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Chemistry (AIPVT)

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The best position of hydrogen in the periodic table is above IA group. What is the reason?

In the classification of elements in the periodic table, hydrogen is placed at the top of IA group. It has many similarities with the group elements.

  1. Electropositive nature of all the IA group elements

  2. All the elements have similar outermost shell configuration

  3. Elements have the tendency to form ionic compouds.

  4. All the elements have low melting points.

  5. All of the above


Correct Option: E
Explanation:

All the answers given above are correct.

It is false that electron affinity

When an element gives off its electron and forms a positive ion, it is called electropositivity of that element.

X + e-= X- + energy

 

  1. causes energy to be released

  2. causes energy to be absorbed

  3. is expressed in eV (electron volt)

  4. involves formation of an anion

  5. decreases down a group


Correct Option: B
Explanation:

A negative ion is formed when an electron is added to a neutral atom. The energy released during this process is called electron affinity of that atom.

The most reactive element among group 17 will be

Among the halogen family, if we observe the values like ionisation energies, electron affinity and electronegativity, we can predict the reactivity of an element among the group. As we see the trend, all the values decrease down the group.

  1. 9F18

  2. 17Cl35

  3. 35Br79

  4. 53I126

  5. 85At210


Correct Option: A
Explanation:

Flourine will be the most reactive among halogens.

At STP, which substance is the best conductor of electricity?

Conductivity refers to the ability of a material to transmit energy. There are different types of conductivity, including electrical conductivity and thermal conductivity.

  1. 7N14

  2. 10Ne20

  3. 16S32

  4. 5B10

  5. 47Ag108


Correct Option: E
Explanation:

Copper is less expensive and gold has a much higher corrosion resistance.

Hydrogen resembles with carbon because of

1H1- hydrogen belongs to first group of periodic table with the electronic configuration of 1s1.

6C12- carbon belongs to p-block and electronic configuration is 1s22s22p4.

  1. the same number of electrons in the valence shell

  2. similar physical properties

  3. remarkable reducing properties

  4. homovalent similarity

  5. allotropy similarity


Correct Option: C
Explanation:

Reduction is a chemical reaction in which proton is added or electron is removed.

Reduction is a chemical reaction in which proton is added or electron is removed.

Which of the following elements would lose an electron easily?

Ionisation energy is the energy required to remove the most loosely held electron from one mole of gas. This is more easily seen in symbol terms as

 X(g)------------->X+ + e-

  1. 11Na23

  2. 12Mg24

  3. 19K37

  4. 20Ca40

  5. 56Ba137


Correct Option: C
Explanation:

First ionisation energy of potassium is 419 kJmol-1.

Which set of elements contains a metalloid?

Metals are generally hard, shiny and malleable. They are good conductors. Examples of metals are gold, silver, iron, uranium and zinc.

Non-metals are brittle and are not easily molded into shapes. They are poor conductors of heat and electricity. Examples of non-metal elements are hydrogen and carbon.

Metalloids share characteristics of both metals and non-metals and are also called semi-metals. Metalloids are typically semi-conductors, which means that they both insulate and conduct electricity. This semi-conducting property makes them very useful as a computer chip material. Examples of metalloid elements are silicon and boron.

  1. 19K39, 33As74.9, 18Ar39.9, 25Mn54

  2. 3Li6.54, 12Mg24.305, 20Ca40.078, 36Kr83.378

  3. 83Fr223, 53I126.9, 8O16, 86Rn222

  4. 3Li6, 12Mg24.305, 20Ca40.078, 18Ar39

  5. 11Na23, 19K39, 26Fe55.845, 16S32.06


Correct Option: A
Explanation:

 
 This is correct.

Down a group, electron affinity

The amount of energy released when an electron is added to a neutral atom or molecule in the gaseous state to form a negative ion:

 X + e → X + energy

  1. decreases

  2. increases

  3. remains the same

  4. increases and then, decreases

  5. decreases and then, increases


Correct Option: A
Explanation:

While going down in a group, electron affinity value decreases.

The element with the highest electron affinity is

When an atom gains electron, energy is given off and this energy is known as electron affinity for that particular atom or molecule. Electron affinity is defined as the energy released when an electron is added to a gaseous atom or ion. 

