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Periodic Classification of Elements

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In the modern periodic table, the elements of a group have similar properties because they have the same

  1. atomic number

  2. atomic weight

  3. number of valence electrons

  4. electronic configuration

  5. number of neutrons


Correct Option: C
Explanation:

The properties of an element depend on the valence electrons or the number of electrons in the outermost orbit. In a group of modern periodic table, all the elements have the same number of valence electrons. For example, all alkali elements have one electron in their outermost orbit. Hence, they have similar properties.

According to the periodic law, when the elements are arranged in the _______________ order of their ________________, their properties show periodicity.

  1. increasing, atomic weights

  2. decreasing, atomic weights

  3. increasing, atomic numbers

  4. decreasing, atomic numbers

  5. increasing, atomic mass numbers


Correct Option: C
Explanation:

As per the definition of the modern periodic law stated by Mosely, the physical and chemical properties of elements are the periodic functions of their atomic numbers. Hence, the third option is correct.

In the same period or group, there is a gradation in a particular property because

  1. there is a gradual increase in the number of shells across a period

  2. there is a gradual change in the electronic configuration of the elements

  3. there is a gradual increase in the number of valence electrons down the group

  4. there is a gradual increase in the atomic weights of the elements

  5. there is a gradual increase in their atomic size


Correct Option: B
Explanation:

In the modern periodic table, the elements are arranged in the increasing order of their atomic numbers. The number of electrons in an atom are equal to its atomic number. Hence, there is a gradual change in their electronic configuration.

Find the odd one out.

Sodium (Z = 11); Aluminium (Z = 13); Chlorine (Z = 17); Argon (Z = 18); Potassium (Z = 19)

  1. Aluminium

  2. Argon

  3. Chlorine

  4. Potassium

  5. Sodium


Correct Option: D
Explanation:

Potassium belongs to the fourth period whereas the remaining elements belong to the third period.

Atomic numbers of four elements A, B, C, D and E are 14, 15, 17, 18 and 19, respectively. Which of these is highly non-metallic?

  1. A

  2. B

  3. C

  4. D

  5. E


Correct Option: C
Explanation:

Metals have 1, 2 or 3 electrons in their outermost orbit and non-metals have 5, 6 or 7 electrons in their outermost orbit. The electronic configurations of A, B, C, D and E are 2, 8, 4; 2, 8, 5; 2, 8, 7; 2, 8, 8; and 2, 8, 8, 1, respectively. As the element C has 7 electrons in its outermost orbit as compared to 5 electrons in element B, so it is more non-metallic. Hence, option (3) is the correct answer.

Arrange the elements O, B, N and F in the increasing order of their atomic sizes.

  1. F < O < N < B

  2. B < N < O < F

  3. O < F < N < B

  4. B < O < N < F

  5. F < N < B < O


Correct Option: A
Explanation:

The second period in the modern periodic table consists of the elements lithium, beryllium, boron, carbon, nitrogen, oxygen, fluorine and neon, in that order. The given elements belong to the second period. As we move from left to right of a period, the atomic size decreases. Hence, the first option is correct.

An element 'X' is a silver-gray solid with a density of 0.86 g/cm3 and melting point of 630C. The element exhibits vigorous reaction with cold water. In which group is the element likely to be found in the periodic table?

  1. Group 1

  2. Group 2

  3. Group 14

  4. Group 17

  5. Group 18


Correct Option: A
Explanation:

Elements of group 1 are alkali metals. They are lustrous solids with low density and low melting points. They react vigorously with cold water to form alkalis. Hence, option (1) is the correct answer.

Which of the following factors affect the ionisation potential?

  1. Atomic number and number of neutrons

  2. Atomic size and nuclear charge

  3. Number of valence electrons and atomic weight

  4. Number of neutrons and mass number

  5. Number of protons and relative atomic mass


Correct Option: B
Explanation:

Ionisation potential is the energy required to remove one or more electrons from the outermost orbit of an isolated gaseous atom. The smaller the size of the atom, the more difficult it becomes to remove the valence electron due to the attraction of the nuclear charge on the electrons.

