional networks of interconnected channels and cavities of molecular dimensions.

Which of the following can be excluded from the properties of emulsion?

  1. The particle size ranges from 1000 إ to 10,000 إ

  2. These are coagulated by the addition of electrolytes 

  3. Shows thixotropy

  4. Shows Brownian movement


Correct Option: C
Explanation:

Some gels are known to liquify on shaking and reset on being allowed to stand. This reversible sol-gel transformation is called thixotropy.

Which of the following can be excluded from the main characteristic properties of colloidal solutions?

  1. Shows colligative properties

  2. The colloidal solutions are quite stable

  3. Undergoes sedimentation

  4. Colloidal sols are homogeneous in nature


Correct Option: D
Explanation:

Colloidal sols are heterogeneous in nature. They consists of two phases; the dispersed phase and the dispersion medium.

Reverse of which of the following processes is called streaming potential?

  1. Electro-osmosis

  2. Electrophoresis

  3. Tyndall effect

  4. Brownian movement


Correct Option: A
Explanation:

Electro-osmosis is a phenomenon in which dispersion medium is allowed to move under the influence of an electrical field, whereas colloidal particles are not allowed to move. The existence of electro-osmosis has suggested that when liquid is forced through a porous material or a capillary tube, a potential difference is setup between the two sides called as streaming potential. So the reverse of electro-osmosis is called streaming potential.

Which of the following destroys the activity of the catalyst?

  1. Ribozyme

  2. Catalytic poisons

  3. Catalytic promoters

  4. Inhibitors


Correct Option: B
Explanation:

Substances which destroy the activity of the catalyst by their presence are known as catalytic poisons. (i) For example, the presence of traces of arsenious oxide (As2O3) in the reacting gases reduces the activity of platinized asbestos which is used as catalyst in contact process for the manufacture of sulphuric acid.

The process used to prevent the sol particles from setting out under the action of gravity is known as

  1. ultra centrifugation

  2. ultra filtration

  3. electrodialysis

  4. dialysis


Correct Option: A
Explanation:

The sol particles are prevented from setting out under the action of gravity by kinetic impacts of the molecules of the medium. The setting force can be enhanced by using high speed centrifugal machines having 15,000 or more revolutions per minute. Such machines are known as ultra-centrifuges.

Milk is a good example of

  1. zeolite

  2. emulsion

  3. elastic gels

  4. non-elastic gels


Correct Option: B
Explanation:

Emulsion are the colloidal solutions in which both the dispersed phase and the dispersion medium are liquids. A good example of an emulsion is milk in which fat globules are dispersed in water. The size of the emulsified globules is generally of the order of 10-6 m. Emulsion resembles lyophobic sols in some properties.

Corrosion is an example of

  1. polarizability

  2. physisorption

  3. chemisorption

  4. dissociation


Correct Option: C
Explanation:

Chemisorption is a sub-class of adsorption, driven by a chemical reaction occurring at the exposed surface. A new chemical species is generated at the adsorbant surface e.g., corrosion, metallic oxidation. The strong interaction between the adsorbate and the substrate surface creates new types of electronic bonds - ionic or covalent, depending on the reactive chemical species involved.

Which of the following technologies is used to separate a mixture of gases?

  1. Wetting

  2. Protein adsorption

  3. Adsorbtion spillover

  4. Pressure swing adsorption


Correct Option: D
Explanation:

Pressure swing adsorption (PSA) is a technology used to separate some gas species from a mixture of gases under pressure according to the species' molecular characteristics and affinity for an adsorbent material. It operates at near-ambient temperatures and so differs from cryogenic distillation techniques of gas separation.

Which of the following sols are called reversible sols?

  1. Lyophilic colloids

  2. Lyophobic colloids

  3. Multimolecular colloids

  4. Associated colloids (Micelles)


Correct Option: A
Explanation:

In this type of colloids sols, the dispersed phase has great attraction for the dispersion medium. In such colloids, the dispersed phase does not precipitate easily and the sols are quite stable. If the dispersion medium is separated from the dispersed phase, the sol can be reconstituted by simply remixing with the dispersion medium. Hence, these sols are called reversible sols. Examples of lyophilic sols include sols of gum, gelatine, starch, proteins and certain polymers in organic solvents.

Which of the following methods is used for obtaining metals like silver, gold and platinum, in colloidal state?

  1. Peptization

  2. Oxidation

  3. Reduction

  4. Hydrolysis


Correct Option: C
Explanation:

A number of metals such as silver, gold and platinum, have been obtained in colloidal state by treating the aqueous solution of their salts, with a suitable reducing agent such as formaldehyde, phenyl hydrazine, hydrogen peroxide, stannous chloride etc..

The hexadecane or cetyl alcohols are the examples of

  1. water-in-water emulsion

  2. microemulsions

  3. miniemulsion

  4. pickering emulsion


Correct Option: C
Explanation:

A miniemulsion is a special case of emulsion. A miniemulsion is obtained by shearing a mixture comprising two immiscible liquid phases, one surfactant and one co-surfactant. Typical examples are hexadecane or cetyl alcohol.

Soaps and detergents are examples of

  1. macromolecular colloids

  2. associated colloids

  3. micelles

  4. lyophobic colloids


Correct Option: C
Explanation:

Micelles are the clusters or aggregated particles formed by association of colloids in solution. 

- Hide questions