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Chemistry Mixed Test

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Which of the following is used in welding of iron?

  1. Westrosol

  2. PVC

  3. Acrylonitrile

  4. Oxyacetylene

  5. Lewisite


Correct Option: D
Explanation:

This option is correct because oxyacetylene is used in welding, cutting and cleansing of iron.

Which of the following is/are obtained when DDT loses HCl?

  1. PTEF

  2. DDE

  3. BAL

  4. MIC

  5. Both (3) and (4)


Correct Option: B
Explanation:

This option is correct.

Dacron belongs to which of the following units of the polymers?

  1. Polythene

  2. Polystyrene

  3. Neoprene

  4. Terylene

  5. Only (1) and (2)


Correct Option: D
Explanation:

This option is correct because Dacron belongs to terylene unit of the polymers.

Which of the following types of the isomerism is shown by [Cr(NH3)5(NO2)]Cl2 compound?

  1. Optical

  2. Ionisation

  3. Geometrical

  4. Linkage

  5. Hydrated


Correct Option: D
Explanation:

This option is correct because complex pentamminenitrito chromium (III) chloride exhibits the linkage isomerism.

Which of the following is correct regarding sour gasoline?

  1. Gasoline produces an offensive odour with sulphur compounds.

  2. Gasoline has 74 octane number.

  3. Gasoline has 84 octane number.

  4. Gasoline has more than 100 octane number.

  5. None of these


Correct Option: A
Explanation:

This option is correct.

The Kolbe's electrolytic method is introduced by using

  1. CH3COONa and H2O

  2. R2CuLi and RX

  3. CH3CHO and NH2NH2

  4. RX and Zn

  5. RCOOAg and I2


Correct Option: A
Explanation:

This option is correct. In the electrolysis of the concentrated aqeuous solution of alkali salt of the saturated monocarboxylic acid using Pt electrode, alkane is collected at anode, while the strong base is collected at cathode.

Plexiglass and perspex belong to

  1. PVC

  2. PMMA

  3. saran

  4. glyptal

  5. melmac


Correct Option: B
Explanation:

This option is correct.

The phthalic acid and anisole are synthesised by

  1. Gabriel and Williamson synthesis

  2. Williamson and Gattermann Koch synthesis

  3. Wohler and Gabriel synthesis

  4. Wohler and Gattermann Koch synthesis

  5. Fischer-tropsch and Williamson synthesis


Correct Option: A
Explanation:

This option is correct because phthalimide is first of all treated with KOH to form potassium phathalimide, which is then heated with alkyl halides which gives N-alkyl phthalimide. Then, it is hydrolysed by the HCl to form phthalic acid, this is the Gabriel synthesis, while phenol reacts with diethyl sulphonate catalysed by strong base to form the anisole.

The most stable complex ion is

  1. [Fe(OH)6]3-

  2. [Fe(CN)6]3-

  3. [Fe(Cl)6]3-

  4. [Fe(H2O)6]3+

  5. None of these


Correct Option: B
Explanation:

This option is correct because the stability of the complex ion is determined by the strength of ligand. Hence, CN ligand has strong ligand field. On the basis of its nature, this complex ion is the most stable. Cl and water  belongs to low ligand field.

Which of the following produces reddish brown precipitate?

  1. Formic acid and tollen reagent

  2. Formic acid and fehling solution

  3. 2-pentanone is catalysed by I2+NaOH/NaOI

  4. 3-pentanone

  5. Only option (3) and (4)


Correct Option: B
Explanation:

This option is correct because formic acid and Fehling solution react to produce cuprous oxide, which gives reddish brown precipitate.

In which of the following reactions, Pb/BaSO4 catalysis is used?

  1. Perkin reaction

  2. Tishchenko reaction

  3. Rosenmund reaction

  4. Clemmensen reaction

  5. Reformatsky reaction


Correct Option: C
Explanation:

This option is correct because aldehydes are formed more easily to get reduced with acid chloride, but their reduction is checked by barium sulphate. The catalytic hydrogenation of acid chlorides allows the formation of aldehydes.

Which of the following oxides produces an acidic as well as a basic oxide during thermal decomposition?

  1. NaNO3

  2. KClO3

  3. CaCO3

  4. NH4NO3

  5. Both (1) and (2)


Correct Option: C
Explanation:

This option is correct because calcium carbonate when heated, decomposes into calcium oxide and carbon dioxide, which acts as basic as well as acidic oxide.

Which of the following compounds shows maximum covalent character?

  1. SnCl4

  2. AlCl3

  3. MgCl2

  4. FeCl2

  5. NaCl


Correct Option: B
Explanation:

This option is correct.

During the preparation of acetanilide from aniline, a small amount of Zn is added to the reaction mixture because

  1. zinc induces the precipitation

  2. zinc prevents the reduction of aniline during the reaction

  3. zinc reduces the coloured impurities in the aniline and also prevents its oxidation during the reaction

  4. zinc forms the white crystalline complex with aniline

  5. Only (3) and (4)


Correct Option: C
Explanation:

This option is correct because acetanilide are formed by the aniline due to the addition of zinc, this reduces the coloured impurities of the aniline and also prevents the oxidation of the reaction.

Para-toluidine and benzyl amine can be distinguished by

  1. Victor Meyer test

  2. Dyes test

  3. Molisch test

  4. Gattermann reaction

  5. Lucas test


Correct Option: B
Explanation:

This option is correct because para-toluidine contains the amino group. It undergoes the diasotisation reaction to give red dyes. Thus in benzyl amine, amino group is not directly attached with benzene. Hence, it does not undergoes diasotisation reaction.

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