Name the element with the least ionisation potential from the elements of periods 1, 2 and 3.

  1. Hydrogen

  2. Lithium

  3. Sodium

  4. Fluorine

  5. Chlorine


Correct Option: C
Explanation:

Ionisation potential increases as we move from the left to the right of a period and decreases as we move down a group. Sodium is on the extreme left of period 3. Hence, it has the least ionisation potential as compared to the elements of the first three periods.

An element 'A' is in group 2 of period 2 and another element 'B' is in the same group but in period 3. The proton number of 'A' is

  1. 1 less than that of 'B'

  2. 8 less than that of 'B'

  3. 8 more than that of ‘B’

  4. 7 less than that of 'B'

  5. 18 less than that of 'B'


Correct Option: B
Explanation:

In the modern periodic table, the first period has 2 elements, the second has 8 elements and the third also has 8 elements. The electronic configuration of ‘A’ is 2, 2 and the electronic configuration of ‘B’ is 2, 8, 2. In a neutral atom, number of protons is equal to the number of electrons. Hence, ‘A’ will have 8 protons less than 'B'.

Arrange the elements Cl, Al, Na and S in the decreasing order of their ionisation potential.

  1. Na > Al > S > Cl

  2. Cl > Al > S > Na

  3. Na > S > Al > Cl

  4. Cl > Na > S > Al

  5. Cl > S > Al > Na


Correct Option: E
Explanation:

The third period in the modern periodic table consists of the elements sodium, magnesium, aluminium, silicon, phosphorous, sulphur, chlorine and argon, in that order. The given elements belong to the third period. As we move from left to right of a period, the ionisation potential increases. Hence, sodium has the least ionisation potential and chlorine has the highest. So, the fifth option is correct.

Elements with stable configuration, e.g. neon, have an electron affinity value of

  1. 0

  2. 1

  3. -1

  4. between -1 and 0

  5. between 0 and 1


Correct Option: A
Explanation:

As the elements with noble configuration have completely filled valence shells, they neither accept electrons nor lose electrons. Hence, they have 0 electron affinity.

The hydroxide of the element belonging to period 3 and group 13 will be

  1. an alkali

  2. acidic in nature

  3. basic in nature

  4. amphoteric in nature

  5. neutral


Correct Option: D
Explanation:

The element in question is aluminium as it has the electronic configuration 2, 8, 3. This metal is amphoteric in nature; it reacts with both acids and alkalis. Hence, its oxide and hydroxide are amphoteric in nature.

The electronegativity values of three elements 'X', 'Y' and 'Z' are 0.93, 2.6 and 3.2, respectively. The chemical bond formed between the atoms of 'X' and 'Z' will be ___________ and the chemical bond formed between 'Y' and 'Z' will be __________.

  1. covalent, covalent

  2. covalent, electrovalent

  3. electrovalent, covalent

  4. covalent, ionic

  5. electrovalent, ionic


Correct Option: C
Explanation:

The tendency of an atom to attract electrons towards itself when combined in a compound is called electronegativity. If the difference in electronegativity values between the combining atoms is more, then the chemical bond formed between them will be electrovalent. If the difference in electronegativity values between the combining atoms is less, then the chemical bond formed between them will be covalent.

Arrange Br, Br+ and Br- in the increasing order of volumes.

  1. Br < Br- <Br+

  2. Br+ < Br < Br-

  3. Br < Br+ < Br-

  4. Br- < Br < Br+

  5. Br+ < Br- < Br


Correct Option: B
Explanation:

When an atom accepts an electron, the anion is larger than its parent atom because the nuclear charge gets distributed over more electrons than earlier. Similarly, when an atom loses an electron, the cation is smaller than its parent atom because the nuclear charge gets distributed over fewer electrons than earlier.  Hence, the correct option is (2).

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