T + e- =  T-

Cl + e--= Cl1- 

(Ne)3s23p5------>(Ne)3s23p6

 

                                        

 

                                       

 

                                        



 

 

 

 

 

 

 

  1. 11Na23

  2. 12Mg24

  3. 14Si28

  4. 17Cl35

  5. 18Ar36


Correct Option: D
Explanation:

Electron affinity - 349 kJ/mole

 

What affects the ionisation energy of an element?

Ionisation energy of an atom or molecule describes the minimum amount of energy required to remove an electron from the atom or molecule in the gaseous state.

X   +  energy---->  X+ + e-

  1. Atomic size

  2. Electron affinity

  3. Electronegativity

  4. Neutron

  5. Proton


Correct Option: A
Explanation:

In small atoms, electrons remains close to the  nucleus and they have more nuclear attraction, so more energy is required to remove electrons from small atoms. In small atoms, electrons remains close to the nucleus and they have more nuclear attraction, so more energy is required to remove electrons from small atoms.

Which of the following factors does not effect the metallic character of an element?

When an element shows properties like loosing electrons easily, getting reduced easily, formation of ionic halides and basic oxides and has the ability to displace hydrogen from dilute acids, it is considered to be a metal. Metallic character decreases across a period. This occurs because atoms accept electrons more readily to fill the valence shell than loosing one. Metallic character increases while moving down a group because atoms lose electrons more easily because of the increase in the atomic radii, resulting in decrease in the attraction between nucleus and valence electrons.

  1. Atomic size

  2. Ionisation energy

  3. Electronegativity

  4. Atomic radius

  5. Electronic configuration


Correct Option: C
Explanation:

This is the correct option.

Five elements A, B, C, D and E have the following atomic numbers. Among these elements, which element belongs to third period and has the highest ionisation potential?

The minimum amount  of energy is required to pull out an electron from an atom or molecule in the gaseous state.
The first ionisation energy is the energy required to remove the most loosely held electron from one mole of gaseous atoms to produce 1 mole of gaseous ions, each with a charge of 1+.

X(g)------------>X++e-
It is the energy needed to carry out this change per mole of X.

  1. A = 12

  2. B = 17

  3. C = 18

  4. D = 7

  5. E = 11


Correct Option: C
Explanation:

The element C is argon.

Which of the following does not increase while moving towards higher groups?

Periodic properties of chemical elements reoccur periodically. This is the basis of creation of periodic table. In the classification of elements, elements show a periodic trend in many properties. The main basis of classification of these elements is increasing atomic number, which represents increasing positive charge in the nucleus. Negatively charged electrons are arranged in orbitals around the nucleus. The recurring properties of these elements are due to recurring configurations of these electrons in the orbitals around the nucleus.

  1. Atomic radius

  2. Metallic character

  3. Valency

  4. Electronegativity

  5. Ionisation energy


Correct Option: C
Explanation:

In a group, valency is always constant. Across a period, it always increases.

The element which has zero electron affinity in the third period is

When an electron is added to a neutral atom in the gaseous state, certain amount of energy is released. During this process, this energy is called electron affinity of that particular atom.

 X + e-----> X -

For explanation to this question, first electronic configurations of all these elements have to be taken into consideration.

  1. 13Al26

  2. 15P30

  3. 18Ar39

  4. 14Si28

  5. 16S32


Correct Option: C
Explanation:

Electronic configuration = 1s22s22p63s23p6   Electron affinity value = 0 The outermost shell is completely filled, therefore the electron affinity value is zero.

An atom of which of the following elements has the greatest ability to attract electrons?

The ability of attracting electrons of any element is called electronegativity of that element. Electronegativity is affected by both its atomic number as well as the distance between its nucleus and the valence shell electrons. The higher the value of electronegativity, more electrons get attracted. It is a dimensionless quantity, commonly referred to as the Pauling scale on a relative scale starting from 0.7 to 3.98.

  1. 14Si28

  2. 16S32

  3. 6C12

  4. 17Cl35.5

  5. 5B11


Correct Option: D
Explanation:

Chlorine has the highest electronegativity value among the list of elements given.